Patent classifications
C08G64/14
PROCESS FOR PRODUCING POLYCARBONATE USING A REDUCED PHOSGENE EXCESS
The present invention relates to a process for producing polycarbonate according to a phase boundary process, from at least one dihydroxydiaryl alkane, phosgene, at least one catalyst and at least one chain terminator, the process allowing a reduction in the phosgene excess by a specific energy input during the dispersion of the aqueous and organic phases. The process also produces a polycarbonate with a low proportion of oligomers and a low proportion of Di-chain terminator carbonate.
PROCESS FOR PRODUCING POLYCARBONATE USING A REDUCED PHOSGENE EXCESS
The present invention relates to a process for producing polycarbonate according to a phase boundary process, from at least one dihydroxydiaryl alkane, phosgene, at least one catalyst and at least one chain terminator, the process allowing a reduction in the phosgene excess by a specific energy input during the dispersion of the aqueous and organic phases. The process also produces a polycarbonate with a low proportion of oligomers and a low proportion of Di-chain terminator carbonate.
POLYCARBONATE RESIN
A terminally modified polycarbonate resin that has ultraviolet absorbing capability is provided. More specifically, the terminally modified polycarbonate resin has a structure represented by general formula (A) and a constituent unit that is derived from a dihydric phenol. (In general formula (A), R.sub.1 represents a hydrogen atom or an alkyl group having 1-6 carbon atoms; R.sub.2 represents an alkylene group having 1-6 carbon atoms; R.sub.3 represents a hydrogen atom or a methyl group; R.sub.4 represents a hydrogen atom or a halogen atom; and * represents the bonding position to the main chain of the polycarbonate resin.)
##STR00001##
POLYCARBONATE RESIN
A terminally modified polycarbonate resin that has ultraviolet absorbing capability is provided. More specifically, the terminally modified polycarbonate resin has a structure represented by general formula (A) and a constituent unit that is derived from a dihydric phenol. (In general formula (A), R.sub.1 represents a hydrogen atom or an alkyl group having 1-6 carbon atoms; R.sub.2 represents an alkylene group having 1-6 carbon atoms; R.sub.3 represents a hydrogen atom or a methyl group; R.sub.4 represents a hydrogen atom or a halogen atom; and * represents the bonding position to the main chain of the polycarbonate resin.)
##STR00001##
USE OF SULFONIC ACID AS STABILIZER IN POLYCARBONATE
A composition includes a polycarbonate resin formed via an interfacial polymerization process and from 0.05 ppm to 50 ppm of a sulfonic acid. A molded article formed from the composition may exhibit a yellowness index that is less than that of a reference molded article formed from substantially similar polycarbonate composition comprising the polycarbonate resin but in the absence of the sulfonic acid. Methods for forming the molded article in accordance with the above are also described.
USE OF SULFONIC ACID AS STABILIZER IN POLYCARBONATE
A composition includes a polycarbonate resin formed via an interfacial polymerization process and from 0.05 ppm to 50 ppm of a sulfonic acid. A molded article formed from the composition may exhibit a yellowness index that is less than that of a reference molded article formed from substantially similar polycarbonate composition comprising the polycarbonate resin but in the absence of the sulfonic acid. Methods for forming the molded article in accordance with the above are also described.
PROCESS FOR PRODUCING POLYCARBONATE - POINT OF ADDITION OF THE CHAIN TERMINATOR
The present invention relates to a process for producing polycarbonate according to a phase boundary process, from at least one dihydroxydiaryl alkane, phosgene, at least one catalyst and at least one chain terminator, the process producing polycarbonate with a low proportion of oligomers and a low proportion of Di-chain terminator carbonate. The process according to the invention is characterized in that the chain terminator is added to the reaction system at a designated time.
PROCESS FOR PRODUCING POLYCARBONATE - POINT OF ADDITION OF THE CHAIN TERMINATOR
The present invention relates to a process for producing polycarbonate according to a phase boundary process, from at least one dihydroxydiaryl alkane, phosgene, at least one catalyst and at least one chain terminator, the process producing polycarbonate with a low proportion of oligomers and a low proportion of Di-chain terminator carbonate. The process according to the invention is characterized in that the chain terminator is added to the reaction system at a designated time.
Copolycarbonate and method for preparing the same
Provided is a copolycarbonate comprising a first repeating unit of Chemical Formula 1, a second repeating unit of Chemical Formula 2, and a terminal capping group of Chemical Formula 3: ##STR00001##
Also provided are a method of preparing the copolycarbonate and a molded article including the copolycarbonate.
Copolycarbonate and method for preparing the same
Provided is a copolycarbonate comprising a first repeating unit of Chemical Formula 1, a second repeating unit of Chemical Formula 2, and a terminal capping group of Chemical Formula 3: ##STR00001##
Also provided are a method of preparing the copolycarbonate and a molded article including the copolycarbonate.