A one part, storage stable polymerizable formulation includes a monomeric or oligomeric ethylenically unsaturated polymerizable compound that is at least one of methacrylate esters of polyethylene glycols, 1,6-hexane diol, or polypropylene glycol, 1,3- and 1,4-butylene glycol trimethylol propane trimethacrylate, or ethoxylated bisphenol A dimethacrylate. A second polymerizable compound includes dicyclopentadiene modified oligomers. An organic solvent is present and provides storage stability and upon evaporation of the solvent, a rate of polymerization of the compound accelerates independent of addition of a second part. An alkyd is present that includes an unsaturated fatty acid. An optional additive of at least one of a transition metal cure accelerator, a filler, a plasticizer, a colorant, and a cure inhibitor is present. The formulation is at least 30 total weight percent solids. A process of forming a polymerized coating on an article is also provided.

A process for producing unsaturated polyester microparticles comprising: melt-mixing an unsaturated polyester and an oil in an extruder; washing the microparticles with an organic solvent to reduce the amount of oil; and removing the organic solvent to form the microparticles.

The present invention relates to a functional coating obtained from an aqueous coating composition, which composition comprises a pigment and a polymeric binder, wherein the binder has a weight average molecular weight of from 2000 to 50000 g/mole, and an acid value of 40 to 250, and wherein the binder is a polyester comprising a side group introduced by a Diels-Alder and/or pericyclic Ene-reaction, wherein the side group contains an ionic group and/or an ion-forming group.

Maleate polyester polyols and coatings made from the polyols are disclosed. The polyester polyols comprise recurring units of (a) a digested thermoplastic polyester or an aromatic dicarboxylate source; (b) a diol; (c) 5 to 95 mole % of an ,-unsaturated monomer; and (d) 5 to 95 mole % of adipic acid, succinic acid, or a mixture thereof, where the mole % ranges for (c) and (d) are based on the combined molar amounts of (c) and (d). The polyols have hydroxyl numbers within the range of 25 to 450 mg KOH/g, an average of 0.5 to 2.5 reactive unsaturation sites per molecule, and a viscosity less than 1500 cP at 75 C. The polyols are thermally curable or energy-curable. Coatings made from the maleate polyester polyols are also described. Traditional coatings based on polyisocyanates and/or (meth)acrylates can be made, in some cases with improved properties and reduced reliance on the acrylate or isocyanate-based components. Surprisingly, the maleate polyester polyols can also be cured directly using UV to produce coatings under ambient conditions without the need for either acrylic or isocyanate functionality, and this allows coating formulators to reduce cost and more easily achieve regulatory compliance without sacrificing important coating properties. Rigid polyisocyanurate and polyurethane foams produced from the maleate polyester polyols have improved fire retardance.

Provided are an active-energy-ray-curable aqueous resin composition capable of providing excellent coating appearance and excellent adhesion to a substrate, an undercoat agent for an inorganic-material thin film produced using the same, and a molded article produced using the undercoat agent for an inorganic-material thin film. The active-energy-ray-curable aqueous resin composition includes an acryl-modified alkyd resin (A) and a (meth)acryloyl group-containing compound (B) as essential components. The undercoat agent for an inorganic-material thin film is produced using the composition, and the molded article is produced using the undercoat agent for an inorganic-material thin film.

A reactive PSA film that includes: (a) a polymeric film former matrix; (b) one or more reactive components; and (c) a reagent selected from an initiator, a curing agent and an activator. The component (b) is present at a mass fraction of 30%, as based on the sum of (a), (b) and (c). Further, 50 wt % of the film former matrix is a crystallizable polymer which: (i) exhibits a crystallization enthalpy of <1 J/g in a DSC measurement on cooling at 10K/min from at least 30K above a peak temperature of the melting peak of the polymer or 100 C., whichever is greater; and (ii) exhibits a crystallite fusion enthalpy of 15 mJ/mg in its pure state in a first heating curve of a DSC measurement at 10K/min and after storage for one month from 15 to 25 C. and relative humidity from 30 to 70%.

Polyesters having both ?,?-unsaturated groups and moieties containing activated methylene or methine groups, such as those of beta-ketoester and malonate, are curable in the presence of a base catalysts to form crosslinked networks. Formulations based on such polyesters are suitable for use in coatings and cure at temperatures less than 230? C. without the use of isocyanates.

A composition with improved adhesive and sealant properties comprising a pre-polymer comprising a polymeric unit of the general formula (1A1B-).sub.n, wherein A represents a substituted or un-substituted ester, B represents a substituted or un-substituted acid ester comprising at least two acid ester functionalities, and n represents an integer greater than 1, wherein the compositions has a grafted anhydride content of less than about 0.05 mol/mol of polyacid.

In one or more embodiments, the present invention is directed to poly(propylene fumarate) polymers and polymer structures made therefrom (and related methods) that have been end and/or monomer functionalized to add functional groups for post-polymerization modification with bioactive materials or other functional species, preferably through one of many facile click reactions. In some embodiments, end-group functionalization is accomplished via a functionalized initiating alcohol used during polymerization. In some embodiments, functionalization of these poly(propylene fumarate) polymers is accomplished via the functionalization of the propylene oxide monomer precursors, which then form functionalized side-chains on the resulting poly(propylene fumarate) polymers.

A process for producing unsaturated polyester microparticles comprising: melt-mixing an unsaturated polyester and an oil in an extruder; washing the microparticles with an organic solvent to reduce the amount of oil; and removing the organic solvent to form the microparticles.