The present invention relates to a liquid crystal display element including a pair of a substrate arranged opposite to each other, an electrode group disposed on one side or both sides of the pair of substrates facing each other, a plurality of active elements connected to the electrode group, a liquid crystal alignment film disposed on each facing side of the pair of substrates, and a liquid crystal layer interposed between the pair of substrates, wherein the liquid crystal alignment film is manufactured by irradiating linearly polarized light to a film obtained from polyamic acid or a derivative thereof having a photoisomerization structure in the main chain or a film being subject to heat-baking so as to provide alignment-controlling capability, and the liquid crystal layer is a liquid crystal composition having negative () dielectric anisotropy. By the present invention, a liquid crystal display element having improved image sticking characteristics and good alignment stability is provided.

Bis(azo-benzene) diamine monomers and a method of synthesizing the monomers are provided. The bis(azo-benzene) diamine monomers, in combination with amine reactive monomers, form polymers, such as polyimides and copolyimides, having photomechanical and thermomechanical properties.

The present invention provides a liquid crystal display device with reduced power consumption as well as reduced flicker. The liquid crystal display device is one in a transverse electric field mode, including: paired substrates; a photo-alignment film disposed on at least one of the substrates; a horizontal alignment liquid crystal layer disposed between the substrates; and pixels arranged in a matrix form, the liquid crystal layer containing liquid crystal molecules with a bicyclohexyl skeleton and liquid crystal molecules with a difluorobenzene skeleton, the liquid crystal layer having negative anisotropy of dielectric constant, one of the substrates including TFTs disposed in the respective pixels, the TFTs each including a semiconductor layer that contains an oxide semiconductor, the liquid crystal display device having a frame rate of lower than 50 Hz.

Bis(azo-benzene) diamine monomers and a method of synthesizing the monomers are provided. The bis(azo-benzene) diamine monomers, in combination with amine reactive monomers, form polymers, such as polyimides and copolyimides, having photomechanical and thermomechanical properties.

A healable and recyclable polyimide polymer resin includes a chemical structural unit represented by formula (I), which is defined in the description. The chemical structural unit represented by the formula (I) bonds to at least one condensation-polymerizable monomer, so as to form the healable and recyclable polyimide polymer resin, and the condensation-polymerizable monomer is a diamine monomer or a dianhydride monomer.

A healable and recyclable polyimide polymer resin includes a chemical structural unit represented by formula (I), which is defined in the description. The chemical structural unit represented by the formula (I) bonds to at least one condensation-polymerizable monomer, so as to form the healable and recyclable polyimide polymer resin, and the condensation-polymerizable monomer is a diamine monomer or a dianhydride monomer.