Embodiments of a spray-drying process for producing low aspect ratio particles of poly[(methyl methacrylate)-co-(methacrylic acid)] (PMMAMA) are disclosed. In some examples, at least 95% of PMMAMA-containing particles made by the process have an aspect ratio <10. The particles may further include an active ingredient and/or an excipient.

Embodiments of a spray-drying process for producing low aspect ratio particles of poly[(methyl methacrylate)-co-(methacrylic acid)] (PMMAMA) are disclosed. In some examples, at least 95% of PMMAMA-containing particles made by the process have an aspect ratio <10. The particles may further include an active ingredient and/or an excipient.

A continuous inverse emulsion polymerization process may involve combining an aqueous monomer composition with an oil composition in a premix vessel and allowing the aqueous monomer composition to interact with the oil composition in the premix vessel for a period of time effective to form a stable pre-emulsion. The stable pre-emulsion may then be homogenized to form a homogenized emulsion that is then polymerized to form a water-in-oil inverse emulsion polymer. By forming a stable pre-emulsion that is then homogenized, the resulting water-in-oil inverse emulsion polymer may have uniform and consistent polymer size distribution.

A continuous inverse emulsion polymerization process may involve combining an aqueous monomer composition with an oil composition in a premix vessel and allowing the aqueous monomer composition to interact with the oil composition in the premix vessel for a period of time effective to form a stable pre-emulsion. The stable pre-emulsion may then be homogenized to form a homogenized emulsion that is then polymerized to form a water-in-oil inverse emulsion polymer. By forming a stable pre-emulsion that is then homogenized, the resulting water-in-oil inverse emulsion polymer may have uniform and consistent polymer size distribution.

Aqueous inkjet ink compositions are provided. In an embodiment, such a composition comprises water; resin particles; and a colorant; wherein the resin particles comprise a polymerization product of reactants comprising a monomer, an acidic monomer, a multifunctional monomer, and a reactive surfactant, the resin particles having a D.sub.(z, ave) of no greater than about 150 nm, a D.sub.(v,90) of less than about 200 nm, and a polydispersity index (PDI) of no greater than about 0.050. Methods of forming and using the aqueous inkjet ink compositions are also provided.

Aqueous inkjet ink compositions are provided. In an embodiment, such a composition comprises water; resin particles; and a colorant; wherein the resin particles comprise a polymerization product of reactants comprising a monomer, an acidic monomer, a multifunctional monomer, and a reactive surfactant, the resin particles having a D.sub.(z, ave) of no greater than about 150 nm, a D.sub.(v,90) of less than about 200 nm, and a polydispersity index (PDI) of no greater than about 0.050. Methods of forming and using the aqueous inkjet ink compositions are also provided.

An adhesive composition that contains two polymeric materials, a method of making the adhesive composition, and an article that contains the adhesive composition are provided. One of the polymeric materials is derived from a (meth)acrylate macromer having a poly(tetrahydrofuran) group. The articles include a layer of the adhesive composition positioned next to a substrate. The articles can be, for example, an adhesive tape or can be part of another article such as, for example, an electronic device that is impact resistant and/or flexible.

An adhesive composition that contains two polymeric materials, a method of making the adhesive composition, and an article that contains the adhesive composition are provided. One of the polymeric materials is derived from a (meth)acrylate macromer having a poly(tetrahydrofuran) group. The articles include a layer of the adhesive composition positioned next to a substrate. The articles can be, for example, an adhesive tape or can be part of another article such as, for example, an electronic device that is impact resistant and/or flexible.

This invention deals with a new alkylphenol ethoxylated free (APE-free) reactive nonionic surfactant with terminal unsaturation in the hydrophobic part comprising at least one of monoesters and diesters and a process to obtain the APE-free reactive nonionic surfactant comprising the alkoxylation step of fatty acid with terminal unsaturation or direct esterification of fatty acid with terminal unsaturation and glycol derivative. Furthermore, emulsion polymerized latexes are disclosed, which are polymerized with an anionic surfactant and a reactive nonionic surfactant of this invention. Latexes prepared according to this invention generated water-based coating compositions with high water resistance.

This invention deals with a new alkylphenol ethoxylated free (APE-free) reactive nonionic surfactant with terminal unsaturation in the hydrophobic part comprising at least one of monoesters and diesters and a process to obtain the APE-free reactive nonionic surfactant comprising the alkoxylation step of fatty acid with terminal unsaturation or direct esterification of fatty acid with terminal unsaturation and glycol derivative. Furthermore, emulsion polymerized latexes are disclosed, which are polymerized with an anionic surfactant and a reactive nonionic surfactant of this invention. Latexes prepared according to this invention generated water-based coating compositions with high water resistance.