Water-soluble films, water-soluble unit dose articles, and related methods of making and using the same.

Water-soluble films, water-soluble unit dose articles, and related methods of making and using the same.

Disclosed herein are coating compositions and/or coatings comprising a water-soluble resin mixture comprising a polyvinyl alcohol (PVOH) and a polyacrylic acid (PAA), and further comprising a colorant and/or an aversive agent, surfaces of substrates coated with the compositions, and methods of making and using the same.

Disclosed herein are coating compositions and/or coatings comprising a water-soluble resin mixture comprising a polyvinyl alcohol (PVOH) and a polyacrylic acid (PAA), and further comprising a colorant and/or an aversive agent, surfaces of substrates coated with the compositions, and methods of making and using the same.

An object of the present invention is to provide a PVA-based resin having a degree of saponification obtained in the middle stage of the reaction, that is, an average degree of saponification of 68 mol % to 85 mol %, a narrow degree of saponification distribution, and excellent dispersion stability. The present invention relates to a polyvinyl alcohol-based resin having an average degree of saponification of 68 mol % to 85 mol %, and a ¼ value width of 7.0 minutes or less in a degree of saponification distribution obtained by high performance liquid chromatogram measured under specific conditions.

An object of the present invention is to provide a PVA-based resin having a degree of saponification obtained in the middle stage of the reaction, that is, an average degree of saponification of 68 mol % to 85 mol %, a narrow degree of saponification distribution, and excellent dispersion stability. The present invention relates to a polyvinyl alcohol-based resin having an average degree of saponification of 68 mol % to 85 mol %, and a ¼ value width of 7.0 minutes or less in a degree of saponification distribution obtained by high performance liquid chromatogram measured under specific conditions.

The invention describes a method for the manufacture of a plasticized polyvinyl alcohol polymer mixture including the steps of introducing a polyvinyl alcohol or a blend thereof having a degree of hydrolysis in the range of 93% to 98% or more into a mixing reactor; adding a processing agent, and a plasticizer to form a reaction mixture; wherein the plasticizer is selected from the group consisting of the following compounds and mixtures thereof: (a) sugar alcohols selected from the group consisting of: diglycerol, triglycerol, fructose, ribose, xylose, D-mannitol, triacetin, and mixtures thereof; polyols selected from the group consisting of: pentaerythritol, dipentaerythritol, and mixtures thereof; (b) diols selected from the group consisting of: methyl pentanediol, 1,2-propanediol, 1,4-butanediol, 2-hydroxy-1,3-propanediol, 3-methyl-1,3-butanediol, 3,3-dimethyl-1,2-butanediol, and mixtures thereof; (c) glycols selected from the group consisting of: polyethylene glycol 300, polyethylene glycol 400, alkoxylated polyethylene glycol, and mixtures thereof; (d) caprolactam, tricyclic trimethylolpropane formal, rosin esters, euricamide, and mixtures thereof; reacting the reaction mixture in a reaction zone to form plasticized polymer; and allowing the plasticized polymer to pass from the reaction zone.

The invention describes a method for the manufacture of a plasticized polyvinyl alcohol polymer mixture including the steps of introducing a polyvinyl alcohol or a blend thereof having a degree of hydrolysis in the range of 93% to 98% or more into a mixing reactor; adding a processing agent, and a plasticizer to form a reaction mixture; wherein the plasticizer is selected from the group consisting of the following compounds and mixtures thereof: (a) sugar alcohols selected from the group consisting of: diglycerol, triglycerol, fructose, ribose, xylose, D-mannitol, triacetin, and mixtures thereof; polyols selected from the group consisting of: pentaerythritol, dipentaerythritol, and mixtures thereof; (b) diols selected from the group consisting of: methyl pentanediol, 1,2-propanediol, 1,4-butanediol, 2-hydroxy-1,3-propanediol, 3-methyl-1,3-butanediol, 3,3-dimethyl-1,2-butanediol, and mixtures thereof; (c) glycols selected from the group consisting of: polyethylene glycol 300, polyethylene glycol 400, alkoxylated polyethylene glycol, and mixtures thereof; (d) caprolactam, tricyclic trimethylolpropane formal, rosin esters, euricamide, and mixtures thereof; reacting the reaction mixture in a reaction zone to form plasticized polymer; and allowing the plasticized polymer to pass from the reaction zone.

A method for the manufacture of a plasticized polyvinyl alcohol polymer mixture comprising the steps of: introducing into a mixing reactor a polyvinyl alcohol polymer comprising homopolymeric polyvinyl alcohol or a blend thereof having a degree of hydrolysis in the range of 93% to 98% or more; wherein the mixing reactor comprises a blending chamber having a primary inlet, a primary outlet and at least two inter-engaging components extending between the primary inlet and primary outlet, the components being arranged to apply a shearing force to the polymer while the polymer is conveyed by the components from the inlet through a reaction zone to the outlet; one or more secondary inlets located downstream from the primary inlet for introducing reactants comprising a processing aid and a plasticizer to the chamber to form a reaction mixture; wherein the plasticizer is selected from the group consisting of the following compounds and mixtures thereof: (a) sugar alcohols selected from the group consisting of: diglycerol, triglycerol, fructose, ribose, xylose, D-mannitol, triacetin, and mixtures thereof; polyols selected from the group consisting of: pentaerythritol, dipentaerythritol, and mixtures thereof; (b) diols selected from the group consisting of: methyl pentanediol, 1,2-propanediol, 1,4-butanediol, 2-hydroxy-1,3-propanediol, 3-methyl-1,3-butanediol, 3,3-dimethyl-1,2-butanediol, and mixtures thereof; (c) glycols selected from the group consisting of: polyethylene glycol 300, polyethylene glycol 400, alkoxylated polyethylene glycol, and mixtures thereof; (d) caprolactam, tricyclic trimethylolpropane formal, rosin esters, euricamide, and mixtures thereof; wherein the blending chamber comprises a plurality of heated regions arranged so that the mixture is subjected to a temperature profile whereby the temperature increases from the inlet to the outlet; a secondary outlet located between the reaction zone and primary outlet arranged to allow removal of processing aid from the chamber; reacting the processing agent, plasticizer and polymer in the reaction zone to form plasticized polymer; and
allowing the plasticized polymer to pass from the primary outlet.

A method for the manufacture of a plasticized polyvinyl alcohol polymer mixture comprising the steps of: introducing into a mixing reactor a polyvinyl alcohol polymer comprising homopolymeric polyvinyl alcohol or a blend thereof having a degree of hydrolysis in the range of 93% to 98% or more; wherein the mixing reactor comprises a blending chamber having a primary inlet, a primary outlet and at least two inter-engaging components extending between the primary inlet and primary outlet, the components being arranged to apply a shearing force to the polymer while the polymer is conveyed by the components from the inlet through a reaction zone to the outlet; one or more secondary inlets located downstream from the primary inlet for introducing reactants comprising a processing aid and a plasticizer to the chamber to form a reaction mixture; wherein the plasticizer is selected from the group consisting of the following compounds and mixtures thereof: (a) sugar alcohols selected from the group consisting of: diglycerol, triglycerol, fructose, ribose, xylose, D-mannitol, triacetin, and mixtures thereof; polyols selected from the group consisting of: pentaerythritol, dipentaerythritol, and mixtures thereof; (b) diols selected from the group consisting of: methyl pentanediol, 1,2-propanediol, 1,4-butanediol, 2-hydroxy-1,3-propanediol, 3-methyl-1,3-butanediol, 3,3-dimethyl-1,2-butanediol, and mixtures thereof; (c) glycols selected from the group consisting of: polyethylene glycol 300, polyethylene glycol 400, alkoxylated polyethylene glycol, and mixtures thereof; (d) caprolactam, tricyclic trimethylolpropane formal, rosin esters, euricamide, and mixtures thereof; wherein the blending chamber comprises a plurality of heated regions arranged so that the mixture is subjected to a temperature profile whereby the temperature increases from the inlet to the outlet; a secondary outlet located between the reaction zone and primary outlet arranged to allow removal of processing aid from the chamber; reacting the processing agent, plasticizer and polymer in the reaction zone to form plasticized polymer; and
allowing the plasticized polymer to pass from the primary outlet.