The present invention pertains to a membrane for an electrochemical device, to a process for manufacturing said membrane and to use of said membrane in a process for manufacturing an electrochemical device.

The present invention pertains to a process for the manufacture of a dense film. The process includes processing, in a molten phase, a solid composition [composition (C)] comprising; at least one vinylidene fluoride (VDF) fluoropolymer comprising one or more carboxylic acid functional end groups [polymer (F)], at least one poly(alkylene oxide) (PAO) of formula (I):
HO—(CH.sub.2CHR.sub.AO).sub.n—R.sub.B  (I) wherein R.sub.A is a hydrogen atom or a C.sub.1-C.sub.5 alkyl group, R.sub.B is a hydrogen atom or a —CH.sub.3 alkyl group and n is an integer comprised between 2000 and 40000, preferably between 4000 and 35000, more preferably between 11500 and 30000, and -optionally, at least one inorganic filler [filler (I)]; thereby providing a dense film having a thickness of from 5 μm to 30 μm. The present invention also pertains to the dense film provided by this process and to the use of the dense film as dense separator in electrochemical devices.

The present invention pertains to a membrane for an electrochemical device, to a process for manufacturing said membrane and to use of said membrane in a process for manufacturing an electrochemical device.

The present invention pertains to vinylidene fluoride copolymers comprising recurring units derived from hydrophilic (meth)acrylic monomers and from perfluoroalkylvinylether monomers having improved flexibility, to films made thereof and to processes for the manufacture of these films.

The present invention pertains to vinylidene fluoride copolymers having improved flexibility, said copolymers comprising recurring units derived from hydrophilic (meth)acrylic monomers and from perhalogenated monomers, to a process for the manufacture of said copolymers, and to their use in applications where outstanding flexibility is required.

The invention pertains to a process for manufacturing a fluoropolymer hybrid organic/inorganic composite, to fluoropolymer hybrid organic/inorganic composites obtained therefrom and to the use of the same in several fields of use.

The invention pertains to a process for manufacturing a fluoropolymer hybrid organic/inorganic composite, to fluoropolymer hybrid organic/inorganic composites obtained therefrom and to the use of the same in several fields of use.

Provided is a vinylidene fluoride copolymer particle which is capable of efficiently exhibiting high adhesion between an electrode and a separator. The vinylidene fluoride copolymer particle of the present invention comprises vinylidene fluoride; and a compound having an oxygen atom-containing functional group; wherein a ratio of oxygen atom in a surface of the vinylidene fluoride copolymer particle is higher than a ratio of oxygen atom in the vinylidene fluoride copolymer particle other than the surface thereof.

Provided is a vinylidene fluoride copolymer particle which is capable of efficiently exhibiting high adhesion between an electrode and a separator. The vinylidene fluoride copolymer particle of the present invention comprises vinylidene fluoride; and a compound having an oxygen atom-containing functional group; wherein a ratio of oxygen atom in a surface of the vinylidene fluoride copolymer particle is higher than a ratio of oxygen atom in the vinylidene fluoride copolymer particle other than the surface thereof.

The invention pertains to a fluoroelastomer composition comprising: (a) a vinylidene fluoride-based fluoroelastomer [fluoroelastomer (A)] comprising recurring units derived from vinylidene fluoride (VDF) and recurring units derived from at least one additional (per)fluorinated monomer; said fluoroelastomer (A): —possessing a polydispersity index (IMWD) of between 1.5 and 3.5, —comprising an amount of polar end groups of formula —CF.sub.2CH.sub.2OH of at least 3 mmol/kg and at most 6 mmol/kg, and —further comprising end of chain groups of formula —CF.sub.2H, —CF.sub.2CH.sub.3, and, optionally, —OC(o)—R.sub.H (with R.sub.H being a C.sub.1-C.sub.6 alkyl group) in an amount such to satisfy the following inequality: [—CF.sub.2CH.sub.2OH]+[—CF.sub.2H]+[—CF.sub.2CH.sub.3H—OC(o)R.sub.H]≤30+(2×10.sup.6)/M.sub.n, (b) at least one polyhydroxylated curing agent; (c) at least one accelerant; (d) at least one metal oxide selected from the group consisting of divalent metal oxides; and (e) optionally, at least one metal hydroxide, wherein the amount of said metal hydroxide, if present, is below 3 phr, based on 100 weight parts of fluoroelastomer (A).