A method for preventing hardener compounds to be formed from hardener precursors in an aerosol formulation suitable for use in aerosol for making a paint is disclosed.

Embodiments provide a self-healing coating formulation comprised of a one component waterborne epoxy-amine adduct resin system and a microencapsulated healing agent. The self-healing coating formulation hardens to a protective material upon application to a substrate. Components in the protective material and microencapsulated healing agent are uniquely synergistic with each other such that, upon degradation of the protective material, microcapsule rupture causes release of the healing agent, whereby components of the healing agent react with components of the protective material to increase adhesion maintenance and corrosion resistance of the protective coating.

The invention relates to a composition that is liquid at room temperature, can be fixed by radiation and cured by heat, comprising the following components: (A) an at least bifunctional epoxy-containing compound; (B) an at least bifunctional thiol; (C) a radiation-curable compound; (D) a photoinitiator; (E) a stabilizer blend that contains at least one sulfonyl isocyanate and at least one acid; and (F) a nitrogen compound as an accelerator. The compositions are processable at room temperature over a period of at least 24 h and can be completely cured even at low temperatures.

An amino-functional addition product from the reaction of at least one diamine of the formula (I) with at least one aromatic diepoxide in a stoichiometric ratio in the range of 1.3 to 1.7 mole diamine per 1 mole-equivalent of epoxy groups. The addition product is liquid at room temperature without a diluent and has surprisingly low viscosity. The composition allows the manufacture of low-emission epoxy-resin coatings that have good workability, cure particularly rapidly and with high surface quality in cold and damp conditions, and allow for a wide range of combinations with other amines and diluents.

A surfacing material that can provide improved UV resistance while providing good surface properties. The surfacing material includes a resin layer formed from a curable resin composition containing: (A) one or more cycloaliphatic epoxy resin(s), each having two or more epoxy groups per molecule; (B) an epoxy-amine adduct having two or more epoxy groups per molecule and obtained by a reaction of (i) an epoxy compound having two or more alicyclic epoxy groups per molecule with (ii) an amine compound having two or more amino groups per molecule; (C) a curing agent and/or a catalyst; (D) ceramic microspheres; and (E) a flow control agent in the form of inorganic particles, which are not ceramic microspheres.

An ink jet recording head that includes a substrate having an ejection orifice for ejecting a liquid and a member provided with a recessed portion for accommodating the substrate, the head including a gap formed between a wall of the recessed portion of the member and the substrate, and a sealing material that seals the gap, in which the sealing material contains a cured product of a composition containing at least a hydrogenated bisphenol A type epoxy resin, a solid basic compound, and polythiol.

There is provided a thermosetting powder coating material capable of forming a cured product having excellent workability at coating and high plasticity as well as heat resistance, resulting in heat resistance and crack resistance at bending processing. (A) denotes a bisphenol type epoxy resin having epoxy equivalent weight of 600 to 800 g/eq (not including 800 g/eq), (B) a rubber-modified epoxy resin, (C) a bisphenol type phenyl resin curing agent (D) a compound for activating (C), (D1) an imidazole compound and (D2) an amine-epoxy adduct type compound. The thermosetting powder coating material is composed of a finely pulverized composition. The composition comprises (A), (C) and (D) but does not comprise (B). (D) comprises (D1) and (D2), and a weight ratio of (D2) with respect to (D1) is 1.0 or more and 3.7 or less when (D1) is 1.

Provided is a curative part usable in a two-part curable composition. The curative part includes a liquid amine; a heterogeneous dispersant; and core-shell rubber particles having an elastomeric core and a (meth)acrylic shell. The core-shell rubber particles and the heterogeneous dispersant can be collectively shear-dispersed in the liquid amine such that the core-shell rubber particles are substantially non-aggregated and the curative part is phase-stable over a period of at least 3 months at ambient temperature. Advantageously, large amounts of core-shell rubber particles can thus be incorporated into a cured resin matrix, which can afford significantly enhanced impact performance.

An ionic aqueous epoxy curing agent, a preparation method therefor and the use thereof. The aqueous epoxy curing agent is prepared by reacting the following raw materials in parts by weight: a) 1 part of a polyepoxy compound, b) 1.3-6 parts of a multifunctional compound, c) 0.2 to 1.25 parts of a monoepoxy compound, and d) 0.01 to 0.23 parts of a sultone, wherein the multifunctional compound has four or more active hydrogens. The curing agent obtained has a good hydrophilic effect and very good thinning performance, the paint film prepared by mixing same with an epoxy dispersion has the following advantages: excellent salt spray resistance and water resistance, strong adhesion, high hardness, etc.; in addition, the preparation process of the curing agent is simple, the conditions are mild, and room temperature curing is carried out.

An amine-functional adduct from the reaction of an amine mixture containing at least one diamine of formula (I) and at least one diamine of formula (II) in a weight ratio ranging from 65/35 to 95/5 with at least one diepoxide in a stoichiometric ratio of at least 1. 2 moles of diamine of the formula (I) to 1 mole equivalent of epoxide groups. The adduct is liquid at room temperature without diluent even in the presence of a small excess of diamine and is surprisingly low in viscosity. In addition, it is particularly cost-effective, as it is available from an amine mixture that is technically easy to produce. The adduct enables low-emission or emission-free epoxy resin coatings with surprisingly good workability at surprisingly fast curing, which have a high hardness and low tendency to yellowing, and which hardly tend to blushing-related defects even in cold and humid conditions.