The present invention relates to a polymer comprising a repeating group having the structure of formula (I)

##STR00001##

wherein R, R.sup.1, R.sup.2, R.sup.3, R.sup.4, X, and s are as described herein and salt thereof. Also disclosed is a process of synthesizing such polymers.

A polyamic acid according to one or more embodiments of the present invention contains a structural unit represented by general formula (1) and a structural unit represented by general formula (2). In general formula (1), the plurality of R.sup.1s are each independently a hydrogen atom, a monovalent aliphatic group or an aromatic group. In general formula (2), the plurality of R.sup.2s are each independently an alkyl group having 1-3 carbon atoms or an aryl group having 6-10 carbon atoms. In general formulas (1) and (2), X is a tetravalent organic group. In general formula (2), the plurality of Ys are each independently an alkylene group having 1-3 carbon atoms or an arylene group having 6-10 carbon atoms, and m is an integer of 51-199.

##STR00001##

A polyamic acid according to one or more embodiments of the present invention contains a structural unit represented by general formula (1) and a structural unit represented by general formula (2). In general formula (1), the plurality of R.sup.1s are each independently a hydrogen atom, a monovalent aliphatic group or an aromatic group. In general formula (2), the plurality of R.sup.2s are each independently an alkyl group having 1-3 carbon atoms or an aryl group having 6-10 carbon atoms. In general formulas (1) and (2), X is a tetravalent organic group. In general formula (2), the plurality of Ys are each independently an alkylene group having 1-3 carbon atoms or an arylene group having 6-10 carbon atoms, and m is an integer of 51-199.

##STR00001##

The present invention is an assembly layer for a flexible device. Within a temperature range of between about 30 C. to about 90 C., the assembly layer has a shear storage modulus at a frequency of 1 Hz that does not exceed about 2 MPa, a shear creep compliance (J) of at least about 610.sup.6 1 /Pa measured at 5 seconds with an applied shear stress between about 50 kPa and about 500 kPa, and a strain recovery of at least about 50% at at least one point of applied shear stress within the range of about 5 kPa to about 500 kPa within about 1 minute after removing the applied shear stress. The assembly layer includes at least one of a polyisoprene, a polybutadiene, an olefin block copolymer, a polyisobutylene, and high alkyl polyolefin.

The present invention is an assembly layer for a flexible device. Within a temperature range of between about 30 C. to about 90 C., the assembly layer has a shear storage modulus at a frequency of 1 Hz that does not exceed about 2 MPa, a shear creep compliance (J) of at least about 610.sup.6 1 /Pa measured at 5 seconds with an applied shear stress between about 50 kPa and about 500 kPa, and a strain recovery of at least about 50% at at least one point of applied shear stress within the range of about 5 kPa to about 500 kPa within about 1 minute after removing the applied shear stress. The assembly layer includes at least one of a polyisoprene, a polybutadiene, an olefin block copolymer, a polyisobutylene, and high alkyl polyolefin.

Various embodiments provide random copolyimides that may possess the mechanical, thermal, chemical and optical properties associated with polyimides yet achieve a low energy surface. In various embodiments, the copolyimides may be prepared using a minor amounts of a diamino terminated fluorinated alkyl ether oligomer and a diamino terminated siloxane oligomer. The various embodiments include processes for making the copolyimides containing fluorine and silicon surface modifying agents and anisotropic coatings and articles of manufacture from them. Thus the coatings and articles of manufacture made with the copolyimides of the various embodiments may be characterized as having an anisotropic fluorine and silicon composition and low surface energy.

Various embodiments provide random copolyimides that may possess the mechanical, thermal, chemical and optical properties associated with polyimides yet achieve a low energy surface. In various embodiments, the copolyimides may be prepared using a minor amounts of a diamino terminated fluorinated alkyl ether oligomer and a diamino terminated siloxane oligomer. The various embodiments include processes for making the copolyimides containing fluorine and silicon surface modifying agents and anisotropic coatings and articles of manufacture from them. Thus the coatings and articles of manufacture made with the copolyimides of the various embodiments may be characterized as having an anisotropic fluorine and silicon composition and low surface energy.

A composition is provided that includes an elastomer and an additive. The additive stabilizes the elastomer, although it may be useful for an alternate or additional purpose. The elastomer can have a moiety according to the general formula: A-B-A or B-A-B. Each A independently comprises a polysiloxane moiety having at least two siloxy (SiO) groups. Each B independently comprises a moiety, or a precursor thereof, having at least one carboxyl group. B is bonded to a silicon atom in A. The elastomer may comprise the reaction product of a reaction of: a first component having at least one reactive group; a second component having at least one reactive group; and a third component having at least two reactive groups reactive with the reactive groups of the first and second components. In addition, a cosmetic composition is provided that includes the elastomer, the additive, and at least one cosmetic component.

Polymers bearing the following structural elements per molecule: (A) an average of at least two alkoxylated (poly)alkylenimine units, said alkylene being selected from C.sub.2-C.sub.10-alkylene and said alkoxylation being selected from ethoxylation, propoxylation, butoxylation and combinations of at least two of the foregoing, (B) at least one polysiloxane unit, and (C) at least one linkage connecting at least two different alkoxylated (poly)alkylenimine units (A) bearing at least one polysiloxane unit (B), each link-age (C) being selected from organic spacers bearing in the range of from 4 to 30 carbon atoms.

Polymers bearing the following structural elements per molecule: (A) an average of at least two alkoxylated (poly)alkylenimine units, said alkylene being selected from C.sub.2-C.sub.10-alkylene and said alkoxylation being selected from ethoxylation, propoxylation, butoxylation and combinations of at least two of the foregoing, (B) at least one polysiloxane unit, and (C) at least one linkage connecting at least two different alkoxylated (poly)alkylenimine units (A) bearing at least one polysiloxane unit (B), each link-age (C) being selected from organic spacers bearing in the range of from 4 to 30 carbon atoms.