A method of manufacturing a conductive layer includes the step of dissolving an organic semiconductor polymer in a first solvent, the first solvent being an aromatic or heterocyclic compound comprising one or more electron-rich carbon atom(s) and/or heteroatom(s). The method also includes dissolving a dopant in a second solvent, the second solvent being a polar solvent. The method also includes mixing the solutions of the organic semiconductor polymer and the dopant to form a dispersion comprising doped conductive polymer particles suspended in the solvent blend. The method also includes depositing the dispersion by a solution deposition technique to form a conductive layer. The solution deposition technique is preferably an inkjet printing, dispense printing or drop casting method. The dispersion provides a stable ink composition for the manufacturing of thick and uniform layers with excellent conductivity and thermopower, and allows simple fabrication of thermoelectric legs with enhanced performance.

An organic electronic material containing a charge transport polymer that includes a 9-phenylcarbazole moiety, and also includes a structure branched in at least three directions from the 9-phenylcarbazole moiety, wherein the organic electronic material satisfies at least one of (I) or (II) below. (I) The 9-phenylcarbazole moiety has a hydrogen atom at position 4 of the phenyl group of the 9-phenylcarbazole moiety. (II) The charge transport polymer also has a triphenylamine structure in which at least one phenyl group has an alkoxy group.

Provided are a conductive composite structure for an electronic device, a method of preparing the conductive composite structure, an electrode for an electronic device including the conductive composite structure, and an electronic device including the conductive composite structure. The conductive composite structure may contain graphene and an organic composite layer including a conductive polymer having a work function of about 5.3 eV or lower, and has a sheet resistance deviation of about 10% or less.

Composite materials are made by impregnating a non-conductive material with a conducting monomer to form a monomer-impregnated non-conductive material, and polymerizing the monomer-impregnated non-conductive material to form the composite material. The composite materials are used in medical devices and implants.

A method of forming a polymer comprising repeat units of formula (II) or a salt thereof by forming a precursor polymer of formula (I) and converting the precursor polymer to the polymer comprising repeat units of formula (II): (Formulae (II), (III)) wherein BG is a backbone group; Sp.sup.1 and Sp.sup.2 are each a spacer group; x is 0 or 1; y is at least 1; X is O or NR.sup.2 wherein R.sup.2 is H or a substituent; P is selected from the group consisting of unsubstituted or substituted benzyl, CR.sup.1.sub.3, COR.sup.1, COOR.sup.1 or, if XO, SiR.sup.1.sub.3; wherein R.sup.1 in each occurrence is a C.sub.1-20 hydrocarbyl group; R.sup.3 in each occurrence is a substituent; and z is 0 or a positive integer. The polymer of formula (II) may form a layer of an organic electronic device and the layer may be formed by deposition of the polymer dissolved in a polar solvent.

Polymerize ethylenedioxythiophene (EDOT) in a polymerization process using dinonylnaphthalenesulfonic acid (DNNSA) as the dopant and Fe(III) p-toluenesulfonate (Fe (III) p-TSA) as the oxidizing agent to produce an organically soluble polyethylenedioxythiophene (PEDOT).

Provided herein is a class of copolymers, including triblock brush copolymers having specific block configurations, for example, ABC triblock brush copolymers and ABA triblock brush copolymers. In an embodiment, for example, copolymers of the invention incorporate various polymer side chain groups which contribute beneficial physical, chemical, or electronic properties such as increased mechanical or elastic strength, improved ionic or electric conductivity. In some embodiments, the provided copolymers exhibit advantageous steric properties allowing for rapid self-assembly into a variety of morphologies that are substantially different than non-brush, block copolymers.

Composite materials are made by impregnating a non-conductive material with a conducting monomer to form a monomer-impregnated non-conductive material, and polymerizing the monomer-impregnated non-conductive material to form the composite material. The composite materials are used in medical devices and implants.

There is provided a material comprising a n-doped electrically conductive polymer comprising at least one electron-deficient aromatic moiety, each electron-deficient aromatic moiety having a gas-phase electron affinity (E.sub.A) of 1-3 eV; and at least one counter-cation covalently bonded to the polymer or to a further polymer comprised in the material, the polymer being n-doped to a charge density of 0.1-1 electron per electron-deficient aromatic moiety, the polymer being capable of forming a layer having a vacuum workfunction (WF) of 2.5-4.5 eV, and wherein all the counter-cations comprised in the material are immobilised such that any electron in the polymer cannot significantly diffuse or migrate out of the polymer. There is also provided a method of preparing the material.

The present invention relates to an organic composition which comprises a conjugated polymer as hole-transport compound and a doping compound. The present invention furthermore relates to the use of the composition according to the invention in organic electroluminescent devices, in particular in the so-called buffer layer of such devices. The present invention also relates to a formulation which comprises the composition according to the invention and a solvent and to an organic electroluminescent device which comprises the composition according to the invention.