Provided herein is a dual cure resin useful for the production of an object by additive manufacturing, comprising or consisting essentially of: (a) a photoinitiator; (b) not more than 5, 10 or 20 ppm of a polyurethane catalyst (e.g., tin, tertiary amine, bismuth, zinc, zirconium, or nickel catalysts); (c) a polyol; (d) free (i.e., unblocked) polyisocyanate; and (e) blocked polyisocyanate, the isocyanate groups of which are blocked by reaction with an amine (meth)acrylate blocking agent. Methods of making an object with the resin are also provided.

An alkoxylated bio-oil composition is provided. The alkoxylated bio-oil composition may include an alkoxylated bio-oil prepared from an alkoxylation of dewatered bio-oil. A method for preparing an alkoxylated bio-oil composition is provided. A copolymer composition is provided. The copolymer composition may include an alkoxylated bio-oil copolymer unit. A method for preparing a copolymer composition is provided.

The present application provides a storage-stable polyisocyanate composition and a preparation method. The polyisocyanate composition is obtained by selecting one or more diisocyanate from aliphatic diisocyanates and alicyclic diisocyanates, and reacting same with an alcohol compound; the polyisocyanate composition contains an isocyanurate group, a uretdione group, a carbamate group, and an allophanate group; within the polyisocyanate composition, the molar ratio of the carbamate group/(uretdione group+isocyanurate group) is 0.01-0.2, and preferably 0.01-0.1. Compared to existing techniques, the present application has the advantage of a noticeable increase in system viscosity of uretdione polyisocyanate during storage. With the present application, by means of controlling the ratio of the carbamate group/(uretdione group+isocyanurate group) within the system, the increase in viscosity of a product during storage is inhibited, thereby improving the storage stability of the product.

Process for preparing rigid polyurethane or urethane-modified polyisocyanurate foams from polyisocyanates and polyfunctional isocyanate-reactive compounds in the presence of blowing agents wherein the polyfunctional isocyanate-reactive compounds comprise an unmodified or modified novolac polyol and a polyether polyol having a hydroxyl number of between 50 and 650 mg KOH/g obtained by reacting a polyfunctional initiator first with ethylene oxide and subsequently with propylene oxide wherein the propoxylation degree is between 0.33 and 2 mole propylene oxide per active hydrogen atom in the initiator and wherein the molar ratio of ethylene oxide to propylene oxide in said polyether polyol is at least 2.

A polyurethane insulation foam composition is disclosed herein. The polyurethane insulation foam comprises: (i) an isocyanate compound; (ii) an isocyanate reactive compound; (iii) water; (iv) a tertiary amine compound; (v) a hydrophilic carboxylic acid compound; (vi) a halogenated olefin compound; and (vii) optionally, other additives.

A reactive composition for making a PIR comprising foam at an isocyanate index of at least 120, said composition comprising at least an isocyanate composition comprising one or more isocyanate compounds, an isocyanate-reactive composition comprising one or more isocyanate-reactive compounds, at least one PIR promoting catalyst, at least one physical blowing agent with a lambda gas ≤12 mW/m.Math.K at 10° C., at least one CO.sub.2 scavenging compound selected from at least one epoxy compound, and optionally a catalyst promoting epoxy reaction with CO.sub.2 characterized in that the amount of isocyanate-reactive compounds in the reactive composition is at least 10 wt % calculated on the total weight of the reactive composition, or at least more than the amount of epoxy compounds and the molar amount of epoxy compounds in the reactive composition is at least 7.8 times higher than the molar amount of CO.sub.2 formed by the water present in the reactive composition after reaction with isocyanates.

A method for the synthesis of an auxetic polyurethane foam with a defined cell structure and an auxetic polyurethane foam substrate obtainable by a method according to the invention. The method includes mixing a polyol reagent and a foaming reagent, forming a reaction mixture, mixing an isocyanate with the reaction mixture, compressing and/or contracting the isocyanate/reaction mixture, and allowing the compressed and/or contracted isocyanate/reaction mixture to cure.

The present invention provides a two-component polyurethane composition, and belongs to the technical field of high polymer material. The two-component polyurethane composition comprises component A and component B. According to mass percent, the component A comprises 0-100% of high activity polyether polyol, 0-100% of cross-linking agent, 0-40% of chain extender, 0-50% of plasticizer and 0-5% of catalyst; according to mass percent, the component B comprises 0-100% of diphenylmethane diisocyanate and derivative thereof, and 0-50% of plasticizer; and the mass ratio of the component A to the component B is 1:0.1-1:3. The two-component polyurethane composition provided by the present invention has low heat release and excellent mechanical properties.

The present invention provides a two-component polyurethane composition, and belongs to the technical field of high polymer material. The two-component polyurethane composition comprises component A and component B. According to mass percent, the component A comprises 0-100% of high activity polyether polyol, 0-100% of cross-linking agent, 0-40% of chain extender, 0-50% of plasticizer and 0-5% of catalyst; according to mass percent, the component B comprises 0-100% of diphenylmethane diisocyanate and derivative thereof, and 0-50% of plasticizer; and the mass ratio of the component A to the component B is 1:0.1-1:3. The two-component polyurethane composition provided by the present invention has low heat release and excellent mechanical properties.

Solid, non-melting polyurethanes having a glass transition temperature of at least 40° C. and free isocyanate groups are self-bonding materials that are useful in a variety of adhesive and molding operations. Under conditions of heat and moisture, these polyurethanes will self-bond. The polyurethanes can be used as adhesive coatings, which are solid and non-tacky and thus can be transported and stored easily under ambient conditions. These polyurethane adhesives are especially useful in applications in which, due to the location and/or orientation of the substrates, liquid or melting materials cannot be applied easily or will run off the substrates.