[Problem] To provide a radiation curable resin composition which is suitable as a primary material for optical fibers, while having a high curing rate by means of irradiation of radiation [Solution] A radiation polymerizable composition for forming an optical fiber primary coating layer, said composition containing: (A) a urethane oligomer containing a structure represented by formula (I) (in formula (I), R represents a vinyl group; and * represents a bonding hand); (B) one or more compounds selected from among (i) maleic acid anhydride, (ii) a compound represented by formula (II) (in formula (II), R.sup.I represents a single bond or an alkanediyl group having from 1 to 6 carbon atoms; and R.sup.2 represents a hydrogen atom, a hydroxy group or a specific group represented by formula (II-1) or formula (II-2)), and (iii) a compound represented by formula (III) (in formula (III), R.sup.5 represents an alkanediyl group having from 1 to 6 carbon atoms); and (C) a radiation polymerization initiator.

[Problem] To provide a radiation curable resin composition which is suitable as a primary material for optical fibers, while having a high curing rate by means of irradiation of radiation [Solution] A radiation polymerizable composition for forming an optical fiber primary coating layer, said composition containing: (A) a urethane oligomer containing a structure represented by formula (I) (in formula (I), R represents a vinyl group; and * represents a bonding hand); (B) one or more compounds selected from among (i) maleic acid anhydride, (ii) a compound represented by formula (II) (in formula (II), R.sup.I represents a single bond or an alkanediyl group having from 1 to 6 carbon atoms; and R.sup.2 represents a hydrogen atom, a hydroxy group or a specific group represented by formula (II-1) or formula (II-2)), and (iii) a compound represented by formula (III) (in formula (III), R.sup.5 represents an alkanediyl group having from 1 to 6 carbon atoms); and (C) a radiation polymerization initiator.

A surface covering is provided. The surface covering includes a laminated panel and an ultra-violet (UV) curable surface coating applied to the laminated panel. The ultra-violet (UV) curable surface coating includes a first coating, a second coating, abrasive resistant particles, and an antimicrobial additive. The second coating is a composition distinctive of the first coating, the first coating is cured at a lower energy than the second coating, the second coating is cured at a higher energy to cure both the first coating and the second coating. The abrasive resistant particles include silicon carbide (SiC) particles wherein at least 50% of the silicon carbide (SiC) particles have a particle size of less than 45 m.Math.. The antimicrobial additive selected from a group consisting of N-butyl- 1, 2-benzisothiazolin-3-one, alkyl dimethyl ammonium saccharinates, Zinc 2-pyridinethiol-1-oxide, 10, 10′-Oxybisphenoxarsine (OBPA), 4,5-Dichloro-2-octyl-4isothiazolin-3-one (DCOIT) and mixtures thereof.

A surface covering is provided. The surface covering includes a laminated panel and an ultra-violet (UV) curable surface coating applied to the laminated panel. The ultra-violet (UV) curable surface coating includes a first coating, a second coating, abrasive resistant particles, and an antimicrobial additive. The second coating is a composition distinctive of the first coating, the first coating is cured at a lower energy than the second coating, the second coating is cured at a higher energy to cure both the first coating and the second coating. The abrasive resistant particles include silicon carbide (SiC) particles wherein at least 50% of the silicon carbide (SiC) particles have a particle size of less than 45 m.Math.. The antimicrobial additive selected from a group consisting of N-butyl- 1, 2-benzisothiazolin-3-one, alkyl dimethyl ammonium saccharinates, Zinc 2-pyridinethiol-1-oxide, 10, 10′-Oxybisphenoxarsine (OBPA), 4,5-Dichloro-2-octyl-4isothiazolin-3-one (DCOIT) and mixtures thereof.

Provided is a resin composition from which a three-dimensional molding can be produced at an appropriate speed and with high dimensional accuracy, wherein the obtained three-dimensional molding has high strength. This resin composition is used in a method for producing a three-dimensional molding composed of a cured product of a liquid resin composition by selectively irradiating the liquid resin composition with active energy rays. The resin composition includes at least: a first polymerizable compound, in a liquid state at room temperature, having radical polymerizability; a second polymerizable compound, in a liquid state at room temperature, having no radical polymerizability; and a filler, wherein the surface of the filler is covered with the second polymerizable compound.

Non-sensitizing pressure sensitive adhesives which are useful in medical applications and other uses where an adhesive is in contact with skin are obtained by energy-curing compositions containing one or more acrylate-functionalized compounds and possibly other components which are selected such that the cured adhesive passes an in vitro cytotoxicity test in accordance with ISO 10993-5 (2009).

Non-sensitizing pressure sensitive adhesives which are useful in medical applications and other uses where an adhesive is in contact with skin are obtained by energy-curing compositions containing one or more acrylate-functionalized compounds and possibly other components which are selected such that the cured adhesive passes an in vitro cytotoxicity test in accordance with ISO 10993-5 (2009).

Provided is a photopolymerizable composition comprising a blend of: a) from 40 wt. % to 70 wt. % of at least one urethane component; b) from 25 wt. % to 70 wt % of at least one monofunctional reactive diluent; c) from 0.1 wt. % to 5 wt. % of at least one initiator; and d) from 2 wt. % to 10 wt % of an amine-functional (meth)acrylate monomer of formula (I), C═C—CO—O—R.sub.1—NR.sub.2R.sub.3(I); e) optionally, at least one multiple-functional reactive diluent; f) optionally, from 0.001 wt. % to 1 wt. % of an inhibitor, wherein the wt. % in all instances is based on total weight of the photopolymerizable composition, wherein at least one of R.sub.1, R.sub.2, and R.sub.3 is an alkyl group, and wherein the amine-functional (meth)acrylate monomer is not an amide. Also provided is a process of producing a photopolymerizable composition, the process comprising blending the ingredients of the prior sentence. Further provided is a process of producing a three-dimensional object, the process comprising the steps of: A) depositing the photopolymerizable composition according to the first sentence atop a carrier to obtain a layer of a construction material joined to the carrier which corresponds to a first selected cross section of the precursor; B) depositing additional photopolymerizable composition atop a previously applied layer of the construction material to obtain a further layer of the construction material which corresponds to a further selected cross section of the precursor and which is joined to the previously applied layer, C) repeating step B) until the precursor is formed, wherein the depositing of the photopolymerizable composition at least in step B) comprises introducing energy to a selected region of the photopolymerizable composition corresponding to the respectively selected cross section of the object.

Provided is a photopolymerizable composition comprising a blend of: a) from 40 wt. % to 70 wt. % of at least one urethane component; b) from 25 wt. % to 70 wt % of at least one monofunctional reactive diluent; c) from 0.1 wt. % to 5 wt. % of at least one initiator; and d) from 2 wt. % to 10 wt % of an amine-functional (meth)acrylate monomer of formula (I), C═C—CO—O—R.sub.1—NR.sub.2R.sub.3(I); e) optionally, at least one multiple-functional reactive diluent; f) optionally, from 0.001 wt. % to 1 wt. % of an inhibitor, wherein the wt. % in all instances is based on total weight of the photopolymerizable composition, wherein at least one of R.sub.1, R.sub.2, and R.sub.3 is an alkyl group, and wherein the amine-functional (meth)acrylate monomer is not an amide. Also provided is a process of producing a photopolymerizable composition, the process comprising blending the ingredients of the prior sentence. Further provided is a process of producing a three-dimensional object, the process comprising the steps of: A) depositing the photopolymerizable composition according to the first sentence atop a carrier to obtain a layer of a construction material joined to the carrier which corresponds to a first selected cross section of the precursor; B) depositing additional photopolymerizable composition atop a previously applied layer of the construction material to obtain a further layer of the construction material which corresponds to a further selected cross section of the precursor and which is joined to the previously applied layer, C) repeating step B) until the precursor is formed, wherein the depositing of the photopolymerizable composition at least in step B) comprises introducing energy to a selected region of the photopolymerizable composition corresponding to the respectively selected cross section of the object.

Provided is a composition comprising: A) an aliphatic polyurethane which comprises a reaction product of a first aliphatic polyisocyanate, a first polyol, and a thiol, optionally in the presence of a catalyst, and B) a urethane (meth)acrylate prepolymer, optionally a reactive diluent, and a photoinitiator, wherein the urethane (meth)acrylate prepolymer comprises a reaction product of a second aliphatic polyisocyanate, a second polyol and an acrylate, wherein the reactive diluent comprises a (meth)acrylate monomer, wherein the first aliphatic polyisocyanate and second aliphatic polyisocyanate may be identical or different, and wherein the first polyol and the second polyol may be identical or different. Also provided is a process comprising combining: A) a polyurethane which comprises a reaction product of a first aliphatic polyisocyanate, a first polyol, and a thiol, optionally in the presence of a catalyst, and B) a urethane (meth)acrylate prepolymer, a reactive diluent, and a photoinitiator, wherein the urethane (meth)acrylate prepolymer comprises a reaction product of a second aliphatic polyisocyanate, a second polyol and an acrylate, wherein the reactive diluent comprises a (meth)acrylate monomer, wherein the first aliphatic polyisocyanate and second aliphatic polyisocyanate may be identical or different, and wherein the first polyol and the second polyol may be identical or different. The compositions of the invention may find use in 3D printing applications.