Provided herein is a resin product useful for the production of three-dimensional objects by additive manufacturing, and methods using the same. The resin may include a reactive blocked prepolymer comprising a prepolymer blocked with reactive blocking groups; a polyol; a photoinitiator; and at least one organometallic catalyst. A packaged product useful for the production of three-dimensional objects by additive manufacturing, the product comprising a single container having a single chamber and a resin in the chamber with all components mixed together, is also provided.

Provided herein is a resin product useful for the production of three-dimensional objects by additive manufacturing, and methods using the same. The resin may include a reactive blocked prepolymer comprising a prepolymer blocked with reactive blocking groups; a polyol; a photoinitiator; and at least one organometallic catalyst. A packaged product useful for the production of three-dimensional objects by additive manufacturing, the product comprising a single container having a single chamber and a resin in the chamber with all components mixed together, is also provided.

A copolymer of a 1,3-diene and of an olefin selected from the group consisting of α-monoolefins, ethylene and mixtures thereof is provided. The copolymer bears, at one of its chain ends, an alkoxysilyl or silanol function, functional group F.sup.1, and the copolymer is different from a copolymer of a 1,3-diene and a vinylaromatic monomer.

A copolymer of a 1,3-diene and of an olefin selected from the group consisting of α-monoolefins, ethylene and mixtures thereof is provided. The copolymer bears, at one of its chain ends, an alkoxysilyl or silanol function, functional group F.sup.1, and the copolymer is different from a copolymer of a 1,3-diene and a vinylaromatic monomer.

This disclosure relates to a method and an apparatus for the delivery of a multi-component olefin polymerization catalyst to a polymerization reactor. The apparatus includes: a first catalyst component delivery conduit; a second catalyst component delivery conduit which is disposed within the first catalyst component delivery conduit; a first catalyst component mixing conduit; a third catalyst component delivery conduit which is disposed within the first catalyst component mixing conduit; a second catalyst component mixing conduit comprising an upstream section and a downstream section, the downstream section terminating within the polymerization reactor; and a diluent delivery conduit; the first and second catalyst component delivery conduits each being open-ended and co-terminating at the first catalyst component mixing conduit; the first catalyst component mixing conduit and the third catalyst component delivery conduit each being open-ended and co-terminating at the upstream section of the second catalyst component mixing conduit; and the diluent delivery conduit terminating at the downstream section of the second catalyst component mixing conduit.

This disclosure relates to a method and an apparatus for the delivery of a multi-component olefin polymerization catalyst to a polymerization reactor. The apparatus includes: a first catalyst component delivery conduit; a second catalyst component delivery conduit which is disposed within the first catalyst component delivery conduit; a first catalyst component mixing conduit; a third catalyst component delivery conduit which is disposed within the first catalyst component mixing conduit; a second catalyst component mixing conduit comprising an upstream section and a downstream section, the downstream section terminating within the polymerization reactor; and a diluent delivery conduit; the first and second catalyst component delivery conduits each being open-ended and co-terminating at the first catalyst component mixing conduit; the first catalyst component mixing conduit and the third catalyst component delivery conduit each being open-ended and co-terminating at the upstream section of the second catalyst component mixing conduit; and the diluent delivery conduit terminating at the downstream section of the second catalyst component mixing conduit.

An ethylene/butadiene copolymer comprising statistically distributed ethylene units and butadiene unit is provided. The molar fraction of the ethylene units in the copolymer is greater than or equal to 50%, relative to the total number of moles of ethylene and butadiene units. The microstructure of the copolymer is homogeneous. A process for preparing such a copolymer and also the uses of this copolymer, in particular in rubber compositions for tires is also provided.

An ethylene/butadiene copolymer comprising statistically distributed ethylene units and butadiene unit is provided. The molar fraction of the ethylene units in the copolymer is greater than or equal to 50%, relative to the total number of moles of ethylene and butadiene units. The microstructure of the copolymer is homogeneous. A process for preparing such a copolymer and also the uses of this copolymer, in particular in rubber compositions for tires is also provided.

The present disclosure provides a redox initiator system for initiating polymerization comprising an oxidizing agent, a photolabile reducing agent, and a transition metal complex that participates in a redox cycle. On exposure to actinic radiation, such as UV, the photolabile compound photolyzes, releasing the reducing agent and initiating the redox-initiated polymerization

The present disclosure provides a redox initiator system for initiating polymerization comprising an oxidizing agent, a photolabile reducing agent, and a transition metal complex that participates in a redox cycle. On exposure to actinic radiation, such as UV, the photolabile compound photolyzes, releasing the reducing agent and initiating the redox-initiated polymerization