Disclosed is a thermoplastic resin including an alkyl acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A), or an alkyl acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A) and a matrix resin (B) including one or more selected from the group consisting of an aromatic vinyl compound, a vinyl cyanide compound, an alkyl methacrylate, and an alkyl acrylate, wherein the total content of the alkyl acrylate is 20 to 50% by weight, and an alkyl acrylate coverage value (X) as calculated by Equation 1 below is 65 or more:

X={(G−Y)/Y}×100,   [Equation 1]

wherein G represents the total gel content (%) of the thermoplastic resin, and Y represents the content (% by weight) of the alkyl acrylate in the gel of the thermoplastic resin.

Disclosed are a copolymerized PVDF resin for lithium battery binders and its preparation method. 300 to 600 parts of deionized water, 0.04 to 0.25 part of a pH buffer regulator, 85 to 99.5 parts of a vinylidene fluoride (VDF) monomer, 0.5 to 15 parts of a comonomer, 0.3 to 3 parts of a metallocene synergist, 0.2 to 1.0 part of an initiator, 0.08 to 0.35 part of a dispersant react at 40 to 65° C., 5.5-8.0 Mpa. At the end of the reaction, the unreacted monomers are recovered, and then the operations of washing, filtering, and drying are carried out to obtain the copolymerized PVDF resin. For the copolymerized PVDF resin for lithium battery binders, the binding of PVDF resin to a positive electrode active material and current collector is improved, and the rotational viscosity of the NMP solution and the preparation and dispersion requirements for PVDF resin slurry are reduced.

Disclosed are a copolymerized PVDF resin for lithium battery binders and its preparation method. 300 to 600 parts of deionized water, 0.04 to 0.25 part of a pH buffer regulator, 85 to 99.5 parts of a vinylidene fluoride (VDF) monomer, 0.5 to 15 parts of a comonomer, 0.3 to 3 parts of a metallocene synergist, 0.2 to 1.0 part of an initiator, 0.08 to 0.35 part of a dispersant react at 40 to 65° C., 5.5-8.0 Mpa. At the end of the reaction, the unreacted monomers are recovered, and then the operations of washing, filtering, and drying are carried out to obtain the copolymerized PVDF resin. For the copolymerized PVDF resin for lithium battery binders, the binding of PVDF resin to a positive electrode active material and current collector is improved, and the rotational viscosity of the NMP solution and the preparation and dispersion requirements for PVDF resin slurry are reduced.

This invention relates to novel macromers that comprise a polyether polyol having (meth)acrylate unsaturation. These novel macromers are the polymerization product of a glycidyl (meth)acrylate, with a polyether polyol, and optionally, an alkylene oxide, in the presence of a double metal cyanide catalyst. This invention also relates to preformed stabilizers prepared from these macromers, and to polymer polyols prepared from these novel macromers and novel preformed stabilizers. The present invention also relates to processes for preparing these compositions, to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.

This invention relates to novel macromers that comprise a polyether polyol having (meth)acrylate unsaturation. These novel macromers are the polymerization product of a glycidyl (meth)acrylate, with a polyether polyol, and optionally, an alkylene oxide, in the presence of a double metal cyanide catalyst. This invention also relates to preformed stabilizers prepared from these macromers, and to polymer polyols prepared from these novel macromers and novel preformed stabilizers. The present invention also relates to processes for preparing these compositions, to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.

The present invention relates to a method of preparing an ASA graft copolymer, a method of preparing a thermoplastic resin composition including the ASA graft copolymer, and a method of manufacturing a molded article using the thermoplastic resin composition. More particularly, the present invention provides an ASA graft copolymer having improved thermal stability through addition of an emulsifier in a specific amount range in a seed preparation step and introduction of a multifunctional carboxylic acid having 20 or more carbon atoms or a salt thereof, as an emulsifier, in a shell preparation step and a high-quality thermoplastic resin composition exhibiting excellent impact resistance, such as impact strength and tensile strength, and excellent appearance, such as surface gloss, whiteness, and retention-associated heat discoloration, and causing considerable reduction in the amount of gas generated on a surface of a resin during a high-temperature thermoforming process due to inclusion of the ASA graft copolymer.

The present invention relates to a method of preparing an ASA graft copolymer, a method of preparing a thermoplastic resin composition including the ASA graft copolymer, and a method of manufacturing a molded article using the thermoplastic resin composition. More particularly, the present invention provides an ASA graft copolymer having improved thermal stability through addition of an emulsifier in a specific amount range in a seed preparation step and introduction of a multifunctional carboxylic acid having 20 or more carbon atoms or a salt thereof, as an emulsifier, in a shell preparation step and a high-quality thermoplastic resin composition exhibiting excellent impact resistance, such as impact strength and tensile strength, and excellent appearance, such as surface gloss, whiteness, and retention-associated heat discoloration, and causing considerable reduction in the amount of gas generated on a surface of a resin during a high-temperature thermoforming process due to inclusion of the ASA graft copolymer.

A thermoplastic resin composition includes 7% to 64% by mass of rubber-containing graft copolymer (A), 2% to 35% by mass of thermoplastic elastomer (B), 0.5% to 90% by mass of polycarbonate-based resins (C), and 0.5% to 20% by mass of inorganic compound (D) having volume average particle diameter (MV) of 1 to 200 μm (where a total of (A), (B), (C), and (D) (hereafter referred to as “total of a component (A) to a component (D)”) is 100% by mass). The rubber-containing graft copolymer (A) is a graft copolymer in which 35 to 80 parts by mass of rubber-like polymer selected from diene-based rubber, acrylic rubber, and ethylene-based rubber is graft-polymerized with 20 to 65 parts by mass of vinyl-based monomer mixture containing an aromatic-vinyl-based monomer and a vinyl-cyanide-based monomer (where a total of the rubber-like polymer and the vinyl-based monomer mixture is 100% by mass).

A thermoplastic resin composition includes 7% to 64% by mass of rubber-containing graft copolymer (A), 2% to 35% by mass of thermoplastic elastomer (B), 0.5% to 90% by mass of polycarbonate-based resins (C), and 0.5% to 20% by mass of inorganic compound (D) having volume average particle diameter (MV) of 1 to 200 μm (where a total of (A), (B), (C), and (D) (hereafter referred to as “total of a component (A) to a component (D)”) is 100% by mass). The rubber-containing graft copolymer (A) is a graft copolymer in which 35 to 80 parts by mass of rubber-like polymer selected from diene-based rubber, acrylic rubber, and ethylene-based rubber is graft-polymerized with 20 to 65 parts by mass of vinyl-based monomer mixture containing an aromatic-vinyl-based monomer and a vinyl-cyanide-based monomer (where a total of the rubber-like polymer and the vinyl-based monomer mixture is 100% by mass).

Processes for producing filled polyol compositions, such as polymer polyol compositions. The processes include reacting a polymerizable composition in the presence of a composition comprising a base polyol and an amine antioxidant, in which the amine antioxidant comprises a secondary diarylamine, a primary aromatic amide, a triazole, or a combination thereof.