Disclosed are biomimetic imageable polymeric materials that include a polymer or copolymer and a covalently-linked contrasting agent where the disclosed films are both bioresorbable and visible by X-ray fluoroscopic imaging and/or magnetic resonance imaging. The invention also provides methods of preparing the polymeric materials and their use in and as implantable medical devices.

This invention relates to a polyester composition comprising: (1) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 70 to about 100 mole % residues of terephthalic acid or esters thereof; (ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; (b) a glycol component comprising: (i) about 10 to about 50 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; (ii) about 50 to about 90 mole % residues of 1,4-cyclohexanedimethanol; wherein the total mole % of the dicarboxylic acid component is 100 mole %, wherein the total mole % of the diol component is 100 mole %; and (2) lithium atoms, gallium atoms, and less than 30 ppm, or less than 20 ppm, or less than 10 ppm, or less than 5 ppm, or less than 2 ppm, or from 0 to 30 ppm, or from 0 to 20 ppm, or from 0 to 10 ppm, or 0 ppm of tin atoms.

A polyester composition comprising: (1) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 70 to about 100 mole % residues of terephthalic acid or esters thereof; (ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; (b) a glycol component comprising: (i) about 10 to about 60 mole % of 2, 2,4,4-tetramethyl-1,3-cyclobutanediol residues; (ii) about 40 to about 90 mole % residues of 1,4-cyclohexanedimethanol; (iii) optionally, residues of at least one modifying glycol; wherein the total mole % of the dicarboxylic acid component of the final polyester is 100 mole %; wherein the total mole % of the glycol component of the final polyester is 100 mole %; and (2) residues comprising titanium atoms and zinc atoms, and less than 30 ppm, or less than 20 ppm, or less than 10 ppm, or less than 5 ppm, or less than 2 ppm, or from 0 to 30 ppm, or from 0 to 20 ppm, or from 0 to 10 ppm, or 0 ppm of tin atoms.

This invention relates to a polyester composition comprising: (1) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 70 to about 100 mole % residues of terephthalic acid or esters thereof; (ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; (b) a glycol component comprising: (i) about 10 to about 50 mole % of 2,2,4,4-tetramethyM,3-cyclobutanediol residues; (ii) about 50 to about 90 mole % residues of modifying glycols; wherein the total mole % of the dicarboxylic acid component is 100 mole %, wherein the total mole % of the diol component is 100 mole %; and (2) lithium atoms, gallium atoms; and, optionally, less than 30 ppm, or less than 20 ppm, or less than 10 ppm, or less than 5 ppm, or less than 2 ppm, or from 0 to 30 ppm, or from 0 to 20 ppm, or from 0 to 10 ppm, or 0 ppm of tin atoms.

The invention discloses a class of new polymers, trans-ring-fused poly(4-hydroxybutyrate)s (RF-P4HB) that exhibit a unique set of properties, including robust thermal stability and mechanical strength, quantitative recyclability to the building block monomers via thermolysis and/or chemical catalysis, and convenient production from the chemical ring-opening polymerization under ambient temperature and pressure. Another unique property is the formation of crystalline stereocomplexed polymers with high melting temperature upon mixing the two enantiomeric RF-P4HB chains via stereocomplexing co-crystallization. This invention also provides the corresponding ring-fused lactone monomer structures that enable the synthesis of the RF-P4HB polymers, through trans-fusing of rings to the parent -butyrolactone ring. Furthermore, a polymerization or copolymerization process for the synthesis of RF-P4HB polymers and copolymers is disclosed.

Disclosed is a biaxially stretched polyester film containing an antimony compound as a catalyst component, and a magnesium compound and a phosphorus compound as additives, in which an amount of metal antimony included in residues on a membrane filter having an average pore diameter of 0.1 m, after a solution in which 1 g of the biaxially stretched polyester is dissolved in 5 ml of hexafluoroisopropanol is filtered by the filter, is 10 to 100 mg per 1 kg of the biaxially stretched polyester.

Disclosed are biomimetic imageable polymeric materials that include a polymer or copolymer and a covalently-linked contrasting agent where the disclosed films are both bioresorbable and visible by X-ray fluoroscopic imaging and/or magnetic resonance imaging. The invention also provides methods of preparing the polymeric materials and their use in and as implantable medical devices.

A composite polyester hot-melt adhesive, a preparation method thereof and a preparation method of an anti-scouring geotextile are provided. The preparation method of the composite polyester hot-melt adhesive includes the following steps: performing an esterification reaction on a dibasic acid and a dihydric alcohol under a protection of nitrogen and an action of a titanium/cobalt composite catalyst, adding a stabilizer for a polycondensation reaction to obtain a polyester hot-melt adhesive, then adding polymethyl methacrylate (PMMA) microspheres for mixing and stirring to obtain the composite polyester hot-melt adhesive. The anti-scouring geotextile is obtained by bonding a polyethylene terephthalate woven fabric with a polypropylene geotextile by the composite polyester hot-melt adhesive. The composite polyester hot-melt adhesive has the advantages of high bonding strength and good anti-impact performance, and the prepared anti-scouring geotextile has the advantages of high anti-scouring strength, good soil conservation performance, strong protection capability and long service life.

The invention relates to a class of difunctional benzoxazine compounds useful as curatives, as well as methods of preparation, and uses thereof. The difunctional benzoxazine compounds comprise two benzoxazine rings, each disubstituted with two furfuryl groups. The two benzoxazine rings may be attached via a hydrocarbyl linker or two benzoxazine moieties may share a common benzene group. The difunctional benzoxazine compounds are capable of self-polymerisation via a ring opening reaction which allows them to act as a curative. In one aspect, the present invention provides a compound of formula (I) below. (I)

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Disclosed is a biodegradable polyester elastomer which is formed by an esterification reaction between an acidic compound and an alcohol compound using a superacidic catalyst. Thereby, the reaction time of the esterification reaction can be reduced remarkably.