The present disclosure relates to a polyester resin blend, a polyester film and a preparation method of the same. The polyester resin blend is capable of providing a heat shrinkable label that is transparent and has excellent shrinkage even if it contains recycled polyethylene terephthalate as well as virgin polyethylene terephthalate. In addition, the heat shrinkable label can be reused while attached to a PET container, etc., and is expected to be useful for providing continuously usable plastics that have been recently attracting attention.

The invention concerns a bottle (1) molded from at least one thermoplastic polymer of at least one Furan Dicarboxylic Acid (FDCA) monomer, preferably 2,5-Furan Dicarboxylic Acid (2,5-FDCA) monomer, and at least one diol monomer, preferably Monoethyleneglycol (MEG) monomer, said bottle, having a main axis (X), being provided with a body (5) and a bottom base (6) extending from a lower end of the body (5). The bottom base (6) comprises:—a peripheral seat (7) defining a laying plane (8);—a concave arch (10) which extends from the periphery of a central zone (11) of the bottom base (6) to the peripheral seat (7), said concave arch (10) having a rounded general shape with a concavity turned towards the outside of the container (1) and the middle point of the central zone (11) being named push-up (11a);—a series of reinforcing grooves (13) which extend radially from the central zone (11) to at least the peripheral seat (7);—base feet (14) located between two adjacent reinforcing grooves (13); According to the invention, the bottle bottom base (6) comprises an offset sitting radius, defined as the distance between the maximum bottle diameter and the contact point of the base feet with the laying plan (8) that is in the range of 5 to 10 mm for a bottle having a diameter (D) between 40 and 150 mm.

The invention concerns a bottle (1) molded from at least one thermoplastic polymer of at least one Furan Dicarboxylic Acid (FDCA) monomer, preferably 2,5-Furan Dicarboxylic Acid (2,5-FDCA) monomer, and at least one diol monomer, preferably Monoethyleneglycol (MEG) monomer, said bottle, having a main axis (X), being provided with a body (5) and a bottom base (6) extending from a lower end of the body (5). The bottom base (6) comprises:—a peripheral seat (7) defining a laying plane (8);—a concave arch (10) which extends from the periphery of a central zone (11) of the bottom base (6) to the peripheral seat (7), said concave arch (10) having a rounded general shape with a concavity turned towards the outside of the container (1) and the middle point of the central zone (11) being named push-up (11a);—a series of reinforcing grooves (13) which extend radially from the central zone (11) to at least the peripheral seat (7);—base feet (14) located between two adjacent reinforcing grooves (13); According to the invention, the bottle bottom base (6) comprises an offset sitting radius, defined as the distance between the maximum bottle diameter and the contact point of the base feet with the laying plan (8) that is in the range of 5 to 10 mm for a bottle having a diameter (D) between 40 and 150 mm.

A resin binder composition for toners, containing a polyester resin A which is a polycondensate A of raw materials A containing an alkylene oxide adduct of bisphenol A, an aromatic dicarboxylic acid compound, a trivalent or higher polyvalent raw material monomer which is at least any one members of a trihydric or higher polyhydric alcohol and a tricarboxylic or higher polycarboxylic acid compound, and an amorphous acid modified product A of an α-olefin polymer having 4 or more carbon atoms and 18 or less carbon atoms, the polyester resin A having a softening point of 120° C. or more and 150° C. or less; and a toner for electrostatic image development, containing these resin binder composition for toners. The resin binder composition for toners of the present invention is suitably used for a toner for electrostatic image development which is usable in development of latent images formed in, for example, electrostatic image development method, electrostatic recording method, electrostatic printing method or the like.

A resin binder composition for toners, containing a polyester resin A which is a polycondensate A of raw materials A containing an alkylene oxide adduct of bisphenol A, an aromatic dicarboxylic acid compound, a trivalent or higher polyvalent raw material monomer which is at least any one members of a trihydric or higher polyhydric alcohol and a tricarboxylic or higher polycarboxylic acid compound, and an amorphous acid modified product A of an α-olefin polymer having 4 or more carbon atoms and 18 or less carbon atoms, the polyester resin A having a softening point of 120° C. or more and 150° C. or less; and a toner for electrostatic image development, containing these resin binder composition for toners. The resin binder composition for toners of the present invention is suitably used for a toner for electrostatic image development which is usable in development of latent images formed in, for example, electrostatic image development method, electrostatic recording method, electrostatic printing method or the like.

The present disclosure relates to a catalyst system to produce crystallizable polyester compositions which comprise residues of terephthalic acid, neopentyl glycol (NRG), 1,4-cyclohexanedimethanol (CHDM), ethylene glycol (EG), and diethylene glycol (DEG), in certain compositional ranges having certain advantages and improved properties including recyclability.

The present disclosure relates to a catalyst system to produce crystallizable polyester compositions which comprise residues of terephthalic acid, neopentyl glycol (NRG), 1,4-cyclohexanedimethanol (CHDM), ethylene glycol (EG), and diethylene glycol (DEG), in certain compositional ranges having certain advantages and improved properties including recyclability.

The present disclosure relates to a catalyst system to produce crystallizable polyester compositions which comprise residues of terephthalic acid, neopentyl glycol (NRG), 1,4-cyclohexanedimethanol (CHDM), ethylene glycol (EG), and diethylene glycol (DEG), in certain compositional ranges having certain advantages and improved properties including recyclability. The present disclosure also relates to a catalyst system to produce crystallizable polyester compositions which comprise residues of recycled terephthalic acid, recycled neopentyl glycol (NRG), recycled 1,4-cyclohexanedimethanol (CHDM), recycled ethylene glycol (EG), and/or recycled diethylene glycol (DEG), in certain compositional ranges having certain advantages and improved properties including recyclability.

The present disclosure relates to a catalyst system to produce crystallizable polyester compositions which comprise residues of terephthalic acid, neopentyl glycol (NRG), 1,4-cyclohexanedimethanol (CHDM), ethylene glycol (EG), and diethylene glycol (DEG), in certain compositional ranges having certain advantages and improved properties including recyclability. The present disclosure also relates to a catalyst system to produce crystallizable polyester compositions which comprise residues of recycled terephthalic acid, recycled neopentyl glycol (NRG), recycled 1,4-cyclohexanedimethanol (CHDM), recycled ethylene glycol (EG), and/or recycled diethylene glycol (DEG), in certain compositional ranges having certain advantages and improved properties including recyclability.

A resin binder composition for toners, containing a polyester resin A having a constituting unit derived from an alcohol component containing an alkylene oxide adduct of bisphenol A and a constituting unit derived from a carboxylic acid component containing an amorphous acid modified product A of an α-olefin polymer having 4 or more carbon atoms and 18 or less carbon atoms; a resin binder composition for toners containing a polyester resin A which is a polycondensate of an alcohol component containing an alkylene oxide adduct of bisphenol A and a carboxylic acid component containing an amorphous acid modified product A of an α-olefin polymer having 4 or more carbon atoms and 18 or less carbon atoms; and a toner for electrostatic image development, containing these resin binder composition for toners. The resin binder composition for toners of the present invention is suitably used for a toner for electrostatic image development which is usable in development of latent images formed in, for example, electrostatic image development method, electrostatic recording method, electrostatic printing method or the like.