C08F297/044

LAMINATE PRODUCTION METHOD

A laminate production method is provided which can sufficiently prevent the occurrence of blocking without causing deterioration in the outstanding characteristics of acrylic block copolymers such as adhesive performance, and can also ensure excellent processability during extrusion. The laminate production method includes a step (1) of bringing raw pellets of an acrylic block copolymer (A) into contact with an aqueous dispersion (C) containing acrylic resin particles (B) and no surfactants, the acrylic block copolymer (A) including at least one polymer block (a1) including acrylic acid alkyl ester units and at least one polymer block (a2) including methacrylic acid alkyl ester units, a step (2) of removing water attached to the pellets and thereby obtaining pellets (D), and a step (3) of preparing an adhesive composition using an adhesive feedstock including the pellets (D) from the step (2), and extruding the adhesive composition to form an adhesive layer and thereby producing a laminate including the adhesive layer and a substrate layer.

LAMINATE PRODUCTION METHOD

A laminate production method is provided which can sufficiently prevent the occurrence of blocking without causing deterioration in the outstanding characteristics of acrylic block copolymers such as adhesive performance, and can also ensure excellent processability during extrusion. The laminate production method includes a step (1) of bringing raw pellets of an acrylic block copolymer (A) into contact with an aqueous dispersion (C) containing acrylic resin particles (B) and no surfactants, the acrylic block copolymer (A) including at least one polymer block (a1) including acrylic acid alkyl ester units and at least one polymer block (a2) including methacrylic acid alkyl ester units, a step (2) of removing water attached to the pellets and thereby obtaining pellets (D), and a step (3) of preparing an adhesive composition using an adhesive feedstock including the pellets (D) from the step (2), and extruding the adhesive composition to form an adhesive layer and thereby producing a laminate including the adhesive layer and a substrate layer.

POLYMERIC COMPOSITION COMPRISING A THERMOPLASTIC ELASTOMER WITH BUTADIENE AND STYRENE BLOCKS AND A COMPATIBLE PLASTICIZER

A polymer composition comprises: a) at least one block thermoplastic elastomer comprising at least one elastomer block and at least one thermoplastic block, the elastomer block(s) predominantly comprising units derived from butadiene, the thermoplastic block(s) consisting of units derived from one or more styrene monomers, b) at least one plasticizer selected from butadiene oligomers with: b1) the molar content of 1,2-polybutadiene units in said plasticizer is within a range of from 70% to 130% of that in the elastomer block of the thermoplastic elastomer, and the molar mass of the plasticizer is greater than 1500 and less than 50 000 g/mol, or else b2) the molar content of 1,2-polybutadiene units in the plasticizer is less than 70%, or greater than 130%, of that in the elastomer block of the thermoplastic elastomer, and the molar mass of the plasticizer is greater than 4000 and less than 50 000 g/mol.

BINDER COMPOSITION FOR NON-AQUEOUS SECONDARY BATTERY ELECTRODE, SLURRY COMPOSITION FOR NON-AQUEOUS SECONDARY BATTERY ELECTRODE, ELECTRODE FOR NON-AQUEOUS SECONDARY BATTERY, AND NON-AQUEOUS SECONDARY BATTERY

Provided is a binder composition for a non-aqueous secondary battery electrode that enables production of a slurry composition that can be used in high-speed application and high-speed pressing and that enables formation of an electrode for a non-aqueous secondary battery that can cause a non-aqueous secondary battery to display excellent low-temperature cycle characteristics. The binder composition contains water and a particulate polymer that is formed of a polymer including a block region formed of an aromatic vinyl monomer unit. The particulate polymer has a volume-average particle diameter of not less than 0.08 μm and less than 0.6 μm.

Hot-Melt Adhesive Composition and Manufacturing Method Therefor
20220089921 · 2022-03-24 · ·

A hot melt adhesive composition is provided that includes: a diblock copolymer including a styrene-based monomer-derived unit and a conjugated diene-based monomer-derived unit; a triblock copolymer which is a coupled polymer of the diblock copolymer; and a crosslinked block copolymer including a crosslinking agent-derived crosslinked part crosslinked with two or more of the diblock copolymer and the triblock copolymer. The conjugated diene-based monomer-derived unit includes an isoprene-derived unit and an epoxidized isoprene rubber.

Ultrahigh melt flow styrenic block copolymers
11279821 · 2022-03-22 · ·

A selectively hydrogenated block copolymer of general formula S-E-S, (S-E.sub.1).sub.nX, or mixtures thereof is disclosed, where n has a value of 2-6, and X is a coupling agent residue. Before hydrogenation, S is a polystyrene block having a molecular weight of 4,400-5,600 g/mol, and E and E1 are polydiene blocks having molecular weights of 18,000-36,000 g/mol and 9,000 to 18,000 g/mol, respectively, selected from polybutadiene, polyisoprene and mixtures thereof, and having a total vinyl content of 60-85 mol %. After hydrogenation, the block copolymer has 0-10 percent of styrene double bonds reduced and at least 80 percent of conjugated diene double bonds reduced. The block copolymer has a solution viscosity of less than 80 centipoise (cP); a polystyrene content of 25-40 wt. % and up to 50 wt. % of diblock units of general formula S-E or S-E.sub.1.

Branched Polymers Made Using Multifunctional Coupling Agents

Branched block copolymers, derived from alkenyl aromatic hydrocarbon-1,3-diene monomer system, and branched polyisoprene homopolymers, derived from isoprene, are obtained by polymerization in the presence of an anionic initiator; at a temperature from 0° C. to 100° C.; followed by coupling with a multifunctional coupling agent of formula (R.sup.1O).sub.3Si—Y—Si(OR.sup.2).sub.3, wherein R.sub.1 and R.sub.2 are independently C.sub.1-C.sub.6 alkyl groups; and Y is a C.sub.2-C.sub.8 alkylene group. The polymers thus obtained can be used in many applications, including rubber cements having high solids content and low zero shear viscosities, and for producing aqueous latices therefrom.

Block Copolymer Compositions

A composition comprising selectively hydrogenated block copolymers (a) and (b having peak molecular weights of 150-1,000 kg/mol, 6-60 kg/mol, respectively, is disclosed. Component (a) comprises one or more structures A-B-A, (A-B-A)nX, A-(B-A)n, and (A-B)nX. Component (b) comprises one or more structures C-D, D-C-D, and (D-C)nX. The value of “n” is 1-30, and “X” is a residue of a coupling agent. Before hydrogenation, blocks A and C, are vinyl aromatic polymer blocks; and blocks B and D are polymer blocks comprising 60-100 mol % of one or more conjugated dienes and 0-40 mol % of a vinyl aromatic monomer. The HSBC compositions and TPE blends exhibits good elasticity, good processibility, low extractables, and low compression set.

Block Copolymer Compositions

A composition comprising selectively hydrogenated block copolymers (a) and (b having peak molecular weights of 150-1,000 kg/mol, 6-60 kg/mol, respectively, is disclosed. Component (a) comprises one or more structures A-B-A, (A-B-A)nX, A-(B-A)n, and (A-B)nX. Component (b) comprises one or more structures C-D, D-C-D, and (D-C)nX. The value of “n” is 1-30, and “X” is a residue of a coupling agent. Before hydrogenation, blocks A and C, are vinyl aromatic polymer blocks; and blocks B and D are polymer blocks comprising 60-100 mol % of one or more conjugated dienes and 0-40 mol % of a vinyl aromatic monomer. The HSBC compositions and TPE blends exhibits good elasticity, good processibility, low extractables, and low compression set.

BLOCK COPOLYMER COMPOSITION, HEAT SHRINK FILM USING SAME, AND PACKAGE PROVIDED WITH HEAT SHRINK FILM

A block copolymer composition containing at least one type of block copolymer component obtained by using a vinyl aromatic hydrocarbon and a conjugated diene, wherein the block copolymer composition satisfies the conditions (1) to (3) indicated below. (1) The weight-average molecular weight is at least 100000 and at most 300000, and the conjugated diene content is at least 18 mass % and at most 35 mass %. (2) The vinyl aromatic hydrocarbon block percentage is at least 80% and at most 100% relative to the total amount of the vinyl aromatic hydrocarbon. (3) At least 30 mass % and at most 60 mass % of block copolymer components having a conjugated diene content of at least 30 mass % are included.