A method for producing a fluoropolymer, which includes polymerizing a fluoromonomer in a solvent to produce the fluoropolymer. The solvent contains a fluorine-containing ether compound (1) represented by

formula:R.sup.1—O—R.sup.2

wherein R.sup.1 represents a partially fluorinated alkyl group, and R.sup.2 represents a non-fluorinated alkyl group, a partially fluorinated alkyl group, or a completely fluorinated alkyl group, and in the solvent, a content of a fluorine-containing olefin compound (2) represented by

formula:R.sup.3—CF═CF—R.sup.4—O—R.sup.2

wherein R.sup.3 represents H, F, a partially fluorinated alkyl group, or a completely fluorinated alkyl group, R.sup.4 represents a single bond, a partially fluorinated alkylene group, or a completely fluorinated alkylene group, and R.sup.2 is the same as described above, is 1.00% by mass or less based on a content of the fluorine-containing ether compound (1), and wherein the fluoromonomer is selected from tetrafluoroethylene, chlorotrifluoroethylene, and vinylidene fluoride.

To provide a powder coating material capable of forming a coating film excellent in impact resistance, flexibility and adhesion to substrate and excellent in surface smoothness even when formed under low temperature film-forming conditions. The powder coating material of the present invention is a powder coating material comprising a fluorinated polymer having units based on a fluoroolefin, units based on a monomer represented by the formula X—Z and units based on a monomer represented by the formula CHR.sup.21═CR.sup.22 (CH.sub.2).sub.nCOOH, wherein the content of the units based on a monomer represented by the formula X—Z is from 5 to 20 mol % to all units in the fluorinated polymer, and the fluorinated polymer has a melt viscosity at 170° C. of from 20 to 100 Pa.Math.s (in the formulae, X is a specific monovalent polymerizable group, Z is a specific alkyl group, a specific cycloalkyl group or a specific aryl group, R.sup.21 and R.sup.22 are each independently a hydrogen atom or a specific alkyl group, and n is an integer of from 0 to 12.

Disclosed are copolymers formed by copolymerization of: (1) one or more hydrofluoroolefin monomer(s) selected from the group consisting of hydrofluoroethylenes, hydrofluoropropenes, hydrofluorobutenes, hydrofluoropentenes and combinations of these, and preferably selected from 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene, with said 1,3,3,3-tetrafluoropropene preferably comprising, consisting essentially of or consisting of trans-1,3,3,3-tetrafluoropropene, and combinations of these, and (2) one or more chlorofluoroethylene monomers, preferably chlorotrifluoroethylene (“CTFE”) monomers, wherein the mole ratio of monomer (1) to monomer (2) is preferably from about 30:1 to about 1:30.

A curable composition containing at least one of a haloalkyl ether (meth)acrylate or a haloalkenyl ether (meth)acrylate and, optionally, one or more different types of co-monomers is cured to provide a polymer having advantageous properties as a result of the incorporation of halogenated functionality derived from the haloalkyl/haloalkenyl ether (meth)acrylate monomer.

Provided is an ECTFE resin composition that is superior in transparency and resistant to yellowing for an extended period of time. The ECTFE resin composition generates a smaller amount of acidic gases, for example, when it is extrusion molded at high temperature. It is an ethylene-chlorotrifluoroethylene copolymer resin composition including a bisphenol-based antioxidant. It is preferably an ethylene-chlorotrifluoroethylene copolymer resin composition additionally including a phosphorus-based antioxidant.

A powder coating material capable of forming a coating film that is excellent in weather resistance, processability and impact resistance and that improves corrosion resistance of a substrate (in particular, a substrate made of aluminum or of an aluminum alloy), wherein the powder coating material contains a powder of a resin composition, wherein the resin composition contains a fluorinated polymer (A) having a number average molecular weight of from 10,000 to 50,000 and a fluorine content of at least 10 mass %, a resin (B) having a fluorine content of less than 10 mass % or containing no fluorine atom, a curing agent, a plasticizer having a melting point of from 50 to 150 C. and core-shell particles, and wherein the absolute value of the difference between the melting point of the plasticizer and the glass transition temperature of a polymer of a shell portion in the core-shell particles is within 30 C. and the content of the plasticizer is from 5 to 25 parts by mass based on 100 parts by mass of the fluorinated polymer (A).

The present invention relates to a fluid-system component comprising a thermoplastic polymeric composition, said composition comprising one or more semi crystalline polymer, said semi crystalline polymer comprising recurring units derived from ethylene (E) and at least one of chlorotrifluoroethylene (CTFE) and tetrafluoroethylene (TFE); said semi crystalline polymer having a heat of fusion of less than 35 J/g [polymer (A)], and wherein said thermoplastic polymeric composition when subject to the extraction test described herein has a leeching of less than 50 ppb preferably less than 10 ppb for each of Ca, Fe, K, Na, Zn, Ti, Sn, Ce, Cu, Zr, Bi, Si, Al, Sb.

The invention pertains to a multilayer assembly comprising: (L1) a first inner layer [layer (L1)] made from a first composition [composition (C1)], said composition (C1) comprising: at least one polymer comprising recurring units derived from ethylene (E) and from chlorotrifluoroethylene (CTFE), and at least one Ti compound; and (L2) a second outer layer [layer (L2)] made from a second composition [composition (C2)], said composition (C2) being substantially free from TiO.sub.2-containing additives, said second composition comprising at least one semi-crystalline polymer comprising recurring units derived from ethylene and from at least one fluoromonomer selected from chlorotrifluoroethylene (CTFE), tetrafluoroethylene (TFE) and mixtures thereof, said semi-crystalline polymer having a heat of fusion of at least 35 J/g [polymer (A)].

To provide a powder coating material capable of forming a coating film excellent in impact resistance, flexibility and adhesion to substrate and excellent in surface smoothness even when formed under low temperature film-forming conditions.

The powder coating material of the present invention is a powder coating material comprising a fluorinated polymer having units based on a fluoroolefin, units based on a monomer represented by the formula XZ and units based on a monomer represented by the formula CHR.sup.21CR.sup.22 (CH.sub.2).sub.nCOOH, wherein the content of the units based on a monomer represented by the formula XZ is from 5 to 20 mol % to all units in the fluorinated polymer, and the fluorinated polymer has a melt viscosity at 170 C. of from 20 to 100 Pa.Math.s (in the formulae, X is a specific monovalent polymerizable group, Z is a specific alkyl group, a specific cycloalkyl group or a specific aryl group, R.sup.21 and R.sup.22 are each independently a hydrogen atom or a specific alkyl group, and n is an integer of from 0 to 12.

In some aspects, polymeric yarns and communications cables incorporating the same are provided herein. Additionally, in some aspects, methods of producing polymeric yarns and communications cables incorporating the same are provided.