The present disclosure relates to the technical field of the production of polyether polyols, and provided is a process for producing a low-odor polyether polyol, the process comprising the following steps: an initial polymerization reaction step, involving: adding an initiator and an alkaline catalyst into a reaction container, and then inputting an epoxy olefin into the reaction container for a polymerization reaction to obtain a mixed material; a circulation distribution polymerization step, involving: taking the mixed material, outputting same, splitting same and then spraying same into the reaction container at a high speed, circulating the above operations while inputting the epoxy olefin and maintaining a rotation speed of 90-105 r/min for stirring the mixed material that has been sprayed into the reaction container, continuing to proceed with the polymerization reaction, and curing same to obtain a crude polyether polyol; and a refining step, involving: taking the crude polyether polyol for a neutralization or dilution treatment to obtain a mixed solution of the crude polyether polyol, then aggregating a mixed solution stream by means of a hydrophilic medium, settling and separating to obtain the low-odor polyether polyol. The production process of the present disclosure has the advantages of a short processing time, a high yield and a low VOC content.

The present invention relates to a method for producing a mixture comprising at least one compound having at least two hydroxy and/or amino groups made of a biomass material. The invention also relates to such a mixture and to the use thereof for producing a polymer such as for example a polyurethane foam.

A polymer represented by the following general formula (I):

##STR00001##

wherein X.sup.1, X.sup.2, and X.sup.3 each represent a chalcogen atom, R.sup.1 and R.sup.2 each independently represent any one selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, and an aralkyl group, R.sup.3 and R.sup.4 each independently represent any one selected from the group consisting of an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, and an aralkyl group, R.sup.5 and R.sup.6 each independently represent any one selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, and an aralkyl group, R.sup.7 represents a hydrogen atom or a methyl group, R.sup.8 represents any one selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, and an aralkyl group, n is any integer, and none of R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are bonded to each other to form a ring structure.

Related are a high-molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether and a preparation method. During preparation, an allyl alcohol raw material and a supported catalyst Rb-NHPA are firstly added into a high-pressure reaction kettle, and it is heated after being replaced with a nitrogen gas; then after the internal temperature of the reaction kettle is raised to a reaction temperature, an ethylene oxide (EO) and propylene oxide (PO) mixture is continuously fed for a reaction; and finally, after the internal temperature of the reaction kettle is reduced, an acetic acid is dropwise added into the reaction kettle so that the crude product of the high-molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether is neutralized to be neutral. The refining process of a polyether is omitted, the process flow is greatly simplified, and the process time is effectively saved. In addition, the supported catalyst Rb-NHP may be recycled.

A macromonomeric stabilizer, a preparation method thereof, a method for preparing a polymeric polyol using same, and the polymeric polyol prepared. Also disclosed are a soft polyurethane foam obtained by foaming a composition of the polymeric polyol prepared and a polyisocyanate, and a molded product comprising the soft polyurethane foam. The preparation method of the macromonomeric stabilizer comprises the following steps: reacting a polyol with a tricarboxylate not comprising a polymerizable ethylenically unsaturated double bond, or a derivative thereof, to form an adduct; and reacting the resulting adduct with an epoxide comprising a polymerizable ethylenically unsaturated double bond. The macromonomeric stabilizer of the present invention has a low viscosity, comprises a plurality of active sites, and can be directly used in subsequent reactions. The preparation method of the macromonomeric stabilizer can be carried out under normal pressure, without the need for end-blocking with ethylene oxide.

A composition comprising water and a polyalkylene glycol having an allyl content of less than 20 ueq/g, which composition has reduced foaming properties and preferably a biodegradability of at least 60% as determined using OECD 301F. The polyalkylene glycol can be made by forming a first intermediate comprising an oxypropylene block by reacting propylene oxide with a polyol initiator in the presence of a Double Metal Cyanide catalyst, and then reacting the first intermediate with ethylene oxide in the presence of a KOH catalyst.

The present invention relates to compounds according to formula (Ia) or formula (Ib);

##STR00001##

##STR00002##

wherein each W is independently selected from the group consisting of H, F, Cl, Br, I and (CY.sub.2).sub.mCY.sub.3; each Y is independently selected from the group consisting of F, Cl, Br and I; each Z is independently selected from the group consisting of H, OH, (CW.sub.2).sub.pCW.sub.3, CY.sub.3, OCW.sub.3, O(CW.sub.2).sub.pCW.sub.3, OCW((CY.sub.2).sub.mCY.sub.3)CWCW.sub.2, (CW.sub.2).sub.pOH, polyalkylene glycol and 15 polyolester; n is an integer from 2 to 49; m is an integer from 0 to 3; p is an integer from 0 to 9; the molecular weight average (Mw) is ≤5500; and the polydispersity index is ≤1.45; compositions comprising these compounds and methods for their production.

A macromonomeric stabilizer, a preparation method thereof, a method for preparing a polymeric polyol using same, and the polymeric polyol prepared. Also disclosed are a soft polyurethane foam obtained by foaming a composition of the polymeric polyol prepared and a polyisocyanate, and a molded product comprising the soft polyurethane foam. The preparation method of the macromonomeric stabilizer comprises the following steps: reacting a polyol with a tricarboxylate not comprising a polymerizable ethylenically unsaturated double bond, or a derivative thereof, to form an adduct; and reacting the resulting adduct with an epoxide comprising a polymerizable ethylenically unsaturated double bond. The macromonomeric stabilizer of the present invention has a low viscosity, comprises a plurality of active sites, and can be directly used in subsequent reactions. The preparation method of the macromonomeric stabilizer can be carried out under normal pressure, without the need for end-blocking with ethylene oxide.

The invention relates to the use of a polymer P as antifoaming agent, the polymer P being a linear polymer prepared by polymerization of monomer chosen from monomer M1, monomer M2, or monomer M1 and monomer M2 monomer M1 having the following formula (I): wherein R.sup.1 and R.sup.2, independently of each other, is chosen from: —a benzyl, —a (C.sub.1-C.sub.12)alkyl group optionally substituted by a —O—(C.sub.1-C.sub.12)alkyl group, and —a (C.sub.3-C.sub.12)cycloalkyl group optionally substituted by a —O—(C.sub.1-C.sub.12)alkyl group, monomer M2 having the following formula (II): wherein R4 represents: a (C.sub.1-C.sub.12)alkyl group or a —CH.sub.2—O—R.sup.5 group, wherein R.sup.5 is chosen from: a benzyl, a (C.sub.1-C.sub.12)alkyl group optionally substituted by a —O(C.sub.1-C.sub.12)alkyl, and a (C.sub.3-C.sub.12)cycloalkyl group optionally substituted by a —O—(C.sub.1-C.sub.12)alkyl group, R.sup.3 represents a (C.sub.1-C.sub.12)alkyl group, or R.sup.3 and R.sup.4 form together, with the carbon atom bearing them, a ((C.sub.3-C.sub.12)cycloalkyl group.

##STR00001##

The disclosure provides a double metal cyanide catalyst, a preparation method and a application method thereof. Besides impurities, there are only two metal elements consisted of zinc and cobalt in the catalyst. The catalyst is obtained by reacting water-soluble metal salts of zinc and cobalt in water-soluble solvents. The catalyst is modified by a mixed acid during synthesis of the catalyst, the mixed acid comprising at least one organic acid and at least one water-soluble inorganic acid. the water-soluble inorganic acid is selected from the group consisting of diluted sulfuric acid and diluted hydrochloric acid, with a pH value being in the range of 0 to 5; and the organic acid is any one or more selected from the group consisting of succinic acid, glutaric acid, phthalic acid, iminodiacetic acid, pyromellitic acid, and 1,2,3,4-butanetetracarboxylic acid.