C08G2261/132

Method for removing a pollutant from aqueous solution with a crosslinked polymer

A crosslinked resin made up of polymerized units of a linear polyamine with at least 3 primary and/or secondary amine functionalities and a bisacrylamide. The crosslinked polymers are porous spherical particles with a BET surface area in the range of 50-120 m.sup.2/g. A method of the synthesizing the crosslinked polymer is specified. A method for using the crosslinked resin as an adsorbent material in removing pollutants including organic dyes (e.g. Congo red, Rhodamine B) and heavy metals from an aqueous solution or an industrial wastewater sample is also described.

Bottlebrush copolymers and uses thereof

Materials (e.g., particles, hydrogels) that provide extended release of one or more therapeutic agents are useful platforms for drug delivery. In part, the present invention relates to new triblock (ABC) bottlebrush copolymers which can be used in the formulation of particles and hydrogels for the extended release of therapeutic agents. In certain embodiments, the triblock bottlebrush copolymers, particles, and hydrogels described herein are thermally-responsive and gel at physiological temperature (e.g., upon administration to a subject), providing injectable and/or implantable gels which can be used for extended release drug delivery. The present invention also provides methods for extended release drug delivery, and methods of treating and/or preventing a disease or conditions in a subject, using the inventive copolymers, particles, and hydrogels. In addition, the present invention provides methods of preparing the triblock bottlebrush copolymers described herein.

Fluorescent porous organic nanosheets for chemical sensing

Disclosed herein is a porous polymeric material having a repeating unit according to Formula (I) or (IV), wherein each of A and E has a π conjugated system and each of X and G contain a flexible tetraphenylethylene (TPE) group. Also disclosed herein are fluorescent chemical sensors or biosensors or environmental monitoring assays or nanosheets or composite materials that include the polymer, and a method of detecting a volatile organic chemical or a metal ion in solution phase. ##STR00001##

Cyclopentene ring-opening copolymer and method of producing the same

A cyclopentene ring-opening copolymer having a branch structure contains a structure in which at least four cyclopentene ring-opening polymer chains are linked via a branch-structural unit. At least part of the cyclopentene ring-opening polymer chains is terminally modified.

SHAPING MATERIAL AND SHAPED PRODUCT
20210301079 · 2021-09-30 · ·

Provided is a shaping material with which a shaped product having excellent flame retardancy can be formed. The shaping material contains a hydrogenated cycloolefin ring-opened polymer and an organophosphinate flame retardant. The organophosphinate flame retardant is either or both of a compound indicated by the following formula (I) and a compound indicated by the following formula (II). Moreover, the organophosphinate flame retardant has an average dispersion diameter of 10 μm or less.

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Methanesulfonic Acid Mediated Solvent Free Synthesis of Conjugated Porous Polymer Networks
20210230359 · 2021-07-29 ·

The present disclosure relates to synthesis of porous polymer networks and applications of such materials. The present disclosure relates to a method of fabricating of a porous polymer network comprising: (a) providing: (i) a first reactant comprising a plurality of compounds comprising at least one acetyl group, said plurality of compounds comprising at least one compound type, and (ii) a second reactant comprising an alkylsulfonic acid, and (b) creating a solution of said reactants, (c) casting said solution in a form, and (d) treating said solution under such conditions so as to produce a porous polymer network. In one embodiment, the invention relates to a porous polymer network which has a basic structure selected from the group consisting of

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Metalloporphyrin 2D-sheets for efficient photo- and electro- catalytic splitting of water

The present invention disclosed a novel squaraine linked metalloporphyrin based 2D sheet polymer catalyst of formula (I), process for preparation thereof and use of said catalyst for efficient photo- and electro-catalytic splitting of water. ##STR00001##

Functional Bottlebrush Polymers
20210130525 · 2021-05-06 ·

An example of a bottlebrush polymer has a polymer backbone and a plurality of individual brush moieties bonded to the polymer backbone. The individual brush moieties include a ketone, a hydrophilic segment, and a surface adhesive terminal group. The brush moieties can be functionalized and/or cross-linked.

CROSSLINKED RESIN, SYNTHESIS THEREOF, AND USE FOR REMOVING ORGANIC DYES

A crosslinked resin made up of polymerized units of a linear polyamine with at least 3 primary and/or secondary amine functionalities and a bisacrylamide. The crosslinked polymers are porous spherical particles with a BET surface area in the range of 50-120 m.sup.2/g. A method of the synthesizing the crosslinked polymer is specified. A method for using the crosslinked resin as an adsorbent material in removing pollutants including organic dyes (e.g. Congo red, Rhodamine B) and heavy metals from an aqueous solution or an industrial wastewater sample is also described.

METHOD FOR SYNTHESIZING POLYOLEFIN MATERIAL WITH CONTROLLED DEGREE OF BRANCHING

A method for synthesizing polyolefin materials with a controlled degree of branching includes the following steps: polymerizing cyclic olefin monomers under catalyst conditions. The cyclic olefin monomer is shown in formula I, where n0, n is an integer. By changing monomers and reaction parameters such as reaction temperature, solvent type, catalyst concentration, monomer concentration and reaction time, the degree of branching, the molecular weight and molecular weight distribution of polyolefin can be controlled. Compared with the existing process, the present invention is a new polymerization process, which can prepare the hyperbranched polyolefin with precise and controllable branching structure. The polyolefin material prepared according to the present invention has advantages of a controlled degree of branching, low viscosity and good fluidity, which has broad application in coating, lubricant, polymer and process flow improvement technologies.