A self-lubricating composite material is disclosed. The self-lubricating composite material can include discontinuous polymer fiber segments dispersed within a woven matrix of semi-continuous thermoplastic fiber. The woven matrix can be embedded within a thermosetting resin. Also disclosed are methods of manufacturing the self-lubricating composite material.

The present invention relates to an aqueous polyurethane dispersion and a process for preparing the same, an adhesive containing the same, and an adhesion article obtained by bonding with the adhesive. The aqueous polyurethane dispersion comprises a polyurethane having an anionic group dispersed therein, the polyurethane has a fusion enthalpy of 3 J/g-100 J/g at 20° C.-100° C. of the first temperature rising curve measured with the DSC according to DIN 65467, a weight-average molecular weight of 31,000-95,000, and the aqueous polyurethane dispersion has an acid value of 0.5 mg KOH/g-8.5 mg KOH/g. The adhesive comprising the aqueous polyurethane dispersion of the present invention has an excellent initial bonding force.

The present invention relates to an aqueous polyurethane dispersion and a process for preparing the same, an adhesive containing the same, and an adhesion article obtained by bonding with the adhesive. The aqueous polyurethane dispersion comprises a polyurethane having an anionic group dispersed therein, the polyurethane has a fusion enthalpy of 3 J/g-100 J/g at 20° C.-100° C. of the first temperature rising curve measured with the DSC according to DIN 65467, a weight-average molecular weight of 31,000-95,000, and the aqueous polyurethane dispersion has an acid value of 0.5 mg KOH/g-8.5 mg KOH/g. The adhesive comprising the aqueous polyurethane dispersion of the present invention has an excellent initial bonding force.

Polypeptide particles of the present invention are particles of a polypeptide derived from spider silk proteins, and have an average particle size of 1000 nm or less. A method for producing polypeptide particles of the present invention includes: a solution production step in which the polypeptide is dissolved in at least one solvent selected from the group consisting of DMSO, DMF, and these with an inorganic salt, so as to obtain a solution of the polypeptide; a step in which the solution produced in the solution production step is substituted with a water-soluble solvent so as to obtain an aqueous solution of the polypeptide; and a step in which the aqueous solution of the polypeptide is dried. Thereby, the present invention provides polypeptide particles suitable for application to a living body and capable of being applied to cosmetics, etc., while identifying the properties of the polypeptide particles, and a method for producing the same.

Polypeptide particles of the present invention are particles of a polypeptide derived from spider silk proteins, and have an average particle size of 1000 nm or less. A method for producing polypeptide particles of the present invention includes: a solution production step in which the polypeptide is dissolved in at least one solvent selected from the group consisting of DMSO, DMF, and these with an inorganic salt, so as to obtain a solution of the polypeptide; a step in which the solution produced in the solution production step is substituted with a water-soluble solvent so as to obtain an aqueous solution of the polypeptide; and a step in which the aqueous solution of the polypeptide is dried. Thereby, the present invention provides polypeptide particles suitable for application to a living body and capable of being applied to cosmetics, etc., while identifying the properties of the polypeptide particles, and a method for producing the same.

A method for producing a resin particle dispersion includes: obtaining a phase-inverted emulsion by adding a neutralizer to a resin solution prepared by dissolving a resin having an acid value in an organic solvent to thereby neutralize the resin and then adding an aqueous medium to the resulting resin solution to subject the resin to phase inversion emulsification; and removing the organic solvent from the phase-inverted emulsion. In the course of obtaining the phase-inverted emulsion, a maximum agitation power per unit mass (kg) of the resin when the resin solution containing the aqueous medium added thereto is agitated to perform the phase inversion emulsification is from 0.4 W to 20 W inclusive.

A method for producing a resin particle dispersion includes: obtaining a phase-inverted emulsion by adding a neutralizer to a resin solution prepared by dissolving a resin having an acid value in an organic solvent to thereby neutralize the resin and then adding an aqueous medium to the resulting resin solution to subject the resin to phase inversion emulsification; and removing the organic solvent from the phase-inverted emulsion. In the course of obtaining the phase-inverted emulsion, a maximum agitation power per unit mass (kg) of the resin when the resin solution containing the aqueous medium added thereto is agitated to perform the phase inversion emulsification is from 0.4 W to 20 W inclusive.

A method for producing a resin particle dispersion includes using a resin particle dispersion production apparatus including: two or more resin particle dispersion production lines each including an emulsification tank in which a resin is subjected to phase inversion emulsification using two or more organic solvents and an aqueous medium to thereby obtain a phase-inverted emulsion, a distillation tank in which the organic solvents are removed from the phase-inverted emulsion by reduced pressure distillation to thereby obtain a resin particle dispersion, and plural distillate collection tanks that collect distillates formed during the reduced pressure distillation according to respective target distillate compositions; and a reusable distillate storage tank A that collects and stores a distillate collected in at least one distillate collection tank A among the distillates collected in the plural distillate collection tanks in each of the two or more resin particle dispersion production lines. The distillate collected in the reusable distillate storage tank A is delivered to the emulsification tank in at least one resin particle dispersion production line among the two or more resin particle dispersion production lines to reuse the distillate for production of a phase-inverted emulsion in the at least one resin particle dispersion production line.

A method for producing a resin particle dispersion includes: preparing a phase-inverted emulsion by phase inversion emulsification of a resin using a neutralizer, an organic solvent, and an aqueous medium; and removing the organic solvent from the phase-inverted emulsion to thereby obtain a resin particle dispersion. The acid value A of the resin is from 8 mg KOH/g to 20 mg KOH/g inclusive. The rate of neutralization of the resin with the neutralizer is 60% or more and less than 150%. The organic solvent contains at least one organic solvent B selected from the group consisting of esters and ketones and at least one organic solvent C selected from alcohols. In the phase-inverted emulsion, the acid value A of the resin, the mass Wr (kg) of the resin, the mass Wb (kg) of the organic solvent B, and the mass Wc (kg) of the organic solvent C satisfy relations represented by the following formulas 1 to 6:

30 (Wb+Wc)/(Wr/100) 250,   formula 1

0.67 Wb/(Wb+Wc) 0.85,   formula 2

K1=(Wb×100)/(A×Wr),   formula 3

2 K1≤K1≤16.5,   formula 4

K2=(Wc×100)/(A×Wr), and   formula 5

0.5≤K2≤5.5   formula 6

Nanoemulsions are prepared by: a) solubilizing a silicone resin in an organic solvent system to yield a silicone resin solution concentration of about 80% or less, wherein the organic solvent system comprises a single solvent selected from the group consisting of monoalcohols, polyalcohols, ethers of monoalcohols, ethers of polyalcohols, fatty esters, Guerbet alcohols, isoparaffins, naphthols, glycol ethers, provided that the solvent is not diethyleneglycol monobutyl ether; b) mixing the silicone resin solution with an aminosiloxane polymer to obtain an aminosiloxane polymer:silicone resin mixture having ratio of about 20:1; c) allowing the resin mixture to age for at least about 6 hours at ambient temperature; d) adding the resin mixture to a vessel; e) optionally adding with agitation, an additional organic solvent to the resin mixture; f) mixing until homogenous; g) adding a protonating agent; h) additionally adding an aqueous carrier in an amount to produce the desired concentration of emulsion.