The invention relates to novel organic semiconducting (OSC) random copolymers containing a halo-substituted 4,8-dithiophenyl-benzodithiophene unit and a benzodithiophene-dione unit, to methods for their preparation and educts or intermediates used therein, to compositions and formulations containing them, to the use of the copolymers and compositions as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices, perovskite-based solar cell (PSC) devices, organic photodetectors (OPD), organic field effect transistors (OFET) and organic light emitting diodes (OLED), and to OE devices comprising these copolymers or compositions.

A composition which is useful for producing a light emitting device having excellent light emission efficiency and a light emitting device containing the composition are described. The light emitting device contains an anode, a cathode, and an organic layer disposed between the anode and the cathode and contains a composition containing a metal complex represented by the formula (2), and a compound (B) having a condensed hetero ring skeleton (b) containing a boron atom and at least one selected from the group consisting of an oxygen atom, a sulfur atom, a selenium atom, an sp.sup.3 carbon atom and a nitrogen atom in the ring.

##STR00001##

A charge-transfer salt formed from a material comprising a repeat unit of formula (I) and an n-dopant: wherein BG is a backbone group of the repeat unit; R.sup.1 is a ionic substituent comprising at least one cationic or anionic group; n is at least 1; R.sup.2 is a non-ionic substituent; and m is 0 or a positive integer; the material further comprising a counterion balancing the charge of the cationic or anionic group. ##STR00001##

The present invention relates to a formulation comprising at least one crosslinkable polymer and at least one organic solvent, wherein the at least one crosslinkable polymer is contained in the formulation in a concentration of at least 0.5 g/L, wherein the at least one organic solvent has a boiling point of at least 200° C., characterized in that the solubility of the at least one crosslinkable polymer in the at least one organic solvent is such that the crosslinkable polymer at a concentration of 30 g/L starts to precipitate if 60 vol.-% or less of ethanol is added to the formulation, to the use of these formulations for the preparation of electronic or optoelectronic devices, to a process for the preparation of electronic or optoelectronic devices using these formulations as well as to electronic or optoelectronic devices.

Described herein are methods, compositions and articles of manufacture involving neutral conjugated polymers including methods for synthesis of neutral conjugated water-soluble polymers with linkers along the polymer main chain structure and terminal end capping units. Such polymers may serve in the fabrication of novel optoelectronic devices and in the development of highly efficient biosensors. The invention further relates to the application of these polymers in assay methods.

Provided are: an organic electronic material which can be easily multilayered and that can be used in substrates, such as resin, that cannot be processed at high temperatures; an ink composition containing the same; an organic thin film formed using said organic electronic material or said ink composition; and an organic electronic element and an organic EL element that are formed using said organic thin film and that have a superior luminous efficacy and emission lifespan than conventional elements. Specifically, provided are: an organic electronic material that is characterized by containing an oligomer or a polymer having a structure that branches into three or more directions and has at least one polymerizable substituent; an ink composition containing said organic electronic material; and an organic thin film prepared using the aforementioned organic electronic material. Further, provided are an organic electronic element and an organic electroluminescent element containing said organic thin film.

A compound of formula (I): (Core)n-(X)m wherein Core is a core group; n is 0 and m is 1, or n is 1 and m is at least 1; and X is a group of formula (II): wherein: R.sup.1, R.sup.3 and R.sup.5 are each independently H or a substituent; R.sup.2 and R.sup.4 are each a substituent; one of R.sup.1-R.sup.5 is a direct bond or divalent linking group linking the group of formula (II) to Core in the case where n is 1; x and y are 0, 1, 2, 3 or 4; and the compound of formula (I) is substituted with at least one ionic substituent. The compound may be used as an n-dopant to dope an organic semiconductor. ##STR00001##

The present invention provides an organic nano-grid, a nano-polymer thereof and a preparation method therefor. The organic nano-grid has a general formula (I), and the nano-polymer has a general formula (II), wherein R.sub.1 is an alkyl chain, R.sub.2 is halogen or an electroactive group, and X may comprise a heteroatom such as N, O and S, and n is a natural number from 1 to 10. A nano-connection strategy is applied to the construction of a one-dimensional nano-polymer. The polymer starts from a monomer A.sub.2B.sub.2 to form a corresponding nano-polymer by a Friedel-Crafts polymerization cyclization reaction.

In an embodiment, a composition is provided that includes an indenofluorene moiety; an alkyl radical, an aryl radical, or a heteroaryl radical chemically bound to the indenofluorene moiety; and an electron donor moiety bound to the indenofluorene moiety. In another embodiment, a device is provided that includes compositions described herein. In another embodiment, a method of forming a donor-acceptor small molecule or a donor-acceptor copolymer is provided that includes forming an indenofluorene moiety; forming an electron donor moiety; and reacting the indenofluorene moiety with the electron donor moiety in a cross-coupling reaction.

Described herein are methods, compositions and articles of manufacture involving neutral conjugated polymers including methods for synthesis of neutral conjugated water-soluble polymers with linkers along the polymer main chain structure and terminal end capping units. Such polymers may serve in the fabrication of novel optoelectronic devices and in the development of highly efficient biosensors. The invention further relates to the application of these polymers in assay methods.