Provided are a polymer composite, a rubber composition, and a tire which can reversibly vary tire performance in response to changes in temperature. The present disclosure relates to a polymer composite formed from at least one conjugated diene polymer having a weight average molecular weight of 100,000 or more as determined by gel permeation chromatography, the polymer composite reversibly satisfying the following relationship (II) with respect to the temperature dependence of contact angles of water at two temperatures differing by at least 10° C.: (II) Temperature dependence of contact angles: (Contact angle at lower temperature)/(Contact angle at higher temperature)×100≤90.

Provided are a polymer composite, a rubber composition, and a tire which can reversibly vary tire performance in response to changes in temperature. The present disclosure relates to a polymer composite formed from at least one conjugated diene polymer having a weight average molecular weight of 100,000 or more as determined by gel permeation chromatography, the polymer composite reversibly satisfying the following relationship (II) with respect to the temperature dependence of contact angles of water at two temperatures differing by at least 10° C.: (II) Temperature dependence of contact angles: (Contact angle at lower temperature)/(Contact angle at higher temperature)×100≤90.

Described are articles including treads and/or other tire components that are formed at least in part by rubber compositions having solid agglomerated material comprising disaggregated carbon nanotubes. Such rubber compositions include a diene rubber component and a solid agglomerated material comprising disaggregated carbon nanotubes that consist of a continuous network of carbon nanotubes that contains 1) voids and 2) aggregates of carbon nanotubes having a mean size d.sub.50 of less than 5 μm, the voids and the aggregates together in an amount that is less than 60% of a predetermined surface area, as determined by electron microscopy imagery analysis, the remainder being the disaggregated carbon nanotubes in the continuous network that do not comprise a clearly defined shape.

Described are articles including treads and/or other tire components that are formed at least in part by rubber compositions having solid agglomerated material comprising disaggregated carbon nanotubes. Such rubber compositions include a diene rubber component and a solid agglomerated material comprising disaggregated carbon nanotubes that consist of a continuous network of carbon nanotubes that contains 1) voids and 2) aggregates of carbon nanotubes having a mean size d.sub.50 of less than 5 μm, the voids and the aggregates together in an amount that is less than 60% of a predetermined surface area, as determined by electron microscopy imagery analysis, the remainder being the disaggregated carbon nanotubes in the continuous network that do not comprise a clearly defined shape.

Provided are copolymers which provide improved overall performance in terms of fuel economy and wet grip performance, as well as rubber compositions and tires containing the copolymers. Included is a copolymer obtained by copolymerizing an aromatic vinyl compound, a conjugated diene compound, and a compound represented by the formula (1) below or by copolymerizing a conjugated diene compound and a compound represented by the formula (1) below, the copolymer having a weight average molecular weight of 1.0×10.sup.3 to 2.5×10.sup.6, ##STR00001##
wherein R.sup.1 and R.sup.2 may be the same or different and each represents a functional group containing at least two selected from the group consisting of carbon, hydrogen, and silicon, and R.sup.1 and R.sup.2 may be joined together to form a ring structure.

Provided are copolymers which provide improved overall performance in terms of fuel economy and wet grip performance, as well as rubber compositions and tires containing the copolymers. Included is a copolymer obtained by copolymerizing an aromatic vinyl compound, a conjugated diene compound, and a compound represented by the formula (1) below or by copolymerizing a conjugated diene compound and a compound represented by the formula (1) below, the copolymer having a weight average molecular weight of 1.0×10.sup.3 to 2.5×10.sup.6, ##STR00001##
wherein R.sup.1 and R.sup.2 may be the same or different and each represents a functional group containing at least two selected from the group consisting of carbon, hydrogen, and silicon, and R.sup.1 and R.sup.2 may be joined together to form a ring structure.

Provided is a hydrogenated block copolymer, which is a hydrogenation product of a block copolymer including a polymer block (A) containing more than 70 mol % of a structural unit derived from an aromatic vinyl compound and a polymer block (B) containing 30 mol % or more of a structural unit derived from at least one selected from the group consisting of a conjugated diene compound and isobutylene, the hydrogenated block copolymer being satisfied with the following requirements (1) and (2): Requirement (1): the content of the polymer block (A) in the block copolymer is 1 to 30% by mass; and Requirement (2): when the polymer block (B) is regarded as having a structure with a hydrogenation rate of 100 mol %, an average value of a methylene chain length of a main chain of the structural unit derived from at least one selected from the group consisting of a conjugated diene compound and isobutylene is 1.0 to 6.0.

Provided is a hydrogenated block copolymer, which is a hydrogenation product of a block copolymer including a polymer block (A) containing more than 70 mol % of a structural unit derived from an aromatic vinyl compound and a polymer block (B) containing 30 mol % or more of a structural unit derived from at least one selected from the group consisting of a conjugated diene compound and isobutylene, the hydrogenated block copolymer being satisfied with the following requirements (1) and (2): Requirement (1): the content of the polymer block (A) in the block copolymer is 1 to 30% by mass; and Requirement (2): when the polymer block (B) is regarded as having a structure with a hydrogenation rate of 100 mol %, an average value of a methylene chain length of a main chain of the structural unit derived from at least one selected from the group consisting of a conjugated diene compound and isobutylene is 1.0 to 6.0.

The invention relates to a copolymer of ethylene and of a 1,3-diene of formula CH.sub.2═CR—CH═CH.sub.2, which copolymer bears a silanol or alkoxysilane function, the symbol R representing a hydrocarbon chain having from 3 to 20 carbon atoms. Such a copolymer improves the compromise between the content of ethylene in the polymer, its crystallinity and the stiffness of a rubber composition containing it.

The invention relates to a copolymer of ethylene and of a 1,3-diene of formula CH.sub.2═CR—CH═CH.sub.2, which copolymer bears a silanol or alkoxysilane function, the symbol R representing a hydrocarbon chain having from 3 to 20 carbon atoms. Such a copolymer improves the compromise between the content of ethylene in the polymer, its crystallinity and the stiffness of a rubber composition containing it.