There is described a method for the production of a functional polyester having functional group X. The method comprises the step of melt blending a composition comprising (i) a high number average molecular weight (Mn) polyester having a Mn of ≥6,000 Da; and (ii) a functional compound comprising functional group Y which may be the same as functional group X or be different to functional group X but be operable to form functional group X in the functional polyester. The composition is melt blended such that the high Mn polyester and the functional compound react to produce the functional polyester. The high Mn polyester has a Mn that is higher than the Mn of the functional compound. The present invention extends to functional polyesters produced by the method; aqueous, solventborne and powder coating compositions containing the functional polyester, and articles coated with the said coating compositions.

The present disclosure relates to a method and a composition comprising an esterase for enzymatic surface modification of a polyester. The present disclosure also relates to a method of degradation or hydrolysis of an insoluble plant material.

The disclosure provides a functionalized polymer for use in coating compositions and a method for making the functionalized polymer. In some embodiments, the functionalized polymer is a water-dispersible polymer, more preferably a water-dispersible polyester polymer, having one or more side groups including one or more salt groups. Packaging containers (e.g., food or beverage cans) comprising the functionalized polymer and methods of making such containers are also provided.

Polyesters having both α,β-unsaturated groups and moieties containing activated methylene or methine groups, such as those of beta-ketoester and malonate, are curable in the presence of a base catalysts to form crosslinked networks. Formulations based on such polyesters are suitable for use in coatings and cure at temperatures less than 230° C. without the use of isocyanates.

Disclosed herein are polymeric blends suitable for use in non-pneumatic tires, processes for preparing the polymeric blends, and non-pneumatic tires and components thereof incorporating the polymeric blend. The polymeric blends include a thermoplastic polyester elastomer and a crosslinking compound.

Maleate polyester polyols and coatings made from the polyols are disclosed. The polyester polyols comprise recurring units of (a) a digested thermoplastic polyester or an aromatic dicarboxylate source; (b) a diol; (c) 5 to 95 mole % of an α,β-unsaturated monomer; and (d) 5 to 95 mole % of adipic acid, succinic acid, or a mixture thereof, where the mole % ranges for (c) and (d) are based on the combined molar amounts of (c) and (d). The polyols have hydroxyl numbers within the range of 25 to 450 mg KOH/g, an average of 0.5 to 2.5 reactive unsaturation sites per molecule, and a viscosity less than 1500 cP at 75° C. The polyols are thermally curable or energy-curable. Coatings made from the maleate polyester polyols are also described. Traditional coatings based on polyisocyanates and/or (meth)acrylates can be made, in some cases with improved properties and reduced reliance on the acrylate or isocyanate-based components. Surprisingly, the maleate polyester polyols can also be cured directly using UV to produce coatings under ambient conditions without the need for either acrylic or isocyanate functionality, and this allows coating formulators to reduce cost and more easily achieve regulatory compliance without sacrificing important coating properties. Rigid polyisocyanurate and polyurethane foams produced from the maleate polyester polyols have improved fire retardance.

The present invention relates to a composition comprising methylene malonate monomer and polymer and its use in construction field. Particularly, the invention relates to a composition comprising Component I comprising at least one methylene malonate monomer (A), at least one polymer (B) and at least one acidic stabilizer (C), and Component II comprising at least one alkali accelerator, to the preparation thereof, and to the use of the composition as a protective and/or reinforcement material, particularly used in underground constructions.

A resin composition includes: a resin having a first group capable of forming at least two hydrogen bonds; and a photoisomerization compound having a second group capable of forming at least two hydrogen bonds complementarily with the first group and having a moiety that is reversibly isomerized by light.

A method forming a blocked 1,1-dicarbonyl substituted comprises reacting an alkene of a 1,1-dicarbonyl substituted alkene with a blocking Michael addition donor compound such as an alcohol or thiol. The blocked 1,1-dicarbonyl substituted alkene may be polymerized by providing sufficient thermal energy whereby at least portion of the blocked alkenes revert to alkenes and may be addition polymerized or Michael added with a multifunctional Michael addition donor compound (e.g., polyol or polythiol).

A one part, storage stable polymerizable formulation includes a monomeric or oligomeric ethylenically unsaturated polymerizable compound that is at least one of methacrylate esters of polyethylene glycols, 1,6-hexane diol, or polypropylene glycol, 1,3- and 1,4-butylene glycol trimethylol propane trimethacrylate, or ethoxylated bisphenol A dimethacrylate. A second polymerizable compound includes dicyclopentadiene modified oligomers. An organic solvent is present and provides storage stability and upon evaporation of the solvent, a rate of polymerization of the compound accelerates independent of addition of a second part. An alkyd is present that includes an unsaturated fatty acid. An optional additive of at least one of a transition metal cure accelerator, a filler, a plasticizer, a colorant, and a cure inhibitor is present. The formulation is at least 30 total weight percent solids. A process of forming a polymerized coating on an article is also provided.