The disclosure includes brominated alkenyl alcohols, their use as a flame retardant in polyurethane and polyurethane foams, and polyurethanes containing the brominated alkenyl alcohols. Compositions, methods, and processes are disclosed. The brominated alkenyl alcohols used as flame retardants in polyurethanes can be generally described by Formula (I), the scope of which is disclosed herein.

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The invention refers to a method for producing expanded polymer pellets, which comprises the following steps: melting a polymer comprising a polyamide; adding at least one blowing agent; expanding the melt through at least one die for producing an expanded polymer; and pelletizing the expanded polymer. The invention further concerns polymer pellets produced with the method as well as their use, e.g. for the production of cushioning elements for sports apparel, such as for producing soles or parts of soles of sports shoes. A further aspect of the invention concerns a method for the manufacture of molded components, comprising loading pellets of an expanded to polymer material into a mold, and connecting the pellets by providing heat energy, wherein the expanded polymer material of the pellets or beads comprises a chain extender. The molded components may be used in broad ranges of application.

A polymer composition that includes a polymer produced from ethylene, one or more branched vinyl ester monomers, and optionally, vinyl acetate; optionally a secondary foamable polymer; a foaming agent, and a peroxide is provided. Methods for making such a polymer composition include blending a polymer composition from a mixture of a polymer produced from ethylene, one or more branched vinyl ester monomers, and optionally, vinyl acetate, optionally a secondary foamable polymer; a foaming agent, and a peroxide are provided.

The invention relates to flame-retardant polyurethane foam materials or polyurethane/polyisocyanurate foam materials (also referred to individually or collectively as “PUR/PIR foam materials” below) and to methods for producing PUR/PIR foam materials by reacting a reaction mixture containing A1 an isocyanate-reactive component, A2 a propellant, A3 a catalyst, A4 optionally an additive, and A5 a flame retardant with B an isocyanate component, wherein the production is carried out using an index of 80 to 600. The invention is characterized in that the flame retardant A5 contains (hydroxymethyl)phosphonate and optionally the dimer thereof as component A5.1.

Heterogeneous azeotrope or azeotrope-like compositions comprising Z-1-chloro-2,3,3,3-tetrafluoropropene (HCFO-1224yd(Z)) and water which may include from about 47.0 wt. % to about 99.7 wt. % Z-1-chloro-2,3,3,3-tetrafluoropropene (HCFO-1224yd(Z)) and from about 0.3 wt. % to about 53.0 wt. % water and having a boiling point between about 13.0° C. and about 14.0° C. at a pressure of between about 14.0 psia and about 15.0 psia. The azeotrope or azeotrope-like compositions may be used to as blowing agents in the formation of foams.

Methods, foams and blowing agents for producing thermoplastic foam having low aged lambda and low foam density, wherein the blowing agent comprises: (a) from about 50% by weight to about 70% by weight of an HFO and/or an HFCO having three atoms; (b) a first co-blowing agent consisting essentially of from about 2% to about 15% by weight of methyl formate; (c) a second co-blowing agent consisting essentially of from about 20% to about 30% by weight of dimethyl ether, isobutane and combinations of these; and (d) a third co-blowing agent consisting essentially of from about 2% to about 25% by weight of carbon dioxide, acetone and combinations of these.

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

Storage-stable two-component polyurethane or polyisocyanurate spray foam compositions are disclosed, said compositions comprising: (a) an A-side component comprising one or more polyisocyanate and one or more blowing agent; and (b) a B-side component comprising one or more polyol and one or more blowing agent comprising pressurized gaseous carbon dioxide and one or more liquid blowing agent; wherein both the A-side component and the B-side component, separately, generate less than 300 ppm of fluoride ion after one week of aging at 50° C.

Polyurethane foam-forming compositions, methods of producing polyurethane foams, polyurethane foams produced from such compositions made by such methods, as well as isocyanate-reactive compositions. The polyurethane foam-forming compositions include a polyol blend, a blowing agent composition, and a polyisocyanate. The polyol blend includes an aromatic amine-initiated polyether polyol, a saccharide-initiated polyether polyol, and an aromatic polyester polyol and has a content of —C.sub.2H.sub.4O— units of 3 to 6% by weight, based on the total weight of the polyurethane foam-forming composition. The blowing agent composition includes a hydrochlorofluoroolefin and water.

A composition for preparing polyisocyanurate and polyurethane foams is provided, comprising A) a first isocyanate-reactive component comprising a bisphenol, B) a second isocyanate-reactive component different from the first isocyanate-reactive component, and C) a polyisocyanate component. A method for preparing the polyisocyanurate and polyurethane foams, and foams prepared thereby are also provided.