The present invention relates to a polyorganosiloxane and a moisture and radiation curable adhesive composition comprising the same, in particular, to a polyorganosiloxane and a moisture and radiation curable adhesive composition used in a liquid optical clear adhesive (LOCA) for handheld device and display (HHDD).

An alkoxysilyl group-containing organic silazane compound having an average composition represented by formula (1) below: ##STR00001##
wherein R.sup.1 is a monovalent hydrocarbon group, R.sup.2 is a divalent hydrocarbon group, Y is a group represented by formula (6) or (7) below: ##STR00002##
wherein R.sup.3, R.sup.4, and R.sup.6 are a monovalent hydrocarbon group, X is an oxygen atom or a divalent hydrocarbon group, p is an integer of 0 to 9, and n is 0, 1, or 2, R.sup.5 is a monovalent hydrocarbon group, m is 0 or 1, r is 0, 1, or 2, and a and b are numbers which satisfy 0<a≤1, 0≤b<1, and a+b=1.

A curable organosilicon resin composition includes; (A) an organopolysiloxane having a resin structure containing 10 to 60 mol % of an R.sup.1SiO.sub.3/2 unit, 30 to 80 mol % of an (R.sup.2).sub.2SiO.sub.2/2 unit, and 1 to 30 mol % of an (R.sup.3).sub.3SiO.sub.1/2 unit. At least a part of the (R.sup.2).sub.2SiO.sub.2/2 unit is in continuous repeating units with the average number of the repeating units being 3 to 80. The organopolysiloxane has a weight average molecular weight of 5,000 to 50,000; the amount of the hydroxy groups bonded to silicon atoms is 0.001 to 1.0 mol/100 g; and the amount of the alkoxy groups, each having 1 to 10 carbon atoms, bonded to silicon atoms is 1.0 mol/100 g or less. A curable organosilicon resin composition has excellent workability, can give a cured product rapidly, and can make the cured product excellent in mechanical properties, heat resistance, crack resistance, and adhesive property, the surface tackiness being suppressed.

The present invention relates to a polysiloxane copolymer including a structural unit derived from a siloxane-based polymer and a structural unit derived from a silane-based monomer, and a method for preparing the same. The polysiloxane copolymer of the present invention has excellent heat resistance, flexibility, transparency, photosensitivity, durability and the like, and may be widely used as a material in an optical field or/and an electronic field.

A self-adhesive multi-layer item comprising: 1) a dorsal support DO having a top face SI1 and a bottom face SI2, 2) at least one layer of silicone release coating RC applied to the top face SI1 of the dorsal support DO and which is prepared by irradiation of a curable silicone composition C not containing any solvent and comprising, as constituents: a) at least one functionalized organopolysiloxane A b) an effective amount of at least one type I photoinitiator P of the family of acylphosphine oxide derivatives of formula (III) 3) at least one adhesive PSA, preferably at least one pressure-sensitive adhesive PSA, applied on the layer of silicone release coating, 4) a frontal support FR applied on the adhesive PSA of the component 3), and 5) optionally at least one layer of silicone release coating RC applied on the bottom face SI2 of the dorsal support DO and which is prepared by application and irradiation of said curable silicone composition C, and on this same layer, there is at least one adhesive PSA, preferably at least one pressure-sensitive adhesive PSA.

A self-adhesive multi-layer item comprising: 1) a dorsal support DO having a top face SI1 and a bottom face SI2, 2) at least one layer of silicone release coating RC applied to the top face SI1 of the dorsal support DO and which is prepared by irradiation of a curable silicone composition C not containing any solvent and comprising, as constituents: a) at least one functionalized organopolysiloxane A b) an effective amount of at least one type I photoinitiator P of the family of acylphosphine oxide derivatives of formula (III) 3) at least one adhesive PSA, preferably at least one pressure-sensitive adhesive PSA, applied on the layer of silicone release coating, 4) a frontal support FR applied on the adhesive PSA of the component 3), and 5) optionally at least one layer of silicone release coating RC applied on the bottom face SI2 of the dorsal support DO and which is prepared by application and irradiation of said curable silicone composition C, and on this same layer, there is at least one adhesive PSA, preferably at least one pressure-sensitive adhesive PSA.

A one-part room temperature vulcanisable (RTV) silicone composition containing a catalyst comprising (i) a titanate and/or zirconate and (ii) a metal carboxylate salt which cures to a silicone elastomer which may be used as a clear sealant which avoids discolouration and loss of adhesion upon aging.

A one-part low modulus room temperature vulcanisable (RTV) silicone composition containing a catalyst comprising (i) a titanate and/or zirconate and (ii) a metal carboxylate salt which cures to a low modulus silicone elastomer which may be used as a non-staining (clean) sealant having high movement capability.

A radiation sensitive composition including a siloxane polymer exhibiting phenoplast crosslinking reactivity as a base resin, which is excellent in resolution and can be used as a radiation sensitive composition capable of allowing a pattern having a desired-shape to be formed with sufficient precision. A radiation sensitive composition including as a silane, a hydrolyzable silane, a hydrolysis product thereof, or a hydrolysis-condensation product thereof; and a photoacid generator, in which the hydrolyzable silane includes hydrolyzable silanes of Formula (1)
R.sup.1.sub.aR.sup.2.sub.bSi(R.sup.3).sub.4-(a+b)  Formula (1)
wherein R.sup.1 is an organic group of Formula (1-2) ##STR00001##
and is bonded to a silicon atom through a Si—C bond or a Si—O bond, and R.sup.3 is a hydrolyzable group; and Formula (2)
R.sup.7.sub.cR.sup.8.sub.dSi(R.sup.9).sub.4-(c+d)  Formula (2)
wherein R.sup.7 is an organic group of Formula (2-1) ##STR00002##
and is bonded to a silicon atom through a Si—C bond or a Si—O bond, and R.sup.9 is a hydrolyzable group.

A radiation sensitive composition including a siloxane polymer exhibiting phenoplast crosslinking reactivity as a base resin, which is excellent in resolution and can be used as a radiation sensitive composition capable of allowing a pattern having a desired-shape to be formed with sufficient precision. A radiation sensitive composition including as a silane, a hydrolyzable silane, a hydrolysis product thereof, or a hydrolysis-condensation product thereof; and a photoacid generator, in which the hydrolyzable silane includes hydrolyzable silanes of Formula (1)
R.sup.1.sub.aR.sup.2.sub.bSi(R.sup.3).sub.4-(a+b)  Formula (1)
wherein R.sup.1 is an organic group of Formula (1-2) ##STR00001##
and is bonded to a silicon atom through a Si—C bond or a Si—O bond, and R.sup.3 is a hydrolyzable group; and Formula (2)
R.sup.7.sub.cR.sup.8.sub.dSi(R.sup.9).sub.4-(c+d)  Formula (2)
wherein R.sup.7 is an organic group of Formula (2-1) ##STR00002##
and is bonded to a silicon atom through a Si—C bond or a Si—O bond, and R.sup.9 is a hydrolyzable group.