Provided herein are antioxidant, thermally-responsive copolymer-based compositions and methods of making and using the compositions, e.g., for treatment of ischemia reperfusion injury in a patient. The copolymer comprises a hydrocarbyl backbone, and a plurality of pendant pyrrolidone, antioxidant radical, polyester oligomer, and N-alkyl amide groups.

Provided herein are antioxidant, thermally-responsive copolymer-based compositions and methods of making and using the compositions, e.g., for treatment of ischemia reperfusion injury in a patient. The copolymer comprises a hydrocarbyl backbone, and a plurality of pendant pyrrolidone, antioxidant radical, polyester oligomer, and N-alkyl amide groups.

The present invention discloses a method for preparing high-melt-strength polylactide resin by two-step reaction, which comprises the following steps: mixing polylactide resin and GMA to obtain a premix; mixing multifunctional reactive monomer, a peroxide initiator and organic solvent to obtain a monomer mixture; and adding the premix and the monomer mixture into a screw extruder in sections, after melting, blending, extruding, cooling, pelletizing and drying to obtain a high melt strength polylactide resin. The method of the present invention has a simple production process, can be adapted to large-scale industrial production, the graft modification reaction is rapid and controllable, and the obtained product is safe without residue and high in purity. The high-melt-strength polylactide resin has a low melt flow index, high complex viscosity and storage modulus, and is a green polymer material with wide application prospects.

The present invention discloses a method for preparing high-melt-strength polylactide resin by two-step reaction, which comprises the following steps: mixing polylactide resin and GMA to obtain a premix; mixing multifunctional reactive monomer, a peroxide initiator and organic solvent to obtain a monomer mixture; and adding the premix and the monomer mixture into a screw extruder in sections, after melting, blending, extruding, cooling, pelletizing and drying to obtain a high melt strength polylactide resin. The method of the present invention has a simple production process, can be adapted to large-scale industrial production, the graft modification reaction is rapid and controllable, and the obtained product is safe without residue and high in purity. The high-melt-strength polylactide resin has a low melt flow index, high complex viscosity and storage modulus, and is a green polymer material with wide application prospects.

Thermoset compositions and methods for forming three-dimensional articles via an additive fabrication process, and articles made therefrom are disclosed herein. In an embodiment, a composition comprises a first network-forming component comprising a TPA-based polyester comprising a backbone and having at least 2 polymerizable groups, one or more first network monomers, and a first network initiator. The backbone of the TPA-based polyester comprises the reaction product of a terephthalic acid and a polyol. The composition may further comprise a second network-forming component.

Thermoset compositions and methods for forming three-dimensional articles via an additive fabrication process, and articles made therefrom are disclosed herein. In an embodiment, a composition comprises a first network-forming component comprising a TPA-based polyester comprising a backbone and having at least 2 polymerizable groups, one or more first network monomers, and a first network initiator. The backbone of the TPA-based polyester comprises the reaction product of a terephthalic acid and a polyol. The composition may further comprise a second network-forming component.

The present invention relates to a resin composition for forming an optical film, an optical film, and a polarizing plate, in which the resin composition for forming an optical film improves adhesion between an antiglare layer and a light-transmitting substrate film and enables the antiglare layer and the optical film to exhibit excellent optical properties such as appropriate haze, low gloss value, and excellent antiglare properties. The composition for forming an optical film is a resin composition for forming an optical film for forming an infiltration layer and an antiglare layer having surface irregularities on a light-transmitting substrate film, and comprises: a binder-forming compound including a polyfunctional (meth)acrylate-based compound having three or more functionalities, and a permeable compound having a hydrophilic functional group and a photo-curable functional group; two or more light-transmitting fine particles having a sub-micron (sub-μm) scale; and a permeable solvent capable of dissolving at least a part of the light-transmitting substrate film, wherein the binder-forming compound and the permeable solvent have a weight ratio of 1:0.04 or more.

The present invention relates to a resin composition for forming an optical film, an optical film, and a polarizing plate, in which the resin composition for forming an optical film improves adhesion between an antiglare layer and a light-transmitting substrate film and enables the antiglare layer and the optical film to exhibit excellent optical properties such as appropriate haze, low gloss value, and excellent antiglare properties. The composition for forming an optical film is a resin composition for forming an optical film for forming an infiltration layer and an antiglare layer having surface irregularities on a light-transmitting substrate film, and comprises: a binder-forming compound including a polyfunctional (meth)acrylate-based compound having three or more functionalities, and a permeable compound having a hydrophilic functional group and a photo-curable functional group; two or more light-transmitting fine particles having a sub-micron (sub-μm) scale; and a permeable solvent capable of dissolving at least a part of the light-transmitting substrate film, wherein the binder-forming compound and the permeable solvent have a weight ratio of 1:0.04 or more.

[Problems] An object of the present invention is to provide a crystalline radical polymerizable composition which is excellent in flowability and is easy to handle. [Solution Means] The crystalline radical polymerizable composition for sealing electrical and electronic component according to the present invention is characterized by comprising at least a crystalline radical polymerizable compound, an inorganic filler, a silane coupling agent, and a radical polymerization initiator. In addition, in a preferred embodiment of the crystalline radical polymerizable composition for sealing electrical and electronic component according to the present invention, the crystalline radical polymerizable compound is characterized by comprising one or more selected from unsaturated polyester, epoxy (meth) acrylate, urethane (meth) acrylate, polyester (meth) acrylate, -polyether (meth) acrylate, radical polymerizable monomer and radical polymerizable polymer.

[Problems] An object of the present invention is to provide a crystalline radical polymerizable composition which is excellent in flowability and is easy to handle. [Solution Means] The crystalline radical polymerizable composition for sealing electrical and electronic component according to the present invention is characterized by comprising at least a crystalline radical polymerizable compound, an inorganic filler, a silane coupling agent, and a radical polymerization initiator. In addition, in a preferred embodiment of the crystalline radical polymerizable composition for sealing electrical and electronic component according to the present invention, the crystalline radical polymerizable compound is characterized by comprising one or more selected from unsaturated polyester, epoxy (meth) acrylate, urethane (meth) acrylate, polyester (meth) acrylate, -polyether (meth) acrylate, radical polymerizable monomer and radical polymerizable polymer.