To provide a powder dispersion comprising a tetrafluoroethylene polymer, a particular polyoxyalkylene-modified polydimethylsiloxane and a liquid dispersion medium, and a composite having a baked product having physical properties intrinsic to the tetrafluoroethylene polymer. [Solution] The powder dispersion of the present invention comprises a powder of a tetrafluorethylene polymer, a liquid dispersion medium and a polyoxyalkylene-modified polydimethylsiloxane having a weight average molecular weight of at most 3,000 and an HLB value of from 1 to 18 calculated by Griffin's equation The composite of the present invention is produced by applying the powder dispersion of the present invention to the surface of a substrate and heating the powder dispersion.

This disclosure provides a fluorine-containing mixture and a fluorine-containing super-oleophobic microporous membrane using the fluorine-containing mixture as a raw material, as well as preparation methods and applications for the fluorine-containing mixture and the fluorine-containing super-oleophobic microporous membrane. The fluorine-containing mixture of the present disclosure comprises, by weight percentage, the following components: Component A: 50%˜90%; Component B: 3%˜25%; Component C: 0%˜35%; Component D: 0%˜3%; wherein Component A comprises high molecular weight polytetrafluoroethylene homopolymer or copolymer dispersion resin; Component B comprises one or more fluorine-containing alkyl acrylate monomers; Component C comprises one or more fluorine-free acrylates; Component D comprises high temperature free radical initiator. There's no need to add inflammable or explosive lubricating oil, making the process highly safe; and the obtained fluorine-containing super-oleophobic microporous membrane has high waterproof, air-permeable, oil-resistant and washable performance, in line with the needs of a new generation of waterproof and air-permeable protective clothing.

An elastomeric fluoropolymer includes the following monomer units: about 45 mol % to about 65 mol % —CF.sub.2—CH.sub.2—; about 8 mol % to about 30 mol % —CF.sub.2—CF.sub.2—; about 4.5 mol % to about 25 mol % —CF.sub.2—CF(O—CF.sub.3)—; and about 6 mol % to about 20 mol % —CF.sub.2—CF(O—CF.sub.2—CF.sub.2—O—(CF.sub.2—O).sub.n—CF.sub.3)—, where n is 1 or 2. In some embodiments, a composition includes an elastomeric fluoropolymer and at least one additive. In some embodiments, a composition includes a first elastomeric fluoropolymer and a second elastomeric fluoropolymer blended with the first elastomeric fluoropolymer. The first elastomeric fluoropolymer includes the following monomer units: about 45 mol % to about 65 mol % —CF.sub.2—CH.sub.2—; about 8 mol % to about 30 mol % —CF.sub.2—CF.sub.2—; about 4.5 mol % to about 25 mol % —CF.sub.2—CF(O—CF.sub.3)—; and about 6 mol % to about 20 mol % —CF.sub.2—CF(O—CF.sub.2—CF.sub.2—O—(CF.sub.2—O).sub.n—CF.sub.3)—, where n is 1 or 2.

A resin composition containing: a melt-fabricable fluororesin containing at least one functional group selected from a carbonyl group-containing group and a hydroxy group; at least one fluorine-free resin selected from a liquid crystal polymer, a polyarylene sulfide, and an aromatic polyether ketone; and particulate boron nitride, wherein the particulate boron nitride is contained in an amount of 30 to 65% by volume.

An electric wire for an in-vehicle network cable, including a conductor and a covering that covers a periphery of the conductor. The electric wire has a diameter of 0.5 to 1.5 mm. The covering contains a fluororesin that is a tetrafluoroethylene/hexafluoropropylene/perfluoro(alkyl vinyl ether) copolymer. The fluororesin has a melt flow rate of 20 to 40 g/10 min measured at 372° C. under a 5-kg load, a relative permittivity of 2.2 or lower measured at 25° C. and 6 GHz, a melting point of 250° C. or higher, an MIT folding endurance of 2000 times or more, and a tensile elongation at 150° C. of 300% or higher. Also disclosed is an in-vehicle network cable including the electric wire and an in-vehicle network cable including a twisted pair of electric wires, at least one of which is the above-described electric wire for an in-vehicle network cable.

An electric wire for an in-vehicle network cable, including a conductor and a covering that covers a periphery of the conductor. The electric wire has a diameter of 0.5 to 1.5 mm. The covering contains a fluororesin that is a tetrafluoroethylene/hexafluoropropylene/perfluoro(alkyl vinyl ether) copolymer. The fluororesin has a melt flow rate of 20 to 40 g/10 min measured at 372° C. under a 5-kg load, a relative permittivity of 2.2 or lower measured at 25° C. and 6 GHz, a melting point of 250° C. or higher, an MIT folding endurance of 2000 times or more, and a tensile elongation at 150° C. of 300% or higher. Also disclosed is an in-vehicle network cable including the electric wire and an in-vehicle network cable including a twisted pair of electric wires, at least one of which is the above-described electric wire for an in-vehicle network cable.

To provide a method for producing a fluorinated polymer which does not require an emulsifier as an essential component while an aqueous medium with little environmental burden is used. A method for producing a fluorinated polymer, which comprises polymerizing at least one fluorinated polymer selected from tetrafluoroethylene, chlorotrifluoroethylene and vinylidene fluoride, in an aqueous medium in the presence of a specific polymer having at least one type of units selected from units based on a compound represented by the formula (1) and units based on a compound represented by the formula (2) to produce a fluorinated polymer (provided that when tetrafluoroethylene is polymerized, tetrafluoroethylene is polymerized so that the content of units based on tetrafluoroethylene in the fluorinated polymer becomes less than 99 mass % to all units in the fluorinated polymer):

CXY═CR.sup.1—COO-(L-O).sub.n—R.sup.2  formula (1):

CXY═CR.sup.3—(O).sub.m—CH.sub.2—Z—R.sup.4  formula (2):

Presently described is a monomer having the formula:

##STR00001##

wherein n ranges from 2 to 8; Y is F or C.sub.mF.sub.2m+1; a is 0, or averages 1 to 2; m is independently 1, 2, 3, or 4; and X is F or OH.

Also described is a method of making such monomer, various compounds prepared during while making the monomer, fluoropolymers comprising polymerized units of such monomer, fuel cell membranes, membrane electrode assemblies, and methods of making fluoropolymers.

Presently described is a monomer having the formula:

##STR00001##

wherein n ranges from 2 to 8; Y is F or C.sub.mF.sub.2m+1; a is 0, or averages 1 to 2; m is independently 1, 2, 3, or 4; and X is F or OH.

Also described is a method of making such monomer, various compounds prepared during while making the monomer, fluoropolymers comprising polymerized units of such monomer, fuel cell membranes, membrane electrode assemblies, and methods of making fluoropolymers.

Provided are a fluorine-containing copolymer composition containing a fluorine-containing copolymer and a fluorine-containing compound having two maleimide groups, and a cross-linked product thereof, and a compound.