Provided herein are perfluoro copolymers of a perfluoro dioxole monomer, a perfluoro dioxane monomer, and an optional perhalo monomer. Methods of making the perfluoro copolymers and methods of using the perfluoro copolymers are also disclosed.

Provided herein are perfluoro copolymers of a perfluoro dioxole monomer, a perfluoro dioxane monomer, and an optional perhalo monomer. Methods of making the perfluoro copolymers and methods of using the perfluoro copolymers are also disclosed.

A film includes a copolymer having a tetrafluoroethylene-based unit and an ethylene-based unit, in which the film has a haze of from 1.2% to 8.0%, an ultraviolet reflectance of less than 17.0%, and a thickness of from 250 to 400 μm.

A film includes a copolymer having a tetrafluoroethylene-based unit and an ethylene-based unit, in which the film has a haze of from 1.2% to 8.0%, an ultraviolet reflectance of less than 17.0%, and a thickness of from 250 to 400 μm.

To provide a powder coating material composition capable of forming a fluororesin layer excellent in adhesion to a base material and having foaming or cracking suppressed even when the firing temperature is as high as at least 380° C.

A powder coating material composition comprising a resin powder with an average particle size of from 10 to 800 μm containing polymer A and heat stabilizer B, wherein the proportion of the heat stabilizer B to 100 parts by mass of the polymer A is from 0.01 to 30 parts by mass. Polymer A: A tetrafluoroethylene/perfluoro (alkyl vinyl ether) copolymer having at least one type of functional group selected from the group consisting of a carbonyl group-containing group, etc., or a tetrafluoroethylene/hexafluoropropylene copolymer, having the functional group, and having a melting point of from 260 to 320° C. Heat stabilizer B: A heat stabilizer selected from the group consisting of an aromatic polyether compound, an aromatic amine compound, an aromatic sulfur compound and a polysilane compound.

To provide a powder coating material composition capable of forming a fluororesin layer excellent in adhesion to a base material and having foaming or cracking suppressed even when the firing temperature is as high as at least 380° C.

A powder coating material composition comprising a resin powder with an average particle size of from 10 to 800 μm containing polymer A and heat stabilizer B, wherein the proportion of the heat stabilizer B to 100 parts by mass of the polymer A is from 0.01 to 30 parts by mass. Polymer A: A tetrafluoroethylene/perfluoro (alkyl vinyl ether) copolymer having at least one type of functional group selected from the group consisting of a carbonyl group-containing group, etc., or a tetrafluoroethylene/hexafluoropropylene copolymer, having the functional group, and having a melting point of from 260 to 320° C. Heat stabilizer B: A heat stabilizer selected from the group consisting of an aromatic polyether compound, an aromatic amine compound, an aromatic sulfur compound and a polysilane compound.

Novel copolymers that are fluoropolymers including a first repeat unit that is fluorinated and cyclic and a second repeat unit from a trifluorovinyl methylene ether monomer having sulfur or sulfone functionality in the pendant group are disclosed. The copolymers have relatively high gas permeability as a result of a cyclic repeat unit in the copolymer backbone and ionomers from oxidation of the sulfur containing functionality are particularity useful in the cathode structure of a proton exchange membrane fuel cell.

Novel copolymers that are fluoropolymers including a first repeat unit that is fluorinated and cyclic and a second repeat unit from a trifluorovinyl methylene ether monomer having sulfur or sulfone functionality in the pendant group are disclosed. The copolymers have relatively high gas permeability as a result of a cyclic repeat unit in the copolymer backbone and ionomers from oxidation of the sulfur containing functionality are particularity useful in the cathode structure of a proton exchange membrane fuel cell.

Provided in this patent disclosure are two types of novel fluoro-monomers that can be polymerized for the fabrication of ion-exchange fluoropolymers. In addition, new proton-conductive zirconium-perfluorophosphonic acid fluoropolymer membranes that can reduce metal crossovers in redox flow batteries are also provided.

Provided in this patent disclosure are two types of novel fluoro-monomers that can be polymerized for the fabrication of ion-exchange fluoropolymers. In addition, new proton-conductive zirconium-perfluorophosphonic acid fluoropolymer membranes that can reduce metal crossovers in redox flow batteries are also provided.