A method of preparing an aqueous dispersion of an ethylene-carboxylic acid copolymer according to exemplary embodiments of the present invention includes: mixing 30% by weight or more of an ethylene-(meth)acrylic acid copolymer, a basic compound, and water to form a mixed solution; and adding an inorganic salt compound to the mixed solution. Therefore, the aqueous dispersion of the ethylene-carboxylic acid copolymer may be effectively dispersed.

Polymer particles that comprise a thermoplastic polymer and a nucleating agent may be useful in additive manufacturing methods where warping may be mitigated. For example, a method of producing sais polymer particles may comprise: a thermoplastic polymer, a nucleating agent, a carrier fluid, and optionally an emulsion stabilizer at a temperature at or greater than a melting point or softening temperature of the thermoplastic polymer to emulsify a thermoplastic polymer melt in the carrier fluid; cooling the mixture to form polymer particles; and separating the polymer particles from the carrier fluid, wherein the polymer particles comprise the thermoplastic polymer, the nucleating agent, the emulsion stabilizer, if included, and wherein the polymer particles have a crystallization temperature that is substantially the same as a crystallization temperature of the thermoplastic polymer prior to mixing.

A silicone particle containing: a dialkylsiloxane unit represented by the following general formula (1), R.sup.4.sub.2SiO.sub.2/2 (1), where, in the formula (1), R.sup.4s each independently represent a monovalent hydrocarbon group having 1 to 6 carbon atoms; and a poly(alkyleneoxyalkyl)methylsiloxane unit represented by the following general formula (2), where, in the formula (2), R.sup.1s each independently represent a hydrogen atom or a monovalent hydrocarbon group having 1 to 6 carbon atoms, R.sup.2s each independently represent a divalent aliphatic group having 1 to 6 carbon atoms, and “n” is a number that satisfies 1≤n≤20, where the silicone particle has an oxyalkylene group in a surface thereof. A silicone particle may be readily dispersed in an aqueous material without the use of a dispersant or a surfactant, the silicone particle having a hydrophilic group.

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Aqueous emulsions contain (A) oxamidoester-functionalized organopolysiloxanes having units of the formula
R.sup.1.sub.a(OR.sup.2).sub.bZ.sub.cSiO.sub.(4−a−b−c)/2  (I)
where
Z is a group of the formula
—Y—NR.sup.X—CO—CO—O—R.sup.3  (II),
with the proviso that the sum a+b+c is ≤3 and each molecule contains at least one radical Z.
(B) emulsifiers and
(C) water.

Aqueous emulsions contain (A) oxamidoester-functionalized organopolysiloxanes having units of the formula
R.sup.1.sub.a(OR.sup.2).sub.bZ.sub.cSiO.sub.(4−a−b−c)/2  (I)
where
Z is a group of the formula
—Y—NR.sup.X—CO—CO—O—R.sup.3  (II),
with the proviso that the sum a+b+c is ≤3 and each molecule contains at least one radical Z.
(B) emulsifiers and
(C) water.

The instant invention is an aqueous based blend composition and method of producing the same. The aqueous based blend composition comprises (a) an aqueous polyolefin dispersion comprising the melt blending product of one or more base polymers and one or more stabilizing agents in the presence of water and optionally one or more neutralizing agents, wherein the polyolefin dispersion has an average volume particle size diameter in the range of from 400 to 1500 nm; and a pH range from 8 to 11; and (b) an acrylic emulsion acrylic solids having an average weight particle size diameter in the range of from 75 to 450 nm; an acid level in the range of from 0.25 to 5 percent by weight of acid monomers based on the weight of the acrylic monomer, and a weight average molecular weight in the range of from 200,000 to 5,000,000 g/mole, and a glass transition temperature (T.sub.g) in the range of from 7 to 100° C., wherein said acrylic emulsion has a pH in the range of from 7 to 11; wherein said aqueous based blend composition has a solid content in the range of from 15 to 70 percent by weight of solids, based on the weight of the aqueous based blend composition, and a pH in the range of from 7 to 11.

The instant invention is an aqueous based blend composition and method of producing the same. The aqueous based blend composition comprises (a) an aqueous polyolefin dispersion comprising the melt blending product of one or more base polymers and one or more stabilizing agents in the presence of water and optionally one or more neutralizing agents, wherein the polyolefin dispersion has an average volume particle size diameter in the range of from 400 to 1500 nm; and a pH range from 8 to 11; and (b) an acrylic emulsion acrylic solids having an average weight particle size diameter in the range of from 75 to 450 nm; an acid level in the range of from 0.25 to 5 percent by weight of acid monomers based on the weight of the acrylic monomer, and a weight average molecular weight in the range of from 200,000 to 5,000,000 g/mole, and a glass transition temperature (T.sub.g) in the range of from 7 to 100° C., wherein said acrylic emulsion has a pH in the range of from 7 to 11; wherein said aqueous based blend composition has a solid content in the range of from 15 to 70 percent by weight of solids, based on the weight of the aqueous based blend composition, and a pH in the range of from 7 to 11.

The present invention provides a method for the production of chemically derivatized nanocellulose, comprising the step of a. contacting a precursor cellulosic material with a chemically derivatizing composition to form a liquid reaction mixture, and b. chemically reacting the formed liquid reaction mixture, and c. subjecting the formed liquid reaction mixture to microfluidisation, wherein the steps b. and c. are carried out simultaneously.

The present invention provides a method for the production of chemically derivatized nanocellulose, comprising the step of a. contacting a precursor cellulosic material with a chemically derivatizing composition to form a liquid reaction mixture, and b. chemically reacting the formed liquid reaction mixture, and c. subjecting the formed liquid reaction mixture to microfluidisation, wherein the steps b. and c. are carried out simultaneously.

Methods and apparatus for etching a high aspect ratio feature in a stack on a substrate are provided. The feature may be formed in the process of forming a 3D NAND device. Typically, the stack includes alternating layers of material such as silicon oxide and silicon nitride or silicon oxide and polysilicon. WF.sub.6 is provided in the etch chemistry, which substantially reduces or eliminates problematic sidewall notching. Advantageously, this improvement in sidewall notching does not introduce other tradeoffs such as increased bowing, decreased selectivity, increased capping, or decreased etch rate.