A heat resistant thermoplastic polyurethane composition is made by a reaction including a polyol component comprising the reaction of ε-caprolactone initiated with a polydimethylsiloxane and a polyether polyol.

Polymers are disclosed that incorporate portions of secondary or tertiary polyamide segments connected with polyisocyanates. These polymers have enhanced matting properties. The enhanced matting properties are from creating an inherently matt surface from the polymer without the use of any separate fine particle size matting additives. Conventional matting agents such as fine particle size silica usually results in loss of physical properties such as haze development and porosity in the coating from the matting agent. Composites and hybrids of these polymers and other polyamides, polyurethane with vinyl polymers (acrylates) are also disclosed and claimed.

The present invention relates to a novel process for preparing thermoplastically processable polyurethanes, to thermoplastically processable polyurethane obtainable from the process and to compositions, articles and uses of these polyurethanes.

The present invention provides a sheet-like material having soft texture, durability capable of withstanding practical use, and abrasion resistance. The sheet-like material of the present invention is a sheet-like material containing a nonwoven fabric composed of an ultrafine fiber having an average single fiber diameter 0.3 to 7 μm; and an elastic resin, wherein the elastic resin is a polyurethane resin (D) which contains: as essential constituent monomers, a copolymerized polycarbonate diol (A1) which contains a structural unit derived from C3-5 alkane diol (a1) and a structural unit derived from C8-12 alkane diol (a2), the molar ratio of the alkanediol (a2) with respect to the total number of moles of the alkanediol (a1) and the alkanediol (a2) being 50 to 95 mole %; a polycarbonate diol (A2) containing a structural unit derived from a C4-6 alkane diol (a3); an organic diisocyanate (B); and a chain extender (C), and the polyurethane resin (D) satisfies the following conditions (1) to (3): (1) The copolymerized polycarbonate diol (A1) has a heat quantity of fusion (ΔH) o 40 to 100 J/g, the heat quantity of fusion (ΔH) being determined according to a melting point measuring method provided in JIS K7121-1987; (2) The polycarbonate diol (A2) has a heat quantity of fusion (ΔH) of 0 J/g; (3) A difference (ΔTm) in a melting point (Tm) between a mixture (A12) of the copolymerized polycarbonate diol (A1) with the polycarbonate diol (A2) and the copolymerized polycarbonate diol (A1) is 1.5° C. or lower, the melting point (Tm) being determined by a melting point measuring method provided in JIS K7121-1987.

A polymer comprising at least 1% by mole of a structural unit represented by Formula (2); ##STR00001##
in Formula (2), two R.sup.1s are the same or different from each other and are each a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; X is a single bond, an oxygen atom, or a group represented by —COO—, —OOC—, —CONH—, —NH—, —NHCO—, —NR.sup.3—, or —CH.sub.2O—; Y is a single bond or an oligooxyalkylene group; two R.sup.2s are the same or different from each other and are each an alkyl group having 1 to 6 carbon atoms; R.sup.3 is an alkyl group having 1 to 6 carbon atoms; m is an integer of 1 to 10; and n is an integer of 2 to 10; and having a number average molecular weight of 5,000 or more has various characteristics suitable for use in contact with a living organism and can be easily produced.

The present invention relates to a phosphorus containing polyol, obtainable or obtained by a process comprising the reaction of at least one polyol with a phosphorus containing compound of the general formula (I) as defined herein, as well as the process for preparing a phosphorus containing polyol, comprising the reaction of at least one polyol with a phosphorus containing compound of the general formula (I). Furthermore, the present invention relates to the use of a phosphorus containing polyol as disclosed herein as a flame retardant, to a process for the preparation of a polyurethane and the polyurethane as such. ##STR00001##

CMP polishing pads or layers made from a polyurethane reaction product of a reaction mixture comprising (i) a liquid aromatic isocyanate component comprising one or more aromatic diisocyanates or a linear aromatic isocyanate-terminated urethane prepolymer, and (ii) a liquid polyol component comprising a) one or more polymeric polyols, b) from 12 to 40 wt. %, based on the total weight of the liquid polyol component, of a curative mixture of one or more small chain difunctional polyols having from 2 to 9 carbon atoms, a liquid aromatic diamine, wherein the mole ratio of liquid aromatic diamine to the total moles of small chain difunctional polyols and liquid aromatic diamine ranges from 15:85 to 40:60, wherein, the reaction mixture comprises 48 to 68 wt. % hard segment materials.

The present disclosure provides a coating composition comprising an initiator, a radical curable polyurethane having ethylenically unsaturated functional groups, and a liquid phase, wherein the radical curable polyurethane having ethylenically unsaturated functional groups comprises the reaction products of A) a polyol component; B) a polyisocyanate component; C) an isocyanate-reactive surfactant; and D) isocyanate-reactive component having ethylenically unsaturated functional groups. The resulting cured polyurethane coating resists surface damage by fine particles and has at least washable anti-fog properties, if not permanent anti-fog properties. Articles prepared with a coating according to this invention are also disclosed.

Described herein is a compact polyurethane having a density of ≥850 g/l, obtainable by reacting at least the components: i) a polyisocyanate composition; and ii) a polyol composition, including at least one polyether polyol (ii.1) which is obtainable by reacting ii.1.1) a polyol starter with a functionality of 3 to 6 with ii.1.2) propylene oxide and/or butylene oxide, in the presence of a boron-based, fluorine-containing Lewis acid catalyst (ii.1.3), where the polyether polyol (ii.1) has an equivalent molecular weight of 50 to 150 g/mol, and ii.1.4) optionally further auxiliaries and/or additives.

Also described herein are a process for producing such a compact polyurethane and compact polyurethanes obtainable by this process. Also described herein is a method of using such a compact polyurethane for the production of a fiber composite. Also described herein are a corresponding fiber composite material and a process for producing such a fiber composite.

A two-component polyurethane composition including a polyol component and a polyisocyanate component, wherein the polyol component comprises at least one polyester polyol A1 based on dimer fatty acids and/or dimer fatty alcohols having an OH number of 65-350 mg KOH/g, at least one polybutadiene polyol A2 and at least one alkoxylated alkylenediamine A3. The polyurethane composition has high strength and only a minor dependence of the mechanical properties, especially strength, on temperature, especially in the range from −40° C. to +100° C.