Patent classifications
C08G65/2636
Method For Cyclically Preparing Polyether Polyol By Using DMC Catalyst
The present disclosure discloses a method for preparing a polyether polyol in a continuous reaction cycle. In the method, a low molecular-weight alcohol is polymerized with an alkylene oxide to obtain a low molecular-weight polymer. The low molecular-weight polymer is used as an initiator to react with the alkylene oxide and the low molecular-weight alcohol in the presence of a DMC catalyst and an acid promoter to obtain an intermediate-target polymer. A portion of the intermediate-target polymer is used for producing the target polymer, and the other portion is recycled for reproduction of the intermediate-target polymer. In the present disclosure, no initiator prepared with a base catalyst is used, and thus the loss of material and the discharge of residue and waste water are reduced. The DMC concentration is kept constant in the target polymer during the production such that the dewatering time and induction time are greatly reduced.
Fluorinated polymer and use thereof in the preparation of hydrophilic membranes (vi)
Disclosed is a fluorinated polymer of the formula: RSP, wherein R is a fluorocarbyl group, S is sulfur, and P is: (i) polyglycerol; (ii) poly(allyl glycidyl ether); (iii) a copolymer of glycidol and allyl glycidyl ether, the copolymer having one or more allyl groups; or (iv) poly(allyl glycidyl ether) or copolymer of glycidol and allyl glycidyl ether, wherein one more of the allyl groups have been replaced with a functional group as described herein. Also disclosed is a method of preparing the fluorinated polymer. The fluorinated polymer finds use in improving the hydrophilicity of porous hydrophobic membranes such as PTFE and PVDF.
Contact lens having sensors and methods for producing the same
A device includes a contact lens, a corneal sensor that includes a circular trace of conduction paths located at or near an outer peripheral edge of the contact lens that surrounds an unobstructed area at a center region of the contact lens, and a connection wire coupled to the corneal sensor and configured to electrically couple to an external data acquisition system. Methods of fabricating the device may include providing a thin device that includes a sensor and a connection wire coupled to the sensor, transferring the sensor to a curvilinear inner surface of a contact lens, feeding the connection wire through the inner surface of the contact lens and out of an outer surface of the contact lens, and performing electrochemical polymerization of a conducting polymer material over the sensor to anchor the sensor to the inner surface of the contact lens.
Method for preparing graphene/PEDOT:PSS solution and method for preparing substrate having graphene/PEDOT:PSS composite transparent conductive film
A method for preparing a graphene/PEDOT:PSS solution and preparing a substrate having a graphene/PEDOT:PSS composite transparent conductive film of the disclosure use graphene and PEDOT:PSS solution for preparing a graphene/PEDOT:PSS solution used for preparing a transparent conductive film. The sources of the materials are wide and the cost is cheap. The graphene/PEDOT:PSS solution can be further used for preparing a graphene/PEDOT:PSS composite transparent conductive film on a substrate. Since a wet coating process, which is cheap and highly efficient, is used for preparing the graphene/PEDOT:PSS composite transparent conductive film, expensive PVD devices can be avoided when preparing ITO films and the cost is lowered. The graphene/PEDOT:PSS composite transparent conductive film prepared in the disclosure has high conductivity and transmittance, such that it can be used in CF substrates for replacing commercial used ITO films. It has great potential applications in flexible devices and wearable devices for its outstanding mechanical properties.
Polymeric dispersants from phenyl glycidyl ether
Copolymers comprising recurring units of a phenyl glycidyl ether and alkylene oxides are disclosed. Some of the copolymers comprise a di- or polyfunctional nucleophilic initiator and recurring units of the phenyl glycidyl ether and an alkylene oxide. The di- or polyfunctional nucleophilic initiator is an alcohol, phenol, amine, thiol, thiophenol, sulfinic acid, or deprotonated species thereof. Other copolymers comprise a monofunctional nucleophilic initiator selected from thiols, thiophenols, aralkylated phenols, sulfinic acids, secondary amines, C.sub.10-C.sub.20 terpene alcohols, and deprotonated species thereof. Pigments dispersions comprising the copolymers are also disclosed. The copolymers meet the growing needs of the industry with their ease of manufacture, diverse structures, and desirable performance attributes for dispersing a wide range of organic and inorganic pigments. Agricultural applications for the copolymers are also disclosed.