Thermoplastic elastomer compositions comprising acrylic multigraft copolymers are described. The multigraft copolymers comprise a rubbery polyacrylate backbone and a plurality of randomly spaced glassy polyacrylate side chains. The multigraft copolymers can be prepared using a facile grafting through method that can provide copolymers with enhanced purity. The acrylic multigraft copolymers exhibit microphase separated morphologies and “superelastomeric” properties, including an elongation at break, stress at break, and/or strain recovery behavior that exceeds that of conventional triblock copolymer polyacrylate thermoplastic elastomers.

A (meth)acrylic copolymer (A) having a mass average molecular weight of 50,000 to 1,000,000, in which the (meth)acrylic copolymer (A) is obtained by polymerizing a monomer mixture including a macromonomer (a) that has a number average molecular weight of 500 or more and less than 6000 and a vinyl monomer (b), and preferably includes 7 to 40% by mass of a repeat unit derived from the macromonomer (a), has sufficient coating workability, adhesive holding power and adhesive property as an adhesive composition.

The present invention describes novel macromonomers containing polyisobutene groups and homo- or copolymers thereof.

The present invention describes novel macromonomers containing polyisobutene groups and homo- or copolymers thereof.

There is provided a (meth)acrylic copolymer with which a pressure-sensitive adhesive layer exhibiting excellent low temperature coatability and exhibiting holding power and excellent base material contamination resistance even in a case of being irradiated with a low dose of UV irradiation can be formed. The (meth)acrylic copolymer of the present invention comprises a constituent unit a derived from a macromonomer and a constituent unit b derived from a monomer represented by Formula (b), where a content of the constituent unit b is 0.01% to 25% by mass with respect to a total mass of the (meth)acrylic copolymer. In Formula (b), R.sup.A and R.sup.B each independently represent an alkyl group, a carboxy group, or a halogen atom, n represents an integer of 0 to 5, m represents an integer of 0 to 4, and X represents a (meth)acryloyloxy group or a (meth)acryloyloxyalkyleneoxy group.

There is provided a (meth)acrylic copolymer with which a pressure-sensitive adhesive layer exhibiting excellent low temperature coatability and exhibiting holding power and excellent base material contamination resistance even in a case of being irradiated with a low dose of UV irradiation can be formed. The (meth)acrylic copolymer of the present invention comprises a constituent unit a derived from a macromonomer and a constituent unit b derived from a monomer represented by Formula (b), where a content of the constituent unit b is 0.01% to 25% by mass with respect to a total mass of the (meth)acrylic copolymer. In Formula (b), R.sup.A and R.sup.B each independently represent an alkyl group, a carboxy group, or a halogen atom, n represents an integer of 0 to 5, m represents an integer of 0 to 4, and X represents a (meth)acryloyloxy group or a (meth)acryloyloxyalkyleneoxy group.

A quadripolymer based on host-guest interaction and prepared in the steps including (1) weigh maleic anhydride and dissolve in dichloromethane, add β-phenethylamine dropwise, stir to react for 1 to 3 hours, perform extraction filtration and washing, to obtain N-phenethylmaleamic acid; (2) weigh mono 6-ethylenediamine β-cyclodextrin and maleic anhydride, dissolve in N, N-dimethylformamide, and place at 40° C. for reaction for 3 to 6 hours, the product is precipitated with chloroform, washed and dried under vacuum to obtain maleic anhydride modified mono 6-ethylenediamine β-cyclodextrin; (3) Add acrylamide, acrylic acid, maleic anhydride modified mono 6-ethylenediamine β-cyclodextrin, N-phenethylmaleamic acid, adjust the pH of the solution to 7; introduce nitrogen, add a photoinitiator and place to a photo-initiating device to react 3˜5 hours at a temperature of 10˜30° C. The quadripolymer has good temperature and salt resistance, shear resistance. The raw materials are cheap and easily available. The reaction conditions are mild.

The invention relates to a process for preparing a dispersion of a lipophilic compound in a continuous hydrophilic phase, the morphology of which is submicronic. During the preparation of this dispersion, there is applied, by means of a device which produces a shearing gradient less than 5000 s.sup.−1, a shear stress from 100 to 5000 Pa during the addition of the lipophilic compound in the continuous phase which comprises a rheology-modifying compound selected from anionic copolymers, preferably an anionic polymer, in particular an ASE polymer or a HASE polymer. The dispersed particles of the lipophilic compound are nanometric particles whose size is less than 1 μm. The dispersion, particularly in the form of an emulsion, can be used in numerous fields.

A (meth)acrylic copolymer of the present invention includes at least one constituent unit (A) selected from the group consisting of a constituent unit (A1) having at least one structure (I) represented by Formula (1), Formula (2), or Formula (3), a constituent unit (A2) containing a triorganosilyloxycarbonyl group, and a constituent unit (A3) having at least one structure (III) represented by Formula (4) or Formula (5), a constituent unit (B) derived from a specific polysiloxane block-containing polymerizable monomer (b), and a constituent unit (C) derived from a macromonomer (c).

A (meth)acrylic copolymer of the present invention includes at least one constituent unit (A) selected from the group consisting of a constituent unit (A1) having at least one structure (I) represented by Formula (1), Formula (2), or Formula (3), a constituent unit (A2) containing a triorganosilyloxycarbonyl group, and a constituent unit (A3) having at least one structure (III) represented by Formula (4) or Formula (5), a constituent unit (B) derived from a specific polysiloxane block-containing polymerizable monomer (b), and a constituent unit (C) derived from a macromonomer (c).