Patent classifications
C08G2261/122
Unsymmetrical benzothtadiazole-based random copolymers
A random copolymer comprising the monomer units A, B and C. In this random copolymer A comprises ##STR00001##
B comprises ##STR00002##
and C comprises an aryl group. Additionally, R1 R2, R3 and R4 are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups. X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups.
Polar functional group-partially introduced polymer, preparation method therefor, and organic electronic element containing same
The present invention relates to a polar functional group-partially introduced polymer, a preparation method therefor, and an organic electronic element adopting the same. The organic electronic element of the present invention has excellent photoelectric conversion efficiency and stability and is very advantageous in commercialization, by adopting the polar functional group-partially introduced polymer of the present invention.
BRUSH POLYMERS FOR THERAPEUTIC APPLICATIONS
In an aspect, the invention provides therapeutic agents comprising brush polymers that address challenges associated with conventional administration of free therapeutic peptides. In an embodiment, for example, the invention provides brush polymers incorporating one or more therapeutic peptides as side chain moieties. Therapeutic agents of the invention comprising brush polymers include high-density brush polymers including cross-linked brush polymers and brush block copolymers. In an embodiment, brush polymers of the invention exhibit proteolysis-resistant characteristics and maintain their biological function during formulation and administration. The invention also includes methods of making and using therapeutic agents comprising brush polymers.
BIOFUNCTIONAL THIOPHENE MONOMERS AND POLYMERS THEREOF FOR ELECTRONIC BIOMEDICAL DEVICES
Disclosed herein are functionalized 3,4-alkylenedioxythiophene (ADOT+) monomers represented by a chemical formula (CR.sup.1R.sup.2)(CR.sup.3R.sup.4)(CR.sup.4R.sup.6).sub.xO.sub.2H.sub.2S, wherein x=0 or 1; wherein each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 is independently selected from hydrogen, a hydrocarbyl moiety, and a heteroatom-containing functional group; and wherein at least one of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 comprises the heteroatom-containing functional group selected from an aldehyde, a maleimide, and their derivatives thereof. Also, disclosed herein are aldehyde derivatives represented by (ADOT-CH.sub.2—NH).sub.pY and a maleimide derivative represented by (ADOT-(CH.sub.2).sub.q—N).sub.pZ where p=1-2 and each of Y and Z is a hydrocarbyl moiety or a biofunctional hydrocarbyl moiety. In an embodiment of the ADOT+ monomers, one of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 is replaced by a direct bond to an amide group, an azide group, or an ester group of a biofunctional hydrocarbyl moiety. Also, disclosed herein are polymers and copolymers made therefrom.
MOLECULAR SIEVES MEDIATED UNSATURATED HYDROCARBON SEPARATION AND RELATED COMPOSITIONS, MATERIALS, METHODS AND SYSTEMS
Described herein are compositions having an eight-membered monocyclic unsaturated hydrocarbon, methods and system to separate the eight-membered monocyclic unsaturated hydrocarbon at from a hydrocarbon mixture including additional nonlinear unsaturated C.sub.8H.sub.2m hydrocarbons with 4≤m≤8, by contacting the hydrocarbon mixture with a 10-ring pore molecular sieve having a sieving channel with a 10-ring sieving aperture with a minimum crystallographic free diameter greater than 3 Å and a ratio of the maximum crystallographic free diameter to the minimum crystallographic free diameter between 1 and 2, the molecular sieve having a T1/T2 ratio ≥20:1 wherein T1 is an element independently selected from Si and Ge, and T2 is an element independently selected from Al, B and Ga, the 10-ring pore molecular sieve further having a counterion selected from NH.sub.4.sup.+, Li.sup.+, Na.sup.+, K.sup.+ and Ca.sup.++.
Materials for electronic devices
The present application relates to a polymer containing at least one structural unit of a formula (I). The polymer is suitable for use in an electronic device.
Liquid hydrocarbon-based copolymers bearing two cyclocarbonate ester end groups
1) Hydrocarbon-based copolymer comprising two end groups preceded by an ester function and chosen from a 2-oxo-1,3-dioxolan-4-yl (or cyclocarbonate), a dithiocyclocarbonate, an exo-vinylene cyclocarbonate and a 2-oxo-1,3-dioxolen-4-yl, the main chain of which comprises units (I) and (II) ##STR00001## in which R.sup.0 is notably a methyl radical; and the number-average molecular mass Mn of which is between 400 and 100 000 g/mol. 2) Process for preparing said copolymer, comprising: (i) a step of heating a statistical bipolymer A chosen from a poly(butadiene-isoprene), a poly(butadiene-myrcene) and a poly(butadiene-farnesene); and then (ii) a step of heating the product formed, in the presence of a chain-transfer agent. 3) Use as adhesive, as a mixture with an amine compound comprising at least two amine groups.
Liquid copolymer formed by ring-opening copolymerization of cyclopentene, crosslinkable composition, and crosslinked rubber object
A liquid cyclopentene ring-opened copolymer includes a monomer unit derived from cyclopentene and a monomer unit derived from a norbornene compound, the monomer unit derived from cyclopentene being present in an amount of 60 to 95 wt %, the liquid cyclopentene ring-opened copolymer having a hydroxyl group-terminated copolymer chain and having a melt viscosity at 25° C. of less than 500 Pa.Math.s, which is measured using a B-type viscometer.
Fabrics with Interpenetrating Polymer Networks of Breathable Elastomeric Composites for Nanoscale Diffusion Control and Protection
An interpenetrating network (IPN) polymer membrane material includes a soft polyurethane interspersed with a crosslinked conducting polymer. The material can be reversibly “switched” between its oxidized and reduced states by the application of a small voltage, ˜1 to 4 volts, thus modulating its diffusivity.
Modulating Fabric Diffusivity Using Tether-Containing Conducting Polymers
An interpenetrating network (IPN) polymer membrane material includes a soft polyurethane interspersed with a crosslinked conducting polymer. The material can be reversibly “switched” between its oxidized and reduced states by the application of a small voltage, ˜1 to 4 volts, thus modulating its diffusivity.