A latex composition for dip molding including a latex of a conjugated diene polymer (A) having a methyl ethyl ketone insolubles content of 50% by weight or less, and a latex of a polymer (B) having a methyl ethyl ketone insolubles content of 55% by weight or more.

A method for producing a vinyl polymer including a polymerization step of using a composition including a microcapsule and polymerizing a vinyl monomer by radical reaction to produce a vinyl polymer, in which the microcapsule has a core/shell structure, and the shell includes a water-soluble polymer and the core includes an organic peroxide. The water-soluble polymer is preferably at least one water-soluble polymer selected from the group consisting of polyvinyl alcohol, cellulose derivatives, gelatin, poly(meth)acrylic acid derivatives, polyvinylpyrrolidone, and polyethylene oxide.

A method for producing a vinyl polymer including a polymerization step of using a composition including a microcapsule and polymerizing a vinyl monomer by radical reaction to produce a vinyl polymer, in which the microcapsule has a core/shell structure, and the shell includes a water-soluble polymer and the core includes an organic peroxide. The water-soluble polymer is preferably at least one water-soluble polymer selected from the group consisting of polyvinyl alcohol, cellulose derivatives, gelatin, poly(meth)acrylic acid derivatives, polyvinylpyrrolidone, and polyethylene oxide.

A novel promotor which contains an aniline derivative is introduced. By using the promotor alone, the time and temperature of the curing reaction of the vinyl ester resin can be controlled by the unique steric effect and electronic properties of the aniline derivative. A method for preparing the above promotor is also introduced.

A novel promotor which contains an aniline derivative is introduced. By using the promotor alone, the time and temperature of the curing reaction of the vinyl ester resin can be controlled by the unique steric effect and electronic properties of the aniline derivative. A method for preparing the above promotor is also introduced.

Embodiments are directed to a method of making an olefin-based polymer by free-radical polymerization in a reactor system. The method includes initiating a free-radical polymerization of an olefin-based monomer, propagating growth of the olefin-based polymer during continued free-radical polymerization of the olefin-based monomer, and adding to the reactor system a chain transfer agent that terminates the growth of the olefin-based polymer. The chain transfer agent includes a silane. Examples of suitable silanes are: triethylsilane, diethylmethylsilane, tris(trimethylsilyl)silane, n-butylsilane, dimethylphenylsilane, phenylsilane, chlorodimethylsilane, diisopropylaminosilane, 1,2-bis(dimethylsilyl) benzene, 1,3-bis(dimethylsilyl) benzene, 1,4-bis(dimethylsilyl)benzene, 1,1, 3,3-tetramethyldisiloxane, trimethylsilane, (trimethylsilyl)dimethylsilane, and bis(trimethylsilyl)methylsilane.

Embodiments are directed to a method of making an olefin-based polymer by free-radical polymerization in a reactor system. The method includes initiating a free-radical polymerization of an olefin-based monomer, propagating growth of the olefin-based polymer during continued free-radical polymerization of the olefin-based monomer, and adding to the reactor system a chain transfer agent that terminates the growth of the olefin-based polymer. The chain transfer agent includes a silane. Examples of suitable silanes are: triethylsilane, diethylmethylsilane, tris(trimethylsilyl)silane, n-butylsilane, dimethylphenylsilane, phenylsilane, chlorodimethylsilane, diisopropylaminosilane, 1,2-bis(dimethylsilyl) benzene, 1,3-bis(dimethylsilyl) benzene, 1,4-bis(dimethylsilyl)benzene, 1,1, 3,3-tetramethyldisiloxane, trimethylsilane, (trimethylsilyl)dimethylsilane, and bis(trimethylsilyl)methylsilane.

Low-temperature radical polymerisation of alkoxyamines

The present invention relates to a process for the radical polymerization of alkoxyamines at low temperature, typically at temperatures as low as −50° C., in the presence of a nitroxide reducing agent.

The present invention relates to a novel copolymer, to processes for preparation thereof and to the use thereof.

The invention relates to an organic peroxide emulsion containing at least one organic peroxide, at least one emulsifier comprising at least one nonionic surfactant including at least one fatty chain and/or a protective colloid agent, a combination of two or more antigels containing no more than 9.5 wt% of a first antifreeze relative to the total weight of the ethanol emulsion, at least a second antifreeze and water. The invention also relates to a method for preparing such an emulsion, the use of such an emulsion for the polymerization or copolymerization of one or more ethylenically unsaturated monomers, and a halogenated vinyl polymer obtained by the use of such an emulsion.