A siloxane-modified latex binder includes a polymerization product of a monomer or a mixture of monomers for producing a latex polymer and a non-hydrolyzable siloxane. The non-hydrolyzable siloxane is represented by Formula (I): wherein: R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, and R.sup.8 are independently hydrogen, alkyl, —O-alkyl, —OH, —S-alkyl, —SH, amino, amido, epoxy, carboxyl, acrylate, (meth)acrylate, cycloalkyl, aryl, alkalyl, polyether, alkenyl, or alkynyl; and n is an integer from 0 to about 300; provided that at least one of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, and R.sup.8 is an alkenyl or alkynyl.

A method of making a release coated article is described comprising: providing a release coating composition comprising at least 50 wt. % of a mixture of ethylenically unsaturated monomers based on the total ethylenically unsaturated components; wherein the mixture comprises monomer(s) with a linear alkyl group with at least 18 carbon atoms, and monomer(s) with a branched alkyl group with 7 to 31 carbon atoms, and crosslinking component(s) comprising at least two ethylenically unsaturated groups. The method comprises applying the release coating to a major surface of a substrate and polymerizing the monomer(s) and crosslinking component(s) of the release coating. The monomer(s) with linear alkyl groups and branched alkyl groups are typically present at a weight ratio such that the release coating is a liquid at 25° C. Also described are release coating compositions and articles.

A method of making a release coated article is described comprising: providing a release coating composition comprising at least 50 wt. % of a mixture of ethylenically unsaturated monomers based on the total ethylenically unsaturated components; wherein the mixture comprises monomer(s) with a linear alkyl group with at least 18 carbon atoms, and monomer(s) with a branched alkyl group with 7 to 31 carbon atoms, and crosslinking component(s) comprising at least two ethylenically unsaturated groups. The method comprises applying the release coating to a major surface of a substrate and polymerizing the monomer(s) and crosslinking component(s) of the release coating. The monomer(s) with linear alkyl groups and branched alkyl groups are typically present at a weight ratio such that the release coating is a liquid at 25° C. Also described are release coating compositions and articles.

A transparent, elastic, and biocompatible 1K silicone for additive manufacturing that can be printed by stereolithographic processes, includes at least 25-75% by weight of a monomeric or oligomeric dimethacrylate based on silicone or silicone urethanes having a viscosity of <100 Pa.Math.s, 20-50% by weight of one or more monomeric/oligomeric cyclic (meth)acrylates having a viscosity of <0.5 Pa.Math.s, 1-25% by weight of silicone oil having a viscosity of <1 Pa.Math.s, 0.5-20% by weight of fillers with a particle size of <100 μm, 0.1-5% by weight of one or a combination of a plurality of photoinitiators whose absorption is in the wavelength range of the laser beam or irradiation source used.

A conductive sheet comprising a conductive substrate layer and a hydrogel layer formed of a silicone hydrogel having a polymer comprising a repeat unit (A) derived from a monomer represented by Formula (I) as a gel skeleton. Provided is a conductive sheet which can maintain adhesiveness and flexibility even when used for a long period of time and can attain high biocompatibility.

##STR00001##

A conductive sheet comprising a conductive substrate layer and a hydrogel layer formed of a silicone hydrogel having a polymer comprising a repeat unit (A) derived from a monomer represented by Formula (I) as a gel skeleton. Provided is a conductive sheet which can maintain adhesiveness and flexibility even when used for a long period of time and can attain high biocompatibility.

##STR00001##

There is provided a resin composition containing a copolymer (A) containing a constitutional unit based on a silicone macromonomer (X) that contains a polyalkylsiloxane unit and a constitutional unit based on a monomer (Y) having a group represented by Formula (1) and a component (B) consisting of a silane compound or a partially hydrolyzed condensate thereof, in which with respect to the total mass of all constitutional units that constitute the copolymer (A), the total of a proportion of the constitutional unit based on the silicone macromonomer (X) and a proportion of the constitutional unit based on the monomer (Y) is 55% by mass or more.

—R.sup.1-M(R.sup.2).sub.r(OR.sup.3).sub.m-r  (1)

Provided are an excellently convenient ultraviolet-curable organopolysiloxane causing no surface curing inhibition even when cured in the atmosphere; a composition containing such organopolysiloxane; and a cured product of such composition. The organopolysiloxane is represented by the following formula (1):

##STR00001##

wherein each R.sup.1 independently represents a monovalent hydrocarbon group having 1 to 10 carbon atoms or a group represented by the following formula (2), each molecule has at least one group represented by the following formula (2), m is a number satisfying 1≤m≤10,000,

##STR00002##

wherein R.sup.2 represents a group having at least one of an acryloyl group, methacryloyl group, acryloyloxyalkyl group or methacryloyloxyalkyl group, R.sup.3 represents a divalent hydrocarbon group having 1 to 20 carbon atoms.

Provided are an excellently convenient ultraviolet-curable organopolysiloxane causing no surface curing inhibition even when cured in the atmosphere; a composition containing such organopolysiloxane; and a cured product of such composition. The organopolysiloxane is represented by the following formula (1):

##STR00001##

wherein each R.sup.1 independently represents a monovalent hydrocarbon group having 1 to 10 carbon atoms or a group represented by the following formula (2), each molecule has at least one group represented by the following formula (2), m is a number satisfying 1≤m≤10,000,

##STR00002##

wherein R.sup.2 represents a group having at least one of an acryloyl group, methacryloyl group, acryloyloxyalkyl group or methacryloyloxyalkyl group, R.sup.3 represents a divalent hydrocarbon group having 1 to 20 carbon atoms.

A multifunctional crosslinking agent includes one or more repeating units of a siloxanyl group or a silyl-alkyl-siloxanyl group, and at least two ethylenically unsaturated reactive end groups. One of the at least two ethylenically unsaturated reactive end groups is a (meth)acrylate-containing reactive end group or an acrylamide-containing reactive end group and the other one is an allyl-containing reactive end group or a vinyl-containing reactive end group. Ophthalmic devices are formed from a polymerization product of a monomeric mixture containing one or more of the multifunctional crosslinking agents, one or more first ophthalmic device-forming comonomers having at least one reactive group that preferentially reacts with the (meth)acrylate-containing reactive end group or the acrylamide-containing reactive end group of the multifunctional crosslinking agent, and one or more second ophthalmic device-forming comonomers having at least one reactive group that preferentially reacts with the allyl-containing reactive end group or the vinyl-containing reactive end group of the multifunctional crosslinking agent.