C08F220/44

TRANSPARENT THERMOPLASTIC RESIN COMPOSITION, PRODUCTION METHOD THEREFOR, MOLDED ARTICLE OBTAINED BY MOLDING TRANSPARENT THERMOPLASTIC RESIN COMPOSITION, AND PRODUCTION METHOD FOR MOLDED ARTICLE

A transparent thermoplastic resin composition containing: based on 100 parts by mass of the transparent thermoplastic resin composition, 10 to 60 parts by mass of a graft copolymer (A) obtained by graft copolymerizing a monomer mixture (a) containing at least an aromatic vinyl-based monomer (a1) and a (meth)acrylic acid ester-based monomer (a2) in the presence of a rubbery polymer (R); 40 to 90 parts by mass of a vinyl copolymer (B) obtained by copolymerizing a monomer mixture (b) containing at least an aromatic vinyl-based monomer (b1) and a (meth)acrylic acid ester-based monomer (b2); 100 to 1,000 ppm of a phenolic compound (C); and a dihydrooxaphosphaphenanthrene-based phosphorus compound (D), wherein a molar ratio (P/OH) of a phosphorus atom (P) of the dihydrooxaphosphaphenanthrene-based phosphorus compound (D) to a hydroxyl group (OH) of the phenolic compound (C) is 0.2 to 5.0.

TRANSPARENT THERMOPLASTIC RESIN COMPOSITION, PRODUCTION METHOD THEREFOR, MOLDED ARTICLE OBTAINED BY MOLDING TRANSPARENT THERMOPLASTIC RESIN COMPOSITION, AND PRODUCTION METHOD FOR MOLDED ARTICLE

A transparent thermoplastic resin composition containing: based on 100 parts by mass of the transparent thermoplastic resin composition, 10 to 60 parts by mass of a graft copolymer (A) obtained by graft copolymerizing a monomer mixture (a) containing at least an aromatic vinyl-based monomer (a1) and a (meth)acrylic acid ester-based monomer (a2) in the presence of a rubbery polymer (R); 40 to 90 parts by mass of a vinyl copolymer (B) obtained by copolymerizing a monomer mixture (b) containing at least an aromatic vinyl-based monomer (b1) and a (meth)acrylic acid ester-based monomer (b2); 100 to 1,000 ppm of a phenolic compound (C); and a dihydrooxaphosphaphenanthrene-based phosphorus compound (D), wherein a molar ratio (P/OH) of a phosphorus atom (P) of the dihydrooxaphosphaphenanthrene-based phosphorus compound (D) to a hydroxyl group (OH) of the phenolic compound (C) is 0.2 to 5.0.

LATEX COMPOSITION AND DIP-MOLDED BODY
20230086263 · 2023-03-23 · ·

A latex composition includes a latex of a conjugated diene polymer (A) having a glass transition temperature of 10° C. or less and a latex of a polymer (B) having a glass transition temperature of more than 10° C., wherein the value of (CS(B)−CS(A)) is more than 0% by weight, where a chemical stability of the latex of the conjugated diene polymer (A) to CaCl.sub.2, when the solids concentration of the latex is 20% by weight, is defined as CS(A) (% by weight), and a chemical stability of the latex of the polymer (B) to CaCl.sub.2, when the solids concentration of the latex is 20% by weight, is defined as CS(B) (% by weight).

LATEX COMPOSITION AND DIP-MOLDED BODY
20230086263 · 2023-03-23 · ·

A latex composition includes a latex of a conjugated diene polymer (A) having a glass transition temperature of 10° C. or less and a latex of a polymer (B) having a glass transition temperature of more than 10° C., wherein the value of (CS(B)−CS(A)) is more than 0% by weight, where a chemical stability of the latex of the conjugated diene polymer (A) to CaCl.sub.2, when the solids concentration of the latex is 20% by weight, is defined as CS(A) (% by weight), and a chemical stability of the latex of the polymer (B) to CaCl.sub.2, when the solids concentration of the latex is 20% by weight, is defined as CS(B) (% by weight).

METHOD FOR PRODUCING NITRILE RUBBER
20230092267 · 2023-03-23 · ·

A method for producing a nitrile rubber, includes recovering a nitrile rubber from a latex of nitrile rubber by continuously feeding the latex of nitrile rubber and a coagulant into an extruder including a screw disposed inside a barrel to be rotatably driven, wherein the latex of nitrile rubber fed into the extruder contains 0.1 to 3 parts by weight of a hindered phenol-based antiaging agent having a molecular weight of 300 to 3000 relative to 100 parts by weight of the nitrile rubber.

METHOD FOR PRODUCING NITRILE RUBBER
20230092267 · 2023-03-23 · ·

A method for producing a nitrile rubber, includes recovering a nitrile rubber from a latex of nitrile rubber by continuously feeding the latex of nitrile rubber and a coagulant into an extruder including a screw disposed inside a barrel to be rotatably driven, wherein the latex of nitrile rubber fed into the extruder contains 0.1 to 3 parts by weight of a hindered phenol-based antiaging agent having a molecular weight of 300 to 3000 relative to 100 parts by weight of the nitrile rubber.

RESIN COMPOSITION FOR PLATING

The resin composition for plating of the present invention includes: a graft copolymer (A) in which a monomer component (a) including specific amounts of an aromatic vinyl compound (a1), a vinyl cyanide compound (a2), and another vinyl compound (a3) is graft-polymerized on a rubbery polymer; and a polycarbonate resin (P), wherein an amount of resin (P) is 40 to 70% by mass, based on a total mass of the resin composition, a rubber content (X) in copolymer (A) is more than 40% by mass, based on a total mass of copolymer (A), a graft ratio (Y) of copolymer (A) satisfies formula (1): 793e.sup.−0.041X≥Y≥515e.sup.−0.041X (1), and a rubber content (Z) in the resin composition is 10 to 18% by mass, based on a total mass of the resin composition.

RESIN COMPOSITION FOR PLATING

The resin composition for plating of the present invention includes: a graft copolymer (A) in which a monomer component (a) including specific amounts of an aromatic vinyl compound (a1), a vinyl cyanide compound (a2), and another vinyl compound (a3) is graft-polymerized on a rubbery polymer; and a polycarbonate resin (P), wherein an amount of resin (P) is 40 to 70% by mass, based on a total mass of the resin composition, a rubber content (X) in copolymer (A) is more than 40% by mass, based on a total mass of copolymer (A), a graft ratio (Y) of copolymer (A) satisfies formula (1): 793e.sup.−0.041X≥Y≥515e.sup.−0.041X (1), and a rubber content (Z) in the resin composition is 10 to 18% by mass, based on a total mass of the resin composition.

THERMOPLASTIC RESIN COMPOSITION AND MOLDED ARTICLE PRODUCED BY MOLDING THE SAME
20220348758 · 2022-11-03 ·

A thermoplastic resin composition including a graft copolymer (B) produced by graft polymerization of a vinyl monomer mixture (m1) including an alkyl (meth)acrylate ester, a vinyl cyanide compound, and an aromatic vinyl compound onto a copolymer (A) produced by copolymerizing an alkyl (meth)acrylate ester (a) and a (meth)acrylate ester (b) including an aromatic hydrocarbon group at a specific ratio and a copolymer (C) that is a product of a polymerization reaction of a vinyl monomer mixture (m2) including an alkyl (meth)acrylate ester. The graft copolymer (B) includes at least a graft copolymer (B) having a specific volume-average particle size. The copolymer (A) has a specific volume-average particle size and a specific particle size distribution.

THERMOPLASTIC RESIN COMPOSITION AND MOLDED ARTICLE PRODUCED BY MOLDING THE SAME
20220348758 · 2022-11-03 ·

A thermoplastic resin composition including a graft copolymer (B) produced by graft polymerization of a vinyl monomer mixture (m1) including an alkyl (meth)acrylate ester, a vinyl cyanide compound, and an aromatic vinyl compound onto a copolymer (A) produced by copolymerizing an alkyl (meth)acrylate ester (a) and a (meth)acrylate ester (b) including an aromatic hydrocarbon group at a specific ratio and a copolymer (C) that is a product of a polymerization reaction of a vinyl monomer mixture (m2) including an alkyl (meth)acrylate ester. The graft copolymer (B) includes at least a graft copolymer (B) having a specific volume-average particle size. The copolymer (A) has a specific volume-average particle size and a specific particle size distribution.