A copolymer having tetrafluoroethylene units, hexafluoropropylene units, and units independently represented by formula in a range from 0.02 to 2 mole percent, based on the total amount of the copolymer. Rf is a linear or branched perfluoroalkyl group having from 1 to 8 carbon atoms and optionally interrupted by one or more O groups, z is 1 or 2, each n is independently from 1 to 6, and m is 0 or 1. The copolymer has a melt flow index in a range from 25 grams per 10 minutes to 35 grams per 10 minutes and has a combined number of unstable end groups and CF.sub.2H end groups in a range from 25 per 10.sup.6 carbon atoms up to 120 per 10.sup.6 carbon atoms. The copolymer can be extruded to make articles, such as insulated cables. A method of making the copolymer is also disclosed. ##STR00001##

There is provided a fluorine-containing copolymer containing tetrafluoroethylene unit, hexafluoropropylene unit, and perfluoro(propyl vinyl ether) unit, wherein the copolymer has a content of hexafluoropropylene unit of 7.0 to 12.0% by mass with respect to the whole of the monomer units, a content of perfluoro(propyl vinyl ether) unit of 1.5 to 2.9% by mass with respect to the whole of the monomer units, and a melt flow rate at 372 C. of 40 to 60 g/10 min.

The present invention relates to a method for manufacturing of partially fluorinated polymers, notably vinylidene fluoride (VDF)-based polymers, in emulsion polymerization, and to a polymer obtained from said method.

Described herein is a millable fluorinated block copolymer having at least one A block and at least one B block, wherein the A block is a semi-crystalline segment comprising repeating divalent monomeric units derived from TFE, HFP and VDF; and the B block is a segment comprising repeating dilvalent monomeric units derived from HFP and VDF; and wherein the millable fluorinated block copolymer has a modulus of 0.1 to 2.5 MPa at 100 C.

The invention relates to a heterogeneous, co-continuous copolymer composition of vinylidene fluoride and at least one other comonomer. Preferred comonomers are hexafluoropropylene and perfluoroalkylvinyl ether. The co-continuous morphology is provide by first forming a first phase polymer, then adding one or more comonomers before half of the original monomer stream has been added, and at an effective level to cause phase separation of the copolymer. The co-continuous morphology provides a means for incorporating a high level of comonomer into the copolymer with little or no adverse effect on the melting temperature. The morphology also provides the copolymer composition with a unique combination of properties, including a high melting point, good flexibility and good low temperature impact resistance. The unique properties of the polymer make it useful in end-use application where those properties provide performance advantages, such as in the wire and cable market, and in oil and gas applications.

The invention relates to a heterogeneous, co-continuous copolymer composition of vinylidene fluoride and at least one other comonomer. Preferred comonomers are hexafluoropropylene and perfluoroalkylvinyl ether. The co-continuous morphology is provide by first forming a first phase polymer, then adding one or more comonomers before half of the original monomer stream has been added, and at an effective level to cause phase separation of the copolymer. The co-continuous morphology provides a means for incorporating a high level of comonomer into the copolymer with little or no adverse effect on the melting temperature. The morphology also provides the copolymer composition with a unique combination of properties, including a high melting point, good flexibility and good low temperature impact resistance. The unique properties of the polymer make it useful in end-use application where those properties provide performance advantages, such as in the wire and cable market, and in oil and gas applications.

The invention pertains to peroxide-curable fluoroelastomers for the oil and gas industry, including explosive decompression, and which can be easily processed to yield cured parts in standard machineries at reasonable throughput rates, said fluoroelastomers comprising: recurring units derived from vinylidene fluoride (VDF); recurring units derived from hexafluoropropylene (HFP); recurring units derived from at least one bis-olefin [bis-olefin (OF)] having general formula: ##STR00001##
wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6, equal or different from each other, are H, a halogen, or a C.sub.1-C.sub.5 optionally halogenated group, possibly comprising one or more oxygen group; Z is a linear or branched C.sub.1-C.sub.18 optionally halogenated alkylene or cycloalkylene radical, optionally containing oxygen atoms, or a (per)fluoropolyoxyalkylene radical; and iodine or bromine cure-sites;
said fluoroelastomers further possessing a Mooney viscosity (ML) of at least 85 MU (1+10@121 C.), when measured according to ASTM D1646.

Described herein are conductive fluorinated elastomeric materials and methods of making and using the same. The conductive fluorinated elastomeric materials include a fluorinated polymeric matrix and one or more high aspect-ratio fillers, wherein a surface resistance of the elastomeric material is 15 ohm/square or less and/or a bulk conductivity of the elastomeric material is 0.7 Ohm-cm or less. Also described herein are liquid fluorinated elastomeric compositions, including a fluorinated polymer, one or more high aspect-ratio fillers, and a solvent. Further described herein are molded products including the conductive fluorinated elastomeric materials as described herein and wearable devices including the molded products.

There is provided a curable composition comprising a fluorinated block copolymer having (a) at least one A block, wherein the A block is a semi-crystalline segment comprising repeating divalent monomeric units derived from at least a fluorinated monomer; and (b) at least one B block, wherein the B block is a segment comprising repeating divalent monomeric units that comprises at least a fluorinated monomer and a nitrile-containing cure-site monomer.

The invention provides a molded article containing a specific fluororesin and having excellent hydrophilicity. The molded article containing the fluororesin has a melt flow rate of 1.00 g/10 min or lower and a water contact angle of 90 or smaller. The fluororesin contains at least one copolymer selected from the group consisting of a copolymer containing a tetrafluoroethylene unit and a perfluoro(alkylvinylether) unit and a copolymer containing a tetrafluoroethylene unit and a hexafluoropropylene unit.