Patent classifications
C08F218/08
Apparatus and method for manufacturing high-pressure method low-density polyethylene
Provided are an apparatus and a method for manufacturing high-pressure method low-density polyethylene, the apparatus and the method having excellent characteristics that a chain transfer agent can be supplied by a simpler apparatus, a deviation (variation) of the concentration of the chain transfer agent supplied to a reactor can be reduced, and compression energy of the chain transfer agent can be reduced. An apparatus for manufacturing high-pressure method polyethylene includes a chain transfer agent supply line that is a line connected to a low pressure recycle ethylene supply line for supplying a chain transfer agent.
Apparatus and method for manufacturing high-pressure method low-density polyethylene
Provided are an apparatus and a method for manufacturing high-pressure method low-density polyethylene, the apparatus and the method having excellent characteristics that a chain transfer agent can be supplied by a simpler apparatus, a deviation (variation) of the concentration of the chain transfer agent supplied to a reactor can be reduced, and compression energy of the chain transfer agent can be reduced. An apparatus for manufacturing high-pressure method polyethylene includes a chain transfer agent supply line that is a line connected to a low pressure recycle ethylene supply line for supplying a chain transfer agent.
MODIFIED POLYVINYL ALCOHOL RESIN WITH IMPROVED SOLUBILITY IN ALCOHOL MIXTURES
A sulfonic acid modified polyvinyl alcohol resin comprising up to 15 mol % of a first comonomer comprising sulfonic acid groups. The modified polyvinyl alcohol resin has a hydroxyl unit content of at least 65 mol % and a gel fraction of 3.2 or less. Further, the modified polyvinyl alcohol resin has a disintegration time of 85 seconds or less, as measured in a mixture of 50 vol % water and 50 vol % isopropyl alcohol at 23° C. Additionally, the modified polyvinyl alcohol resin has a hard component present in a component ratio of 10% or greater and 55% or less and having a relaxation time of 0.0091 milliseconds or greater and 0.0104 milliseconds or less, as measured by the pulsed NMR Solid Echo method at 80° C. Also disclosed are methods for producing the sulfonic acid modified polyvinyl alcohol resins, which may advantageously be used in inks, paints, paper coatings, emulsions, or films.
MODIFIED POLYVINYL ALCOHOL RESIN WITH IMPROVED SOLUBILITY IN ALCOHOL MIXTURES
A sulfonic acid modified polyvinyl alcohol resin comprising up to 15 mol % of a first comonomer comprising sulfonic acid groups. The modified polyvinyl alcohol resin has a hydroxyl unit content of at least 65 mol % and a gel fraction of 3.2 or less. Further, the modified polyvinyl alcohol resin has a disintegration time of 85 seconds or less, as measured in a mixture of 50 vol % water and 50 vol % isopropyl alcohol at 23° C. Additionally, the modified polyvinyl alcohol resin has a hard component present in a component ratio of 10% or greater and 55% or less and having a relaxation time of 0.0091 milliseconds or greater and 0.0104 milliseconds or less, as measured by the pulsed NMR Solid Echo method at 80° C. Also disclosed are methods for producing the sulfonic acid modified polyvinyl alcohol resins, which may advantageously be used in inks, paints, paper coatings, emulsions, or films.
RESIN PELLET, METHOD OF MANUFACTURING RESIN PELLET, GRAVURE INK AND WIRE COATING MATERIAL
A resin pellet includes a pellet-shaped ethylene-vinyl acetate copolymer; a liquid coating agent; and a solid coating agent adhered to at least a portion of surfaces of the ethylene-vinyl acetate copolymer and of the liquid coating agent, in which the liquid coating agent is a compound including a hydroxyl group, and the solid coating agent is an organic compound.
RESIN PELLET, METHOD OF MANUFACTURING RESIN PELLET, GRAVURE INK AND WIRE COATING MATERIAL
A resin pellet includes a pellet-shaped ethylene-vinyl acetate copolymer; a liquid coating agent; and a solid coating agent adhered to at least a portion of surfaces of the ethylene-vinyl acetate copolymer and of the liquid coating agent, in which the liquid coating agent is a compound including a hydroxyl group, and the solid coating agent is an organic compound.
ADHESIVE TAPE
The present invention relates to an adhesive tape having a layer structure in which an adhesive layer, a first film layer (I), a base material layer, and a second film layer (II) are arranged in this order, in which the base material layer satisfies a predetermined requirement that a ratio (a)/(b) of a thickness (a) to a thickness (b) is not less than 1.7 or not more than 0.6 in which the thickness (a) is a thickness from the first film layer (I)-side of the base material layer to the outer surface of the adhesive layer and the thickness (b) is a thickness from the second film layer (II)-side surface of the base material layer to the outer surface of the second film layer (II), and at least one layer constituting the layer structure contains a flame retardant (C).
ADHESIVE TAPE
The present invention relates to an adhesive tape having a layer structure in which an adhesive layer, a first film layer (I), a base material layer, and a second film layer (II) are arranged in this order, in which the base material layer satisfies a predetermined requirement that a ratio (a)/(b) of a thickness (a) to a thickness (b) is not less than 1.7 or not more than 0.6 in which the thickness (a) is a thickness from the first film layer (I)-side of the base material layer to the outer surface of the adhesive layer and the thickness (b) is a thickness from the second film layer (II)-side surface of the base material layer to the outer surface of the second film layer (II), and at least one layer constituting the layer structure contains a flame retardant (C).
METHOD FOR PREPARING EVA COPOLYMER WITH HIGH ETHYLENE CONTENT BY SOLUTION POLYMERIZATION UNDER A LOW TO A MEDIUM PRESSURE
Disclosed is a method for preparing an EVA copolymer with a high ethylene content by solution polymerization under a low to a medium pressure. The method comprises the following steps: initiating with a free radical initiator(s), a copolymerization reaction between ethylene and vinyl acetate in a solvent in a reactor under a low to a medium pressure to obtain the EVA copolymer; and continuing to add ethylene during the reaction to maintain the low to medium pressure, wherein the low to medium pressure is 1-101 MPa, and a ratio of a mass of the vinyl acetate to a mass of the initially added ethylene is (1:1) to (1:20). The amount of ethylene incorporated in the EVA copolymer prepared according to the method is ≥ 50 wt%, and the EVA copolymer has properties equivalent to those of an EVA copolymer obtained by bulk polymerization at high temperature under high pressure.
METHOD FOR PREPARING EVA COPOLYMER WITH HIGH ETHYLENE CONTENT BY SOLUTION POLYMERIZATION UNDER A LOW TO A MEDIUM PRESSURE
Disclosed is a method for preparing an EVA copolymer with a high ethylene content by solution polymerization under a low to a medium pressure. The method comprises the following steps: initiating with a free radical initiator(s), a copolymerization reaction between ethylene and vinyl acetate in a solvent in a reactor under a low to a medium pressure to obtain the EVA copolymer; and continuing to add ethylene during the reaction to maintain the low to medium pressure, wherein the low to medium pressure is 1-101 MPa, and a ratio of a mass of the vinyl acetate to a mass of the initially added ethylene is (1:1) to (1:20). The amount of ethylene incorporated in the EVA copolymer prepared according to the method is ≥ 50 wt%, and the EVA copolymer has properties equivalent to those of an EVA copolymer obtained by bulk polymerization at high temperature under high pressure.