The present invention relates to a fluorosurfactant-free emulsion polymerization method for the synthesis of a fluoropolymer, more in particular of a VDF-based polymer.

The invention provides novel latexes of particles of vinylidene fluoride/trifluoroethylene copolymers possessing a more ordered ferroelectric crystalline phase, and hence improved ferro-, pyro-, and piezo-electric properties, and a method for manufacturing the same by emulsion polymerization in the presence of certain cyclic fluorosurfactants.

An object is to provide a fluorine-containing copolymer composition that exhibits long-term stability as well as a fluororesin paint or varnish prepared using the composition.

Provided are: a composition comprising a fluorine-containing copolymer synthesized through copolymerization of 0.001 to 50 mol % of particular ethylenically unsaturated organosilicon compound polymerization units relative to 5 to 85 mol % of fluoroolefin polymerization units by a solution polymerization method, a solvent, and an amine compound; a fluororesin paint or varnish prepared using the composition; and a method of producing the fluorine-containing copolymer composition.

The present invention pertains to a non-linear, copolymer comprising recurring units derived from vinylidene fluoride (VDF) monomer, at least one functional comonomer and optionally at least one fluorinated ethylenic comonomer. The non-linear fluorinated copolymer comprises from 0.01 to 3.0% by moles of recurring units derived from functional comonomer. The non-linear fluorinated copolymer can be used as electrode binder in batteries.

The present invention pertains to a non-linear, copolymer comprising recurring units derived from vinylidene fluoride (VDF) monomer, at least one functional comonomer and optionally at least one fluorinated ethylenic comonomer. The non-linear fluorinated copolymer comprises from 0.01 to 3.0% by moles of recurring units derived from functional comonomer. The non-linear fluorinated copolymer can be used as electrode binder in batteries.

Provided is a binder for a battery, including a fluorine-containing copolymer, wherein the fluorine-containing copolymer comprises a repeating unit (a) based on vinylidene fluoride and at least one repeating unit (b) selected from the group consisting of a repeating unit (bl) represented by a specific structural formula (bl) and a repeating unit (b2) represented by a structural formula (b2), and the fluorine-containing copolymer has a molar ratio of the repeating unit (a) to the repeating unit (b), (a)/(b), of 95/5 to 5/95.

Provided is a binder for a battery, including a fluorine-containing copolymer, wherein the fluorine-containing copolymer comprises a repeating unit (a) based on vinylidene fluoride and at least one repeating unit (b) selected from the group consisting of a repeating unit (bl) represented by a specific structural formula (bl) and a repeating unit (b2) represented by a structural formula (b2), and the fluorine-containing copolymer has a molar ratio of the repeating unit (a) to the repeating unit (b), (a)/(b), of 95/5 to 5/95.

The present invention pertains to a fluoropolymer film comprising at least one fluoropolymer hybrid organic/inorganic composite [polymer (FH)], to a process for the manufacture of said fluoropolymer film and to uses of said fluoropolymer film in various applications, in particular in electrochemical applications.

Provided are a structure for non-aqueous electrolyte secondary batteries in which at least one of a cathode with a separator and an anode with a separator are strongly adhered, an aqueous latex used to obtain the structure for non-aqueous electrolyte secondary batteries, and a separator/intermediate layer laminate.

The aqueous latex according to the present invention contains polymer particles dispersed in water, the polymer particles containing a copolymer comprising a structural unit derived from an unsaturated dibasic acid, and/or a structural unit derived from an unsaturated dibasic acid monoester, and a structural unit derived from a vinylidene fluoride-based monomer, the aqueous latex being used in production of an intermediate layer to be provided in a structure for non-aqueous electrolyte secondary batteries having a cathode, an anode, and a separator laminated between the cathode and the anode, the intermediate layer being provided in at least one of between the cathode and the separator and between the anode and the separator.

An object of the present invention it to provide a novel fluororesin that has excellent mechanical strength and chemical resistance, and very low permeability at high temperature. The fluorine resin is a copolymer that includes copolymerized units derived from tetrafluoroethylene, vinylidene fluoride, and an ethylenically unsaturated monomer other than tetrafluoroethylene and vinylidene fluoride. The fluororesin has a storage modulus E′, as measured at 170° C. by a dynamic viscoelasticity analysis, in the range of 60 to 400 MPa.