Provided is a method of preparing a vinyl chloride-vinyl acetate copolymer latex.

Specifically, in one embodiment of the present invention, provided is a method of preparing a latex including vinyl chloride-vinyl acetate copolymer particles with a high degree of polymerization and molecular weight and a uniform particle composition by performing an emulsion polymerization of a vinyl chloride monomer and a vinyl acetate monomer in the presence of an aqueous dispersion medium and an emulsifier while optimizing a feeding mode of the vinyl chloride monomer and the emulsifier.

Provided is a method of preparing a vinyl chloride-vinyl acetate copolymer latex.

Specifically, in one embodiment of the present invention, provided is a method of preparing a latex including vinyl chloride-vinyl acetate copolymer particles with a high degree of polymerization and molecular weight and a uniform particle composition by performing an emulsion polymerization of a vinyl chloride monomer and a vinyl acetate monomer in the presence of an aqueous dispersion medium and an emulsifier while optimizing a feeding mode of the vinyl chloride monomer and the emulsifier.

Provided is a method of preparing a vinyl chloride-vinyl acetate copolymer latex.

Specifically, in one embodiment of the present invention, provided is a method of preparing a latex including vinyl chloride-vinyl acetate copolymer particles with a high degree of polymerization and molecular weight and a uniform particle composition by performing an emulsion polymerization of a vinyl chloride monomer and a vinyl acetate monomer in the presence of an aqueous dispersion medium and an emulsifier while optimizing a feeding mode of the vinyl chloride monomer and the emulsifier.

The present disclosure generally related to photopolymerizable liquid compositions containing hybridized graft copolymers, reactive diluents and optionally oligomers, photoinitiators, colorants and other additives.

A method for producing a water/oil repellent composition can produce an article which is excellent in the oil repellency while maintaining the water repellency and the heavy-rain durability. The method includes mixing an emulsion of a polymer having from 10 to 50 mass % of units based on a monomer having a perfluoroalkyl group per all units and an emulsion of a monomer component containing at least 80 mass % of a monomer having a perfluoroalkyl group so that the proportion of the mass of the polymer will be from 50 to 99 mass % per the sum of the mass of the polymer and the total mass of the monomer component and then polymerizing the monomer component. The monomer component includes emulsified particles in the emulsion of the monomer component. The emulsified particles have an average particle size of from 50 to 600 nm.

A method for producing a water/oil repellent composition can produce an article which is excellent in the oil repellency while maintaining the water repellency and the heavy-rain durability. The method includes mixing an emulsion of a polymer having from 10 to 50 mass % of units based on a monomer having a perfluoroalkyl group per all units and an emulsion of a monomer component containing at least 80 mass % of a monomer having a perfluoroalkyl group so that the proportion of the mass of the polymer will be from 50 to 99 mass % per the sum of the mass of the polymer and the total mass of the monomer component and then polymerizing the monomer component. The monomer component includes emulsified particles in the emulsion of the monomer component. The emulsified particles have an average particle size of from 50 to 600 nm.

A composition containing: modified polyvinyl alcohol; and unsaturated monocarboxylic acid or a salt thereof, wherein the modified polyvinyl alcohol has a viscosity-average degree of polymerization of from 400 to 3500, has a degree of saponification of from 68 mol % to 99.9 mol %, and contains from 0.01 mol % to 1.50 mol % of an acryloyl group or a methacryloyl group in a side chain, the unsaturated monocarboxylic acid or a salt thereof is at least one selected from the group consisting of acrylic acid, methacrylic acid, sodium acrylate, and sodium methacrylate, and in the composition, a mass ratio of the modified polyvinyl alcohol/the unsaturated monocarboxylic acid or a salt thereof is from 82/18 to 99.9/0.1. The composition is thus provided that is excellent in water solubility and storage stability and polymerization stability of a vinyl compound and contains the modified polyvinyl alcohol.

A composition containing: modified polyvinyl alcohol; and unsaturated monocarboxylic acid or a salt thereof, wherein the modified polyvinyl alcohol has a viscosity-average degree of polymerization of from 400 to 3500, has a degree of saponification of from 68 mol % to 99.9 mol %, and contains from 0.01 mol % to 1.50 mol % of an acryloyl group or a methacryloyl group in a side chain, the unsaturated monocarboxylic acid or a salt thereof is at least one selected from the group consisting of acrylic acid, methacrylic acid, sodium acrylate, and sodium methacrylate, and in the composition, a mass ratio of the modified polyvinyl alcohol/the unsaturated monocarboxylic acid or a salt thereof is from 82/18 to 99.9/0.1. The composition is thus provided that is excellent in water solubility and storage stability and polymerization stability of a vinyl compound and contains the modified polyvinyl alcohol.

Composition comprising at least one vinyl halide polymer and 0.1 to 5% by weight, relative to the weight of the vinyl halide polymer, of at least one polymer of at least one acrylic ester obtained by polymerization in solution in a liquid medium comprising at least one chain transfer agent chosen among the C.sub.3-C.sub.20 hydrocarbons containing at least one secondary alcohol function. Process for its manufacture, article obtained starting from this composition and use of this composition for manufacturing sheets and films via calendaring or for manufacturing profiles by extrusion. Process for the manufacture of a polymer of at least one acrylic ester which can be used in the composition.

Composition comprising at least one vinyl halide polymer and 0.1 to 5% by weight, relative to the weight of the vinyl halide polymer, of at least one polymer of at least one acrylic ester obtained by polymerization in solution in a liquid medium comprising at least one chain transfer agent chosen among the C.sub.3-C.sub.20 hydrocarbons containing at least one secondary alcohol function. Process for its manufacture, article obtained starting from this composition and use of this composition for manufacturing sheets and films via calendaring or for manufacturing profiles by extrusion. Process for the manufacture of a polymer of at least one acrylic ester which can be used in the composition.