The present invention relates to a method for producing a polyacrylonitrile-based fiber, wherein the method polymerizes a monomer mixture including an acrylonitrile-based monomer, a carboxylic acid-based comonomer, and an acrylate-based comonomer, wherein the acrylate-based comonomer includes the steps of producing a polyacrylonitrile-based copolymer so as to be included in an amount of 4 to 20 parts by weight based on 100 parts by weight of the monomer mixture, fiberizing the polyacrylonitrile-based copolymer, oxidizing and stabilizing the fiberized polyacrylonitrile-based copolymer, which may control the oxidation stabilization reaction, particularly the cyclization reaction. Accordingly, the energy consumption of the oxidation stabilization reaction may be reduced, economical efficiency of the production of polyacrylonitrile-based fiber may be obtained, and the physical and mechanical properties of the carbon fiber may be improved.

The present invention relates to a method for producing a polyacrylonitrile-based fiber, wherein the method polymerizes a monomer mixture including an acrylonitrile-based monomer, a carboxylic acid-based comonomer, and an acrylate-based comonomer, wherein the acrylate-based comonomer includes the steps of producing a polyacrylonitrile-based copolymer so as to be included in an amount of 4 to 20 parts by weight based on 100 parts by weight of the monomer mixture, fiberizing the polyacrylonitrile-based copolymer, oxidizing and stabilizing the fiberized polyacrylonitrile-based copolymer, which may control the oxidation stabilization reaction, particularly the cyclization reaction. Accordingly, the energy consumption of the oxidation stabilization reaction may be reduced, economical efficiency of the production of polyacrylonitrile-based fiber may be obtained, and the physical and mechanical properties of the carbon fiber may be improved.

The present invention relates to a method for producing a polyacrylonitrile-based fiber, wherein the method polymerizes a monomer mixture including an acrylonitrile-based monomer, a carboxylic acid-based comonomer, and an acrylate-based comonomer, wherein the acrylate-based comonomer includes the steps of producing a polyacrylonitrile-based copolymer so as to be included in an amount of 4 to 20 parts by weight based on 100 parts by weight of the monomer mixture, fiberizing the polyacrylonitrile-based copolymer, oxidizing and stabilizing the fiberized polyacrylonitrile-based copolymer, which may control the oxidation stabilization reaction, particularly the cyclization reaction. Accordingly, the energy consumption of the oxidation stabilization reaction may be reduced, economical efficiency of the production of polyacrylonitrile-based fiber may be obtained, and the physical and mechanical properties of the carbon fiber may be improved.

Provided are a paste for a secondary battery, and method of producing the same, with which it is possible to produce an electrode that can reduce internal resistance of a secondary battery and that can cause the secondary battery to display excellent cycle characteristics. The paste for a secondary battery contains a conductive additive, a polymer, and a dispersion medium. The conductive additive includes one or more carbon nanotubes having a surface base content of not less than 0.01 mmol/g and not more than 0.10 mmol/g and a ratio of surface acid content relative to the surface base content of not less than 0.1 and not more than 1.0.

Provided are a paste for a secondary battery, and method of producing the same, with which it is possible to produce an electrode that can reduce internal resistance of a secondary battery and that can cause the secondary battery to display excellent cycle characteristics. The paste for a secondary battery contains a conductive additive, a polymer, and a dispersion medium. The conductive additive includes one or more carbon nanotubes having a surface base content of not less than 0.01 mmol/g and not more than 0.10 mmol/g and a ratio of surface acid content relative to the surface base content of not less than 0.1 and not more than 1.0.

A graphic sheet is provided that can be affixed with sufficient adhesive force onto wallpaper, a poster, or other substrate having comparatively low strength, and can be easily renewed without damaging the substrate, which is the underlying layer. A graphic sheet of an embodiment of the present disclosure includes: a base film layer having a first surface and a second surface situated on an opposite side of the first surface; and a tacky acrylic foam layer disposed on or above the second surface of the base film layer. The acrylic foam layer contains an acrylic polymer having 20 mass % or more of a unit derived from ethyl acrylate.

A graphic sheet is provided that can be affixed with sufficient adhesive force onto wallpaper, a poster, or other substrate having comparatively low strength, and can be easily renewed without damaging the substrate, which is the underlying layer. A graphic sheet of an embodiment of the present disclosure includes: a base film layer having a first surface and a second surface situated on an opposite side of the first surface; and a tacky acrylic foam layer disposed on or above the second surface of the base film layer. The acrylic foam layer contains an acrylic polymer having 20 mass % or more of a unit derived from ethyl acrylate.

The current invention relates to an one-pack aqueous coating composition comprising dispersed carbonyl functional vinyl polymer(s) particles, characterized in that the coating composition further comprises carbodihydrazide, whereby (i) the equivalent molar ratio of hydrazide groups to carbonyl groups is from 0.1 to 0.95, (ii) the ratio of number-average molecular weight of the carbonyl functional vinyl polymer(s) to acid value of the carbonyl functional vinyl polymer(s) is higher than 400, and (iii) the acid value of the carbonyl functional vinyl polymer(s) is from 2 to 100 mg KOH/gram carbonyl functional vinyl polymer.

The current invention relates to an one-pack aqueous coating composition comprising dispersed carbonyl functional vinyl polymer(s) particles, characterized in that the coating composition further comprises carbodihydrazide, whereby (i) the equivalent molar ratio of hydrazide groups to carbonyl groups is from 0.1 to 0.95, (ii) the ratio of number-average molecular weight of the carbonyl functional vinyl polymer(s) to acid value of the carbonyl functional vinyl polymer(s) is higher than 400, and (iii) the acid value of the carbonyl functional vinyl polymer(s) is from 2 to 100 mg KOH/gram carbonyl functional vinyl polymer.

An acrylic rubber including: a polymer composition of: 70 to 99.9% by weight of a bonding unit derived from at least one (meth) acrylic acid ester selected from (meth) acrylic acid alkyl ester and (meth) acrylic acid alkoxyalkyl ester; 0.1 to 10% by weight of a bonding unit derived from a monomer containing a reactive group; and 0 to 20% by weight of a bonding unit derived from other monomer, wherein ash content is 0.15% by weight or less, total amount of sodium and sulfur in the ash is 60% by weight or more, a ratio of sodium to sulfur by weight ratio is in the range of 0.5 to 2.5, ratio of Z-average molecular weight to weight average molecular weight is 1.3 or more, and weight average molecular weight is in the range of 1,000,000 to 5,000,000.