Patent classifications
C08F214/265
MATERIAL FOR PRINTED CIRCUIT BOARD, METAL LAMINATE, METHODS FOR PRODUCING THEM, AND METHOD FOR PRODUCING PRINTED CIRCUIT BOARD
A material for a printed circuit board, which is a film composed of a fluorinated resin layer, where the fluorinated resin layer contains a composition containing a fluorinated copolymer having at least one functional group selected from a carbonyl group-containing group, a hydroxy group, an epoxy group and an isocyanate group, has a melt flow rate of at most 15 g/10 min measured at 372 C. under a load of 49N, and has a storage elastic modulus of at least 650 MPa.
Ethylene-tetrafluoroethylene copolymer film and method for producing same
To provide an ETFE film which is unlikely to wrinkle when stretched and retracted, and a method for producing the same. It is an ethylene-tetrafluoroethylene copolymer film characterized in that the crystallinity obtained by the formula (1) from the peak area S.sub.20 in the vicinity of 2=20, the peak area S.sub.19 in the vicinity of 2=19 and the peak area S.sub.17 in the vicinity of 2=17 in the diffraction intensity curve obtained by the X-ray diffraction method, is from 55 to 70%, and the proportion of the quasi-crystal layer obtained by the formula (2) is from 10 to 20%:
crystallinity (%)=(S.sub.19+S.sub.2)/(S.sub.17+S.sub.19+S.sub.20)100(1)
proportion of quasi-crystal layer (%)=S.sub.20/(S.sub.17+S.sub.19++S.sub.20)100(2).
Ethylene-tetrafluoroethylene copolymer film and method for producing same
To provide an ETFE film which is unlikely to wrinkle when stretched and retracted, and a method for producing the same. It is an ethylene-tetrafluoroethylene copolymer film characterized in that the crystallinity obtained by the formula (1) from the peak area S.sub.20 in the vicinity of 2=20, the peak area S.sub.19 in the vicinity of 2=19 and the peak area S.sub.17 in the vicinity of 2=17 in the diffraction intensity curve obtained by the X-ray diffraction method, is from 55 to 70%, and the proportion of the quasi-crystal layer obtained by the formula (2) is from 10 to 20%:
crystallinity (%)=(S.sub.19+S.sub.2)/(S.sub.17+S.sub.19+S.sub.20)100(1)
proportion of quasi-crystal layer (%)=S.sub.20/(S.sub.17+S.sub.19++S.sub.20)100(2).
Method for producing polymer
The present invention relates to a method of producing a polymer including: polymerizing a compound represented by the following formula (3); or copolymerizing the compound represented by the following formula (3) with a compound (6) having a reactive carbon-carbon double bond and differing from the compound represented by the following formula (3), in a presence of at least one compound selected from the group consisting of compounds represented by the following formula (1) and compounds represented by the following formula (2).
PRIMER FOR POWER STORAGE DEVICE ELECTRODE, COMPOSITION FOR FORMING PRIMER LAYER, ELECTRODE FOR POWER STORAGE DEVICE, AND SECONDARY BATTERY
To provide a secondary battery having excellent charge-discharge cycle characteristics (capacity retention rate) and discharge rate characteristics (discharge capacity ratio), as well as a primer for a power storage device electrode, a composition for forming a primer layer and an electrode for a power storage device, to obtain such a secondary battery. A primer for a power storage device electrode, to form a primer layer between a current collector and an electrode active material layer, said primer for a power storage device electrode, containing a fluorinated copolymer which has units based on tetrafluoroethylene or chlorotrifluoroethylene and units based on ethylene, hexafluoropropylene or a perfluoro(alkyl vinyl ether), but does not substantially have units based on vinylidene fluoride, and which has adhesive functional groups that can react with hydroxy groups or can form hydrogen bonds.
MOLDED ARTICLE
A molded article containing a crystal of a fluoropolymer. The fluoropolymer contains at least one selected from vinylidene fluoride/tetrafluoroethylene copolymer, polychlorotrifluoroethylene, an ethylene/tetrafluoroethylene copolymer, a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer and a tetrafluoroethylene/hexafluoropropylene copolymer. Further, the crystal is a nano-oriented crystal having a size of 300 nm or smaller.
MOLDED ARTICLE
A molded article containing a crystal of a fluoropolymer. The fluoropolymer contains at least one selected from vinylidene fluoride/tetrafluoroethylene copolymer, polychlorotrifluoroethylene, an ethylene/tetrafluoroethylene copolymer, a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer and a tetrafluoroethylene/hexafluoropropylene copolymer. Further, the crystal is a nano-oriented crystal having a size of 300 nm or smaller.
POWDER DISPERSION LIQUID, LAMINATE, FILM, AND IMPREGNATED WOVEN FABRIC
To provide a dispersion, a laminate, a film and an impregnated woven fabric.
A powder dispersion comprising powder I of polymer I having units based on tetrafluoroethylene and an oxygen-containing polar group, powder II of polymer II containing units based on a fluoroolefin, a dispersing agent, and a liquid dispersion medium, wherein the ratio of the mass content of the polymer I to the mass content of the polymer II is at most 0.7, or such a power dispersion wherein the dispersing agent is a fluorinated surfactant having a hydroxy group. A laminate, a film, and an impregnated woven fabric produced by using such a powder dispersion.
Insulated electric wire
An insulated electric wire is composed of a conductor, and an insulating layer disposed around an outer circumference of the conductor. The insulating layer is formed from a fluorine-containing elastomer composition, and the fluorine-containing elastomer composition includes a base polymer (A) including 70% by mass or more and 98% by mass or less of a copolymer (a1) of tetrafluoroethylene and an -olefin having 2 to 4 carbon atoms, and 2% by mass or more and 30% by mass or less of an ethylene-ethyl acrylate copolymer (a2) (excluding an ethylene-ethyl acrylate-maleic anhydride ternary copolymer), and a flame retardant (B) including an antimony compound (b1) and a bromine-based flame retardant (b2), and including 1 part by mass or more and 9 parts by mass or less of the antimony compound (b1), and 0.3 parts by mass or more and 15 parts by mass or less of the bromine-based flame retardant (b2) per 100 parts by mass of the base polymer (A).
METHOD FOR PRODUCING MODIFIED POLYTETRAFLUOROETHYLENE, METHOD FOR PRODUCING MODIFIED POLYTETRAFLUOROETHYLENE POWDER, AND METHOD FOR PRODUCING STRETCHED POROUS MATERIAL
To provide a method for producing modified polytetrafluoroethylene, in which formation of a fluorinated oligomer as a by-product is little. A method for producing modified polytetrafluoroethylene which contains substantially no C.sub.6-34 fluorinated oligomer containing hydrophilic functional groups and which contains substantially no fluorinated surfactant, the method comprising conducting copolymerization of tetrafluoroethylene and a monomer having a polar group, in a liquid dispersion 1 comprising a polymer containing units derived from a non-fluorinated monomer and an aqueous medium, or in a solution 2 obtainable by mixing at least one member selected from the group consisting of a polyalkylene oxide compound and a hydrocarbon-containing surfactant, with an oxidizing agent, in an aqueous medium, under such a condition that the amount of the monomer having a polar group to be used, is at most 0.150 mass % to the whole amount of tetrafluoroethylene, to obtain modified polytetrafluoroethylene.