This invention relates to a thermally and/or high-energy radiation curable waterborne or 100% solid coating with high bio-based content. The coating formulation according to the present invention is derived or partially derived from melt polycondensation of a carboxylic acid and a diol with dicyclopentadiene-maleic acid half-ester or nadic acid-maleic acid half-ester or methyl nadic acid-maleic acid half-ester.

A semi-crystalline polyester comprising a repeat unit of the formula:

##STR00001##

wherein A is an aliphatic, aromatic, or heterocyclic group; R.sub.1 is selected from the group consisting of 1,4-butanediol residue and 1,4-cyclohexanedimethanol residue; R.sub.2 is neopentanediol residue; m is between 50 and 99 inclusive; n is between 1 and 50 inclusive; x is between 1 and 200 inclusive; and wherein said semi-crystalline polyester exhibits a minimum crystallization half-time of about 0.3 minutes or greater, or about 0.5 minutes or greater or about 0.6 minutes or greater or about 0.7 minutes or greater is described. The polyesters of the present invention may in various embodiments demonstrate one or more desirable performance characteristics and accordingly are particularly useful in applications and utilities wherein those high levels of performance for such characteristics are required. A process for forming the semi-crystalline polyester is also disclosed.

A semi-crystalline polyester comprising a repeat unit of the formula:

##STR00001##

wherein A is an aliphatic, aromatic, or heterocyclic group; R.sub.1 is selected from the group consisting of 1,4-butanediol residue and 1,4-cyclohexanedimethanol residue; R.sub.2 is neopentanediol residue; m is between 50 and 99 inclusive; n is between 1 and 50 inclusive; x is between 1 and 200 inclusive; and wherein said semi-crystalline polyester exhibits a minimum crystallization half-time of about 0.3 minutes or greater, or about 0.5 minutes or greater or about 0.6 minutes or greater or about 0.7 minutes or greater is described. The polyesters of the present invention may in various embodiments demonstrate one or more desirable performance characteristics and accordingly are particularly useful in applications and utilities wherein those high levels of performance for such characteristics are required. A process for forming the semi-crystalline polyester is also disclosed.

A method for hydrogenating tyrosine derived polyarylates includes dissolving a second polyarylate with DMF in a flask to produce a first solution. A catalyst is added to the first solution to produce a polymer solution. The polymer solution is filtered through a Celite bed to produce a filtrate. The filtrate is added to water and stirred to precipitate the polyarylate.

A semi-crystalline polyester comprising a repeat unit of the formula:

##STR00001##

wherein A is an aliphatic, aromatic, or heterocyclic group; R.sub.1 is selected from the group consisting of 1,4-butanediol residue and 1,4-cyclohexanedimethanol residue; R.sub.2 is neopentanediol residue; m is between 50 and 99 inclusive; n is between 1 and 50 inclusive; x is between 1 and 200 inclusive; and wherein said semi-crystalline polyester exhibits a minimum crystallization half-time of about 0.3 minutes or greater, or about 0.5 minutes or greater or about 0.6 minutes or greater or about 0.7 minutes or greater is described. The polyesters of the present invention may in various embodiments demonstrate one or more desirable performance characteristics and accordingly are particularly useful in applications and utilities wherein those high levels of performance for such characteristics are required. A process for forming the semi-crystalline polyester is also disclosed.

A semi-crystalline polyester comprising a repeat unit of the formula:

##STR00001##

wherein A is an aliphatic, aromatic, or heterocyclic group; R.sub.1 is selected from the group consisting of 1,4-butanediol residue and 1,4-cyclohexanedimethanol residue; R.sub.2 is neopentanediol residue; m is between 50 and 99 inclusive; n is between 1 and 50 inclusive; x is between 1 and 200 inclusive; and wherein said semi-crystalline polyester exhibits a minimum crystallization half-time of about 0.3 minutes or greater, or about 0.5 minutes or greater or about 0.6 minutes or greater or about 0.7 minutes or greater is described. The polyesters of the present invention may in various embodiments demonstrate one or more desirable performance characteristics and accordingly are particularly useful in applications and utilities wherein those high levels of performance for such characteristics are required. A process for forming the semi-crystalline polyester is also disclosed.

A method of producing a liquid crystalline polyester fiber includes subjecting a yarn prepared by melt spinning a liquid crystalline polyester to a solid-phase polymerization after applying inorganic particles (A) and a phosphate-based compound (B) to the yarn. The method can optionally include cleaning the liquid crystalline polyester fiber after the solid-phase polymerization.

A method of producing a liquid crystalline polyester fiber includes subjecting a yarn prepared by melt spinning a liquid crystalline polyester to a solid-phase polymerization after applying inorganic particles (A) and a phosphate-based compound (B) to the yarn. The method can optionally include cleaning the liquid crystalline polyester fiber after the solid-phase polymerization.

A polyarylate resin is represented by general formula (1) shown below. In general formula (1), R.sup.1 represents a hydrogen atom or methyl group. R.sup.2 and R.sup.3 each represent a hydrogen atom or an alkyl group having a carbon number of at least 1 and no greater than 4. R.sup.2 and R.sup.3 are not the same as one another. When R.sup.1 represents a hydrogen atom, R.sup.2 and R.sup.3 are not bonded to one another. When R.sup.1 represents a methyl group, R.sup.2 and R.sup.3 are optionally bonded to one another to form a ring. r and s each represent a number greater than or equal to 0 and less than or equal to 49. t and u each represent a number greater than or equal to 1 and less than or equal to 50. r+s+t+u=100. r+t=s+u. ##STR00001##

A polyarylate resin is represented by general formula (1) shown below. In general formula (1), R.sup.1 represents a hydrogen atom or methyl group. R.sup.2 and R.sup.3 each represent a hydrogen atom or an alkyl group having a carbon number of at least 1 and no greater than 4. R.sup.2 and R.sup.3 are not the same as one another. When R.sup.1 represents a hydrogen atom, R.sup.2 and R.sup.3 are not bonded to one another. When R.sup.1 represents a methyl group, R.sup.2 and R.sup.3 are optionally bonded to one another to form a ring. r and s each represent a number greater than or equal to 0 and less than or equal to 49. t and u each represent a number greater than or equal to 1 and less than or equal to 50. r+s+t+u=100. r+t=s+u. ##STR00001##