Patent classifications
C08F290/062
GLYCIDYL (METH)ACRYLATE POLYMER POLYOL STABILIZERS
This invention relates to novel macromers that comprise a polyether polyol having (meth)acrylate unsaturation. These novel macromers are the polymerization product of a glycidyl (meth)acrylate, with a polyether polyol, and optionally, an alkylene oxide, in the presence of a double metal cyanide catalyst. This invention also relates to preformed stabilizers prepared from these macromers, and to polymer polyols prepared from these novel macromers and novel preformed stabilizers. The present invention also relates to processes for preparing these compositions, to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.
GLYCIDYL (METH)ACRYLATE POLYMER POLYOL STABILIZERS
This invention relates to novel macromers that comprise a polyether polyol having (meth)acrylate unsaturation. These novel macromers are the polymerization product of a glycidyl (meth)acrylate, with a polyether polyol, and optionally, an alkylene oxide, in the presence of a double metal cyanide catalyst. This invention also relates to preformed stabilizers prepared from these macromers, and to polymer polyols prepared from these novel macromers and novel preformed stabilizers. The present invention also relates to processes for preparing these compositions, to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.
NETWORK TOUGHENING OF ADDITIVELY MANUFACTURED, HIGH GLASS TRANSITION TEMPERATURE MATERIALS VIA SEQUENTIALLY CURED, INTERPENETRATING POLYMERS
Resins and formulations of individual monomers bearing both vinyl ester and epoxy functionality were either synthesized or formulated such that vinyl ester components capable of polymerizing by photo-induced, free radical polymerization were mixed with step-growth epoxy-amine systems, facilitating sequential cure. The vinyl ester component was photopolymerized using vat photopolymerization (VPP). Additionally, the preparation of bio-based photo curable thermosetting resins that have tailorable thermal and mechanical properties is provided. All monomers and polymers described herein are useful in a variety of applications, including additive manufacturing applications.
NETWORK TOUGHENING OF ADDITIVELY MANUFACTURED, HIGH GLASS TRANSITION TEMPERATURE MATERIALS VIA SEQUENTIALLY CURED, INTERPENETRATING POLYMERS
Resins and formulations of individual monomers bearing both vinyl ester and epoxy functionality were either synthesized or formulated such that vinyl ester components capable of polymerizing by photo-induced, free radical polymerization were mixed with step-growth epoxy-amine systems, facilitating sequential cure. The vinyl ester component was photopolymerized using vat photopolymerization (VPP). Additionally, the preparation of bio-based photo curable thermosetting resins that have tailorable thermal and mechanical properties is provided. All monomers and polymers described herein are useful in a variety of applications, including additive manufacturing applications.
PHOTOCURABLE COLOR CHANGING COMPOSITIONS AND METHOD OF FORMING FEATURES ON A MEMBRANE SURFACE USING THE SAME
Photocurable compositions that have a color change during curing and methods of preparation and use of such compositions. More particularly, the present invention relates to photocurable compositions that that have a color change during curing and are useful for forming topographical features, e.g., spacer features, and/or fold protection coatings on a portion of a membrane surfaces, and particularly on membranes used in osmosis and reverse-osmosis applications, such as membrane filters.
PHOTOCURABLE COLOR CHANGING COMPOSITIONS AND METHOD OF FORMING FEATURES ON A MEMBRANE SURFACE USING THE SAME
Photocurable compositions that have a color change during curing and methods of preparation and use of such compositions. More particularly, the present invention relates to photocurable compositions that that have a color change during curing and are useful for forming topographical features, e.g., spacer features, and/or fold protection coatings on a portion of a membrane surfaces, and particularly on membranes used in osmosis and reverse-osmosis applications, such as membrane filters.
Raw material for cosmetic and oil-in-water emulsion cosmetic comprising core-corona polymer particle
Provided are: a core-corona polymer particle excellent in emulsion stability and feeling of use, and a raw material for a cosmetic and an oil-in-water emulsion cosmetic comprising the particle. Certain embodiments of the present invention provides a core-corona polymer particle obtained by radical-polymerizing a polyethylene oxide macromonomer represented by formula (1) and one or two or more of hydrophobic monomers represented by formulas (2) and (3) under conditions (A) to (D).
Raw material for cosmetic and oil-in-water emulsion cosmetic comprising core-corona polymer particle
Provided are: a core-corona polymer particle excellent in emulsion stability and feeling of use, and a raw material for a cosmetic and an oil-in-water emulsion cosmetic comprising the particle. Certain embodiments of the present invention provides a core-corona polymer particle obtained by radical-polymerizing a polyethylene oxide macromonomer represented by formula (1) and one or two or more of hydrophobic monomers represented by formulas (2) and (3) under conditions (A) to (D).
SOLID POLYMER ELECTROLYTE CONTAINING BORON AND FLUORINE STRUCTURES, AND PREPARATION METHOD AND APPLICATION THEREOF
The preparation method of the solid polymer electrolyte includes the following steps: S1, adding a vinyl boron fluorine monomer, a vinyl polyether monomer, a modified monomer, and a functional polymer into a solvent, adding an initiator for reaction, and after performing a purification treatment to obtain a polymer system B; S2, adding the polymer system B, a lithium salt, a filler, and an auxiliary agent into a solvent, and adding a crosslinking agent to obtain a mixed solution, and coating the mixed solution on a mold uniformly for reaction; S3, obtaining the solid polymer electrolyte. The obtained solid polymer electrolyte, a positive electrode plate, and a negative electrode plate are assembled into a solid-state battery core, and then a tab welding, a heat treatment, and an encapsulation treatment are performed to obtain a lithium ion battery.
SOLID POLYMER ELECTROLYTE CONTAINING BORON AND FLUORINE STRUCTURES, AND PREPARATION METHOD AND APPLICATION THEREOF
The preparation method of the solid polymer electrolyte includes the following steps: S1, adding a vinyl boron fluorine monomer, a vinyl polyether monomer, a modified monomer, and a functional polymer into a solvent, adding an initiator for reaction, and after performing a purification treatment to obtain a polymer system B; S2, adding the polymer system B, a lithium salt, a filler, and an auxiliary agent into a solvent, and adding a crosslinking agent to obtain a mixed solution, and coating the mixed solution on a mold uniformly for reaction; S3, obtaining the solid polymer electrolyte. The obtained solid polymer electrolyte, a positive electrode plate, and a negative electrode plate are assembled into a solid-state battery core, and then a tab welding, a heat treatment, and an encapsulation treatment are performed to obtain a lithium ion battery.