Provided is a method of producing a vinyl chloride-based polymer composite, which includes: forming particle nuclei by bulk polymerizing vinyl chloride-based monomers; producing a vinyl chloride-based polymer by bulk polymerizing vinyl chloride-based monomers in the presence of the particle nuclei; and producing a vinyl chloride-based polymer composite including the vinyl chloride-based polymer and a cellulose-based compound.

A method for producing a vinyl chloride type polymer is to produce the vinyl chloride type polymer by polymerizing a vinyl chloride monomer, or a mixture of a vinyl chloride monomer with a monomer copolymerizable with the vinyl chloride monomer in an aqueous medium by using a polymerization reactor. An aqueous solution of a copolymerized polyether having a weight-average molecular weight of 1,000 to 3,500 with a mole ratio of ethylene oxide to propylene oxide in the range of 10/90 to 60/40 is charged into the polymerization reactor with an amount of 0.005 to 0.050 part by weight as the copolymerized polyether relative to 100 parts by weight of the vinyl chloride monomer.

A method for producing a vinyl chloride type polymer is to produce the vinyl chloride type polymer by polymerizing a vinyl chloride monomer, or a mixture of a vinyl chloride monomer with a monomer copolymerizable with the vinyl chloride monomer in an aqueous medium by using a polymerization reactor. An aqueous solution of a copolymerized polyether having a weight-average molecular weight of 1,000 to 3,500 with a mole ratio of ethylene oxide to propylene oxide in the range of 10/90 to 60/40 is charged into the polymerization reactor with an amount of 0.005 to 0.050 part by weight as the copolymerized polyether relative to 100 parts by weight of the vinyl chloride monomer.

The present invention relates to a post-processing apparatus configured to post-process latex, the post-processing apparatus including: a receiving tank having therein a receiving part and having an inlet port through which the latex is introduced into the receiving part and a discharge port through which the latex is discharged; an ultrasonic wave generating device configured to generate ultrasonic waves to the latex accommodated in the receiving tank; a pressure reducing part configured to reduce a pressure of the receiving part of the receiving tank to discharge an unreacted monomer to the outside of the receiving tank; and a partition part provided in the receiving part of the receiving tank and comprising a plurality of partitions disposed in a direction from the inlet port toward the discharge port of the receiving tank, in which the latex accommodated in the receiving part moves along upper and lower sides of the plurality of partitions.

The present invention relates to a post-processing apparatus configured to post-process latex, the post-processing apparatus including: a receiving tank having therein a receiving part and having an inlet port through which the latex is introduced into the receiving part and a discharge port through which the latex is discharged; an ultrasonic wave generating device configured to generate ultrasonic waves to the latex accommodated in the receiving tank; a pressure reducing part configured to reduce a pressure of the receiving part of the receiving tank to discharge an unreacted monomer to the outside of the receiving tank; and a partition part provided in the receiving part of the receiving tank and comprising a plurality of partitions disposed in a direction from the inlet port toward the discharge port of the receiving tank, in which the latex accommodated in the receiving part moves along upper and lower sides of the plurality of partitions.

A modified vinyl alcohol-based polymer includes a polyoxyalkylene unit, and an organic acid unit bonded to a polyvinyl alcohol chain, the polyoxyalkylene unit includes a moiety represented by the general formula (I), the moiety being bonded to the polyvinyl alcohol chain only via an ether bond and/or a carbon-carbon bond, wherein a ratio of a number of moles of monomer units bonded to the polyoxyalkylene unit to a total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.01 mol % to 5 mol %, and a ratio of a number of moles of the organic acid unit to the total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.1 mol % to 10 mol %.

A modified vinyl alcohol-based polymer includes a polyoxyalkylene unit, and an organic acid unit bonded to a polyvinyl alcohol chain, the polyoxyalkylene unit includes a moiety represented by the general formula (I), the moiety being bonded to the polyvinyl alcohol chain only via an ether bond and/or a carbon-carbon bond, wherein a ratio of a number of moles of monomer units bonded to the polyoxyalkylene unit to a total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.01 mol % to 5 mol %, and a ratio of a number of moles of the organic acid unit to the total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.1 mol % to 10 mol %.

Provided are a method of preparing a vinyl chloride-based polymer composite, a vinyl chloride-based polymer composite, and a vinyl chloride-based polymer composite composition including the composite, the method including: a first step of performing bulk polymerization of vinyl chloride-based monomers; and a second step of recovering unreacted vinyl chloride-based monomers after the completion of the bulk polymerization and obtaining a vinyl chloride-based polymer composite, wherein polyvinyl alcohol is added in at least one step of the first step and the second step, and the polyvinyl alcohol is added in an amount of 0.003 parts by weight to 0.500 parts by weight based on a total of 100 parts by weight of the vinyl chloride-based monomers.

Provided are a method of preparing a vinyl chloride-based polymer composite, a vinyl chloride-based polymer composite, and a vinyl chloride-based polymer composite composition including the composite, the method including: a first step of performing bulk polymerization of vinyl chloride-based monomers; and a second step of recovering unreacted vinyl chloride-based monomers after the completion of the bulk polymerization and obtaining a vinyl chloride-based polymer composite, wherein polyvinyl alcohol is added in at least one step of the first step and the second step, and the polyvinyl alcohol is added in an amount of 0.003 parts by weight to 0.500 parts by weight based on a total of 100 parts by weight of the vinyl chloride-based monomers.

Provided are a method of preparing a vinyl chloride-based polymer composite, a vinyl chloride-based polymer composite, and a vinyl chloride-based polymer composite composition including the composite, the method including: a first step of performing bulk polymerization of vinyl chloride-based monomers; and a second step of recovering unreacted vinyl chloride-based monomers after the completion of the bulk polymerization and obtaining a vinyl chloride-based polymer composite, wherein polyvinyl alcohol is added in at least one step of the first step and the second step, and the polyvinyl alcohol is added in an amount of 0.003 parts by weight to 0.500 parts by weight based on a total of 100 parts by weight of the vinyl chloride-based monomers.