Patent classifications
C08G77/448
POLY(CARBONATE-SILOXANE) COMPOSITIONS WITH IMPROVED APPEARANCE
A poly(carbonate-siloxane) composition comprising: a poly(carbonate-siloxane) copolymer comprising carbonate units and siloxane units, wherein a siloxane content is greater than 25 wt % to less than 70 wt %, based on the total weight of the poly (carbonate-siloxane) copolymer and wherein the weight average molecular weight of the poly (carbonate-siloxane) copolymer is greater than 30,000 g/mol, as measured by gel permeation chromatography using a crosslinked styrene-divinyl benzene column, using polystyrene standards and calibrated for polycarbonate; a homopolycarbonate comprising a bisphenol A homopolycarbonate; a colorant composition comprising an organic colorant, an inorganic pigment, or a combination thereof, wherein the colorant composition optionally comprises titanium dioxide in an amount of 0.8 wt % or less; optionally, a flame retardant; optionally, an anti-drip agent; optionally, an additive composition, wherein an average siloxane domain size is less than 100 nanometers as determined by scanning electron microscopy, nd a molded sample of the poly(carbonate-siloxane) composition is substantially free of pearlescence.
GLASS FIBER REINFORCED POLYCARBONATE COMPOSITE MATERIAL, PREPARATION METHOD AND APPLICATION THEREOF
A glass fiber reinforced polycarbonate composite material, a preparation method and an application thereof; the material includes the following components: component A: 40 parts to 90 parts of a polycarbonate; component B: 1.5 parts to 50 parts of a polysiloxane block copolymer; component C: 5 parts to 60 parts of a glass fiber; component D: 0.1 parts to 30 parts of a phosphorus-containing compound; and component E: 0.01 parts to 30 parts of a polyolefin compound.
POLYCARBONATE-POLYORGANOSILOXANE COPOLYMER
A polycarbonate-polyorganosiloxane copolymer comprises a polycarbonate block (A-1) formed of a repeating unit with a specific structure and a polyorganosiloxane block (A-2) containing a repeating unit with a specific structure. A difference between the haze value (haze A) after retention for 3 minutes and the haze value (haze B) after retention for 20 minutes, of the polycarbonate-polyorganosiloxane copolymer or a resin composition thereof at 300° C. or 340° C., Δhaze, is less than 0.4.
POLYCARBONATE-POLYORGANOSILOXANE COPOLYMER
A polycarbonate-polyorganosiloxane copolymer comprises a polycarbonate block (A-1) formed of a repeating unit with a specific structure and a polyorganosiloxane block (A-2) containing a repeating unit with a specific structure. A difference between the haze value (haze A) after retention for 3 minutes and the haze value (haze B) after retention for 20 minutes, of the polycarbonate-polyorganosiloxane copolymer or a resin composition thereof at 300° C. or 340° C., Δhaze, is less than 0.4.
THERMOPLASTIC RESIN COMPOSITION, METHOD OF PREPARING THE SAME, AND MOLDED ARTICLE INCLUDING THE SAME
The present invention relates to a thermoplastic resin composition, a method of preparing the same and a molded article including the same. More particularly, the thermoplastic resin composition includes a polycarbonate resin having a limited melt flow index, a polyorganosiloxane-polycarbonate resin, a vinyl cyanide compound-conjugated diene rubber-aromatic vinyl compound copolymer, a polyester resin and an epoxy group-containing copolymer in predetermined weight ratios.
Stable quantum dot compositions
A nano-composite includes a thermoplastic copolymer includes a polycarbonate copolymer including repeating siloxane units and a plurality of quantum dots. A method of making a polymer film includes forming a masterbatch composition by combining (1) a first thermoplastic copolymer including a polycarbonate copolymer including repeating siloxane units and (2) a plurality of quantum dots; combining the masterbatch composition with a second thermoplastic polymer to form a mixture; and forming the polymer film from the mixture. The polycarbonate copolymer has a siloxane content of from 15 wt % to 65 wt %.
Stable quantum dot compositions
A nano-composite includes a thermoplastic copolymer includes a polycarbonate copolymer including repeating siloxane units and a plurality of quantum dots. A method of making a polymer film includes forming a masterbatch composition by combining (1) a first thermoplastic copolymer including a polycarbonate copolymer including repeating siloxane units and (2) a plurality of quantum dots; combining the masterbatch composition with a second thermoplastic polymer to form a mixture; and forming the polymer film from the mixture. The polycarbonate copolymer has a siloxane content of from 15 wt % to 65 wt %.
FLAME-RETARDANT, GLASS FIBER-CONTAINING MOLDING COMPOUNDS CONTAINING SILOXANE-CONTAINING POLYCARBONATE BLOCK CO-CONDENSATE
The present invention relates to flame-retardant moulding compositions comprising glass fibre and siloxane-containing polycarbonate block cocondensate, and also to a process for the production of these moulding compositions. The invention further relates to the use of these flame-retardant moulding compositions in injection-moulding and extrusion applications.
FLAME-RETARDANT, GLASS FIBER-CONTAINING MOLDING COMPOUNDS CONTAINING SILOXANE-CONTAINING POLYCARBONATE BLOCK CO-CONDENSATE
The present invention relates to flame-retardant moulding compositions comprising glass fibre and siloxane-containing polycarbonate block cocondensate, and also to a process for the production of these moulding compositions. The invention further relates to the use of these flame-retardant moulding compositions in injection-moulding and extrusion applications.
Polycarbonate-polyorganosiloxane copolymer and method for continuously producing same
Provided are a polycarbonate-polyorganosiloxane copolymer having a carbon tetrachloride concentration of less than 4 ppm by mass, and the following production method for producing the polycarbonate-polyorganosiloxane copolymer. More specifically, provided is a method of continuously producing a polycarbonate-polyorganosiloxane copolymer, the method comprising the steps of: (A) continuously or intermittently taking a polymerization reaction liquid, which is obtained by polymerizing a dihydric phenol compound, a carbonate precursor, and a specific polyorganosiloxane in the presence of an alkaline compound aqueous solution and a water-insoluble organic solvent, out of a reactor; (B) separating the polymerization reaction liquid taken out in the step (A) into an aqueous phase and a water-insoluble organic solvent phase; (C) washing the water-insoluble organic solvent phase separated in the step (B), followed by separation thereof into an aqueous phase and a water-insoluble organic solvent phase; (D) concentrating the water-insoluble organic solvent phase separated in the step (C); and (E) recovering part or all of the water-insoluble organic solvent removed by evaporation in the step (D), followed by distillation purification thereof in a distillation column, the water-insoluble organic solvent obtained in the step (E) being reused as at least part of the water-insoluble organic solvent in the step (A) or as an extraction solvent for the aqueous phase separated in the step (B), or as both thereof, in the step (E), the distillation purification being performed while a concentration of the polycarbonate-polyorganosiloxane copolymer in a column bottom liquid of the distillation column is controlled to 6% by mass or less.