A method for formation of a polymer film in-situ according to the invention comprises steps of: providing a polymerizable composition in one or multiple parts; initiating polymerization of the polymerizable composition to form a polymerizing composition; prior to completion of polymerization of the polymerizable composition, forming a film therefrom; and fully polymerizing the polymerizing composition to form the polymer film.

The present disclosure relates generally to polyurethane matrix composite materials, for example, suitable for making an exterior cladding product for houses and other buildings. The present disclosure relates more particularly to a polymer matrix composite material including a polyurethane matrix and an inorganic filler in a range from 45% to 85% by weight of the composite material. The inorganic filler includes a first substance from the group consisting of calcium carbonate, sand, talc, kaolin clay, dolomite, feldspar and mica and any mixture thereof, and fly ash, and/or an iron oxide in a range from 0.5% to 7% by weight of the inorganic filler.

Disclosed is a non-porous molded article for a polishing layer, the non-porous molded article including a thermoplastic polyurethane, wherein the thermoplastic polyurethane has a maximum value of a loss tangent (tan 5) in a range of −70 to −50° C. of 4.00×10.sup.−2 or less. Preferably, the thermoplastic polyurethane is obtained by polymerization of a polymer diol having a number average molecular weight of 650 to 1400, an organic diisocyanate, and a chain extender, and a content ratio of nitrogen derived from an isocyanate group of the organic diisocyanate is 5.7 to 6.5 mass %.

A composition for an automotive interior skin, a method for manufacturing the same, and an automotive interior skin manufactured using the same. The composition for an automotive interior skin includes: 30 wt % to 70 wt % of a polyol compound; 5 wt % to 40 wt % of dicyclohexylmethane-4,4′-diisocyanate; and 5 wt % to 30 wt % of an aromatic glycol-based chain extender.

A polyurethane, in particular a thermoplastic polyurethane, is obtainable or obtained by reacting at least a polyisocyanate composition and a polyol composition. The polyol composition contains at least one polyester diol or polyether diol, having a number-average molecular weight in the range from 500 to 3000 g/mol, and at least one polysiloxane having two terminal isocyanate-reactive functionalities selected from a thio group, a hydroxyl group, and an amino group. A process can be used for preparing this polyurethane, and a molded body containing the polyurethane is useful. Foam beads based on polyurethane can be obtained or obtainable from the polyurethane, and a process can be used for producing foam beads. Corresponding bead foams are useful.

A continuous process forms a unitary mat on a line having at least two conveyors spaced from each other. The process includes combining the isocyanate, an isocyanate catalyst, and a plurality of lignocellulosic particles to form a mixture and a self-polymerization product of the isocyanate in-situ in the mixture. The process also includes forming the unitary mat from the mixture on a first conveyer and transferring the unitary mat from the first conveyor to a second conveyor across a predetermined distance while maintaining structural integrity of the unitary mat. The lignocellulosic particles have a moisture content of 0.5 to 30 weight percent of water. Moreover, the continuous process is free of a step of adding water to the isocyanate, the isocyanate catalyst, the lignocellulosic particles, and/or the unitary mat.

Polyurethane composites and methods of preparing polyurethane composites are described herein. The polyurethane composite can comprise (a) a polyurethane formed by the reaction of (i) one or more isocyanates selected from the group consisting of diisocyanates, polyisocyanates, and mixtures thereof, and (ii) one or more polyols; (b) fly ash comprising 50% or greater by weight, fly ash particles having a particle size of from 0.2 micron to 100 microns; and (c) a coarse filler material comprising 80% or greater by weight, filler particles having a particle size of from greater than 250 microns to 10 mm. The coarse filler material can be present in the composite in an amount of from 1% to 40% by weight, based on the total weight of the composite. The weight ratio of the fly ash to the coarse filler material can be from 9:1 to 200:1.

Thermoplastic polymer compositions having enhanced properties, as well as methods of making and using the same, are provided. Thermoplastic polymers according to some aspects of the present invention may be rigid, but may also be suitable for use in applications requiring a thermoplastic polymer resin. Thermoplastic polymers according to various aspects of the present invention may be useful in preparing shaped articles such as, for example, sheets, films, tubes, preforms, bottles, profiles, and other similar articles.

Thermoplastic polyurethane (TPU) compositions, methods for producing TPU compositions, methods of using TPU compositions, and apparatuses produced therefrom are disclosed. Disclosed TPU compositions include a thermoplastic polyurethane polymer, a heat stabilizer, a flow agent, and a filler material. The filler may be a glass fiber. Disclosed TPU compositions have improved thermal stability and improved flow properties suitable for injection molding of articles of manufacture having a large plurality of fine openings or pores. Articles produced from the composition have superior thermal stability, abrasion resistance, and chemical resistance. Example articles include screening members for vibratory screening machines.

The presently claimed invention provides a continuous process for preparing a polyurethane composition which behaves as a rheology modifier upon addition to paint and coating formulations. The present process employs mixers for homogenization of highly viscous polyurethane polymers and by adjusting the process parameters and reactor conditions in specified ranges obtained a polyurethane composition. The polyurethane composition obtained from the process of the present invention is used as thickener in water-borne paint and coating formulations.