The present teachings are directed at 1,1-disubstituted alkene monomers (e.g., methylene beta-ketoester monomers), methods for producing the same, polymerizable compositions including a methylene beta-ketoester monomer, and polymers, compositions and products formed therefrom. The monomer preferably is a high purity monomer. In the method for producing the methylene beta-ketoesters of the invention, a beta-ketoester may be reacted with a source of formaldehyde. The methylene beta-ketoester monomers may be used in monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

Fluorinated photoinitiators and polymerizable compositions including such fluorinated photoinitiators and at least one free-radically polymerizable monomer, oligomer, or mixture thereof. Multilayer films including a substrate and at least a first layer overlaying a surface of the substrate also are described, in which the at least first layer includes a (co)polymer obtained by polymerizing the foregoing polymerizable compositions. Processes for making a multilayer film using the polymerizable composition also are taught. Articles including the multilayer film also are disclosed, in which the article preferably is selected from a photovoltaic device, a display evice, a solid-state lighting device, a sensor, a medical or biological diagnostic device, an electrochromic device, light control device, or a combination thereof.

Fluorinated photoinitiators and polymerizable compositions including such fluorinated photoinitiators and at least one free-radically polymerizable monomer, oligomer, or mixture thereof. Multilayer films including a substrate and at least a first layer overlaying a surface of the substrate also are described, in which the at least first layer includes a (co)polymer obtained by polymerizing the foregoing polymerizable compositions. Processes for making a multilayer film using the polymerizable composition also are taught. Articles including the multilayer film also are disclosed, in which the article preferably is selected from a photovoltaic device, a display evice, a solid-state lighting device, a sensor, a medical or biological diagnostic device, an electrochromic device, light control device, or a combination thereof.

The present invention relates to a resin composition that comprises an acetoacetate ester compound with at least two acetoacetate ester functional groups, an acrylate compound with at least two acrylate functional groups, and a tertiary amine curing catalyst. This resin composition acts as an isocyanate-free binder that is less toxic to the environment. The invention further discloses a method for preparation fiber reinforced parts comprising fibers and said resin composition as well as a method for the preparation of foundry molds for the casting industry, which is based on said binder.

The present invention relates to a resin composition that comprises an acetoacetate ester compound with at least two acetoacetate ester functional groups, an acrylate compound with at least two acrylate functional groups, and a tertiary amine curing catalyst. This resin composition acts as an isocyanate-free binder that is less toxic to the environment. The invention further discloses a method for preparation fiber reinforced parts comprising fibers and said resin composition as well as a method for the preparation of foundry molds for the casting industry, which is based on said binder.

The present invention relates to a curable composition for a glass substitute. By using a curable composition, excellent wear resistance and high hardness at a glass level can be obtained, and two-dimensional planar plastic film and three-dimensional plastic film without cracks or curls can be provided. The plastic films can be a substitute for existing glass, thereby enabling manufacturing of various electronic products, such as a display and the like, which are light and will not be easily damaged by external pressure.

The present invention relates to a curable composition for a glass substitute. By using a curable composition, excellent wear resistance and high hardness at a glass level can be obtained, and two-dimensional planar plastic film and three-dimensional plastic film without cracks or curls can be provided. The plastic films can be a substitute for existing glass, thereby enabling manufacturing of various electronic products, such as a display and the like, which are light and will not be easily damaged by external pressure.

Compounds of formula (I) are photoinitiators or photosensitizers in a photopolymerizable composition:

##STR00001##

R.sub.1 represents a monovalent, linear, branched or cyclic, aliphatic hydrocarbon group having 1 to 20 carbon atoms, optionally substituted with substituent(s) selected from —Cl, —Br, —OH, ═O, —NH—CO—OR.sub.2, —NH—CO—R.sub.2 or free-radically or ionically polymerizable groups. Each R.sub.2 is independently —H or C.sub.1-6 alkyl; n is ≥1. If n=1, Z and Y are absent and X represents —OR.sub.3; if n is >1, Z represents —OR.sub.4—, Y represents —OR.sub.5— and X represents —H or —OH. R.sub.3 represents —H or R.sub.1; and R.sub.4 and R.sub.5 each independently represent a bivalent hydrocarbon group. The polymerizable moieties as optional substituents of R.sub.1 are polymerizable double or triple bonds, lactam, lactone and epoxide moieties, which are subjectable to ring-opening polymerization; and two of R.sub.1 to R.sub.5 may be linked to one another to form a ring or a dimer.

Compounds of formula (I) are photoinitiators or photosensitizers in a photopolymerizable composition:

##STR00001##

R.sub.1 represents a monovalent, linear, branched or cyclic, aliphatic hydrocarbon group having 1 to 20 carbon atoms, optionally substituted with substituent(s) selected from —Cl, —Br, —OH, ═O, —NH—CO—OR.sub.2, —NH—CO—R.sub.2 or free-radically or ionically polymerizable groups. Each R.sub.2 is independently —H or C.sub.1-6 alkyl; n is ≥1. If n=1, Z and Y are absent and X represents —OR.sub.3; if n is >1, Z represents —OR.sub.4—, Y represents —OR.sub.5— and X represents —H or —OH. R.sub.3 represents —H or R.sub.1; and R.sub.4 and R.sub.5 each independently represent a bivalent hydrocarbon group. The polymerizable moieties as optional substituents of R.sub.1 are polymerizable double or triple bonds, lactam, lactone and epoxide moieties, which are subjectable to ring-opening polymerization; and two of R.sub.1 to R.sub.5 may be linked to one another to form a ring or a dimer.

According to the present invention, as a monomer which is unlikely to be crystallized in a curable composition for manufacturing an optical member and which enables manufacture of a cured product having a high level of moisture-heat resistance, a compound represented by General Formula (A) is provided. ##STR00001## In the formula, Ar.sup.11 and Ar.sup.12 each independently represent an aryl group or a heteroaryl group; X.sup.1, Y.sup.1, X.sup.2, Y.sup.2, Z.sup.1, and Z.sup.2 each independently represent a nitrogen atom or a carbon atom, or the like; Ar.sup.13 and Ar.sup.14 each independently represent an arylene group or a heteroarylene group, where at least one of Ar.sup.13 or Ar.sup.14 is a group other than a phenylene group; R.sup.3 to R.sup.6 each independently represent a substituent, q and r each independently are an integer of 0 to 4, and v and w each independently are an integer of 0 or more; L.sup.1 and L.sup.2 each independently represent a single bond, an oxygen atom, an ester bond, or the like; R.sup.11 and R.sup.12 each independently represent a divalent linking group containing a branched alkylene group; and R.sup.21 and R.sup.22 each independently represent a hydrogen atom or a methyl group.