A photocurable composition includes a nanomaterial selected to emit radiation in a first wavelength band in the visible light range in response to absorption of radiation in a second wavelength band in the UV or visible light range. The second wavelength band is different than the first wavelength band. The photocurable composition further includes one or more (meth)acrylate monomers, a thiol crosslinker, and a photoinitiator that initiates polymerization of the one or more (meth)acrylate monomers in response to absorption of radiation in the second wavelength band. A light-emitting device includes a plurality of light-emitting diodes and the cured photocurable composition in contact with a surface through which radiation in a first wavelength band in the UV or visible light range is emitted from each of the light-emitting diodes

A photocurable composition includes a nanomaterial selected to emit radiation in a first wavelength band in the visible light range in response to absorption of radiation in a second wavelength band in the UV or visible light range. The second wavelength band is different than the first wavelength band. The photocurable composition further includes one or more (meth)acrylate monomers, a thiol crosslinker, and a photoinitiator that initiates polymerization of the one or more (meth)acrylate monomers in response to absorption of radiation in the second wavelength band. A light-emitting device includes a plurality of light-emitting diodes and the cured photocurable composition in contact with a surface through which radiation in a first wavelength band in the UV or visible light range is emitted from each of the light-emitting diodes

The optical fibers disclosed is a single mode optical fiber comprising a core region and a cladding region surrounding and directly adjacent to the core region. The core region can have a radius r.sub.1 in a range from 3 μm to 7 μm and a relative refractive index profile Δ.sub.1 having a maximum relative refractive index Δ.sub.1max in the range from 0.25% to 0.50%. The cladding region can include a first outer cladding region and a second outer cladding region surrounding and directly adjacent to the first outer cladding region. The first outer cladding region can have a radius r.sub.4a. The second outer cladding region can have a radius rob less than or equal to 45 μm and comprising silica based glass doped with titania.

The optical fibers disclosed is a single mode optical fiber comprising a core region and a cladding region surrounding and directly adjacent to the core region. The core region can have a radius r.sub.1 in a range from 3 μm to 7 μm and a relative refractive index profile Δ.sub.1 having a maximum relative refractive index Δ.sub.1max in the range from 0.25% to 0.50%. The cladding region can include a first outer cladding region and a second outer cladding region surrounding and directly adjacent to the first outer cladding region. The first outer cladding region can have a radius r.sub.4a. The second outer cladding region can have a radius rob less than or equal to 45 μm and comprising silica based glass doped with titania.

A disclosed multimode optical fiber comprises a core and a cladding surrounding the core. The core has an outer radius r.sub.1 in between 20 μm and 30 μm. The cladding includes a first outer cladding region having an outer radius r.sub.4a and a second outer cladding region having an outer radius r.sub.4b less than or equal to 45 μm. The second outer cladding region comprises silica-based glass doped with titania. The optical fiber further includes a primary coating with an outer radius r.sub.5 less than or equal to 80 μm, and a thickness (r.sub.5−r.sub.4) less than or equal to 30 μm. The optical fiber further includes a secondary coating with an outer radius r.sub.6 less than or equal to 100 μm. The secondary coating has a thickness (r.sub.6−r.sub.5) less than or equal to 30 μm, and a normalized puncture load greater than 3.6×10.sup.−3 g/micron.sup.2.

A disclosed multimode optical fiber comprises a core and a cladding surrounding the core. The core has an outer radius r.sub.1 in between 20 μm and 30 μm. The cladding includes a first outer cladding region having an outer radius r.sub.4a and a second outer cladding region having an outer radius r.sub.4b less than or equal to 45 μm. The second outer cladding region comprises silica-based glass doped with titania. The optical fiber further includes a primary coating with an outer radius r.sub.5 less than or equal to 80 μm, and a thickness (r.sub.5−r.sub.4) less than or equal to 30 μm. The optical fiber further includes a secondary coating with an outer radius r.sub.6 less than or equal to 100 μm. The secondary coating has a thickness (r.sub.6−r.sub.5) less than or equal to 30 μm, and a normalized puncture load greater than 3.6×10.sup.−3 g/micron.sup.2.

Provided are a curable composition for imprinting, which contains a polymerizable compound and a polymerization initiator, in which one of components contained in the composition is a compound which includes a 5-membered ring structure having two or more heteroatoms as ring members; a cured substance of the curable composition for imprinting; an imprint pattern producing method using the curable composition for imprinting; and a method for manufacturing a device, which includes the imprint pattern producing method.

Provided are a curable composition for imprinting, which contains a polymerizable compound and a polymerization initiator, in which one of components contained in the composition is a compound which includes a 5-membered ring structure having two or more heteroatoms as ring members; a cured substance of the curable composition for imprinting; an imprint pattern producing method using the curable composition for imprinting; and a method for manufacturing a device, which includes the imprint pattern producing method.

Vinylcyclopropane of general formulae I ##STR00001##
in which X, Y in each case are O or NH, wherein X and Y cannot have the same meaning, R.sup.1 is a linear or branched C.sub.1-C.sub.8-alkyl radical, which can be interrupted by O, S, an ester group or a urethane group, R.sup.2 is a linear or branched C.sub.2-C.sub.10-alkylene radical, which can be interrupted by O, S, an ester group or a urethane group, R.sup.3 is a hydrocarbon radical with 1 to 20 carbon atoms, which additionally can contain one or more N, O or S atoms, and n is 1, 2, 3 or 4, preferably 1 or 2. The vinylcyclopropanes are characterized by a low shrinkage and a high reactivity on radical polymerization and are suitable in particular for the preparation of dental materials.

Vinylcyclopropane of general formulae I ##STR00001##
in which X, Y in each case are O or NH, wherein X and Y cannot have the same meaning, R.sup.1 is a linear or branched C.sub.1-C.sub.8-alkyl radical, which can be interrupted by O, S, an ester group or a urethane group, R.sup.2 is a linear or branched C.sub.2-C.sub.10-alkylene radical, which can be interrupted by O, S, an ester group or a urethane group, R.sup.3 is a hydrocarbon radical with 1 to 20 carbon atoms, which additionally can contain one or more N, O or S atoms, and n is 1, 2, 3 or 4, preferably 1 or 2. The vinylcyclopropanes are characterized by a low shrinkage and a high reactivity on radical polymerization and are suitable in particular for the preparation of dental materials.