Systems and methods are provided that involve a subcritical water reaction to recycle the cellulose and polyester components of waste cotton and cotton/polyester blend textiles that would otherwise be discarded or disposed of. Specifically, the disclosed methods provide for treatment of the waste textiles to produce advanced materials including cellulose and terephthalic acid (TPA) with a low environmental impact. The cellulose and TPA that are produced are of a high quality allowing for production of regenerated cellulose and regenerated polyethylene terephthalate (PET) suitable for fiber spinning and textile applications.

The present invention relates to a process for the production of ethylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by hydrotreatment of a pyrolysis oil produced from a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and optionally a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising ethylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an ethylene-based polymer; wherein in step (d): .Math. the coil outlet temperature is 2: 800 and:::; 870 C., preferably 2: 820 and:::; 870 C.; and .Math. the weight ratio of steam to feed C is >0.3 and <0.8.

The present invention relates to a process for the production of ethylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by hydrotreatment of a pyrolysis oil produced from a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and optionally a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising ethylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an ethylene-based polymer; wherein in step (d): .Math. the coil outlet temperature is 2: 800 and:::; 870 C., preferably 2: 820 and:::; 870 C.; and .Math. the weight ratio of steam to feed C is >0.3 and <0.8.

A cellulose-aluminum dispersion polyethylene resin composite material, formed by dispersing a cellulose fiber and aluminum into a polyethylene resin, in which the polyethylene resin satisfies a relationship: 1.7>half-width (Log(MH/ML))>1.0 in a molecular weight pattern to be obtained by gel permeation chromatography measurement, a pellet and a formed body using the composite material, and a production method therefor.

A cellulose-aluminum dispersion polyethylene resin composite material, formed by dispersing a cellulose fiber and aluminum into a polyethylene resin, in which the polyethylene resin satisfies a relationship: 1.7>half-width (Log(MH/ML))>1.0 in a molecular weight pattern to be obtained by gel permeation chromatography measurement, a pellet and a formed body using the composite material, and a production method therefor.

This invention relates to the field of plastic waste decomposition. More specifically, the invention comprises products obtained from the decomposition of plastic waste.

A sheet material formed of a degradeable composition comprising 30 to 80 wt % calcium carbonate, an additive, and the balance a polymer selected from polyethylene, polypropylene and copolymers and blends thereof. The additive comprises (a) two or more transition metal compounds, (b) a mono- or poly-unsaturated C.sub.14-C.sub.24 carboxylic acid, or an ester, anhydride or amide thereof, (c) a synthetic rubber. The addition optionally comprises (d) dry starch, and/or (e) calcium oxide, and/or (f) a phenolic antioxidant stabilizer. The two or more transition metal compounds are selected from iron, manganese, copper, zinc, titanium, cobalt and cerium compounds and the transition metals in the two or more transition metal compounds are different.

A sheet material formed of a degradeable composition comprising 30 to 80 wt % calcium carbonate, an additive, and the balance a polymer selected from polyethylene, polypropylene and copolymers and blends thereof. The additive comprises (a) two or more transition metal compounds, (b) a mono- or poly-unsaturated C.sub.14-C.sub.24 carboxylic acid, or an ester, anhydride or amide thereof, (c) a synthetic rubber. The addition optionally comprises (d) dry starch, and/or (e) calcium oxide, and/or (f) a phenolic antioxidant stabilizer. The two or more transition metal compounds are selected from iron, manganese, copper, zinc, titanium, cobalt and cerium compounds and the transition metals in the two or more transition metal compounds are different.

The aim is to refine a method of establishing a predetermined viscosity when recycling polyester wastes having inherently different viscosities in such a way that the desired final material has the appropriate viscosity after a fairly short time, and with little energy consumption, and the color of the melt is also to be influenceable. To this end, it is proposed that the polyester wastes are melted in a first zone (9) of an extruder (1) and the polyester wastes, due to the moisture introduced with them, undergo hydrolytic degradation, in a second zone (11) of the extruder (1) polycondensation takes place and hydrolytic degradation is counteracted and equalization of the viscosity differences is started, in a third zone (13) of the extruder (1) a solvent such as water or alcohol is added such that hydrolytic and/or glycolytic degradation of the melt take(s) place and result(s) in uniform viscosity of the melt, in a fourth zone (14) of the extruder (1) active mixing of the melt takes place and the melt is transferred from the extruder (1) into a polycondensation reactor (6), and the final desired viscosity of the melt is set in the polycondensation reactor (6).

The aim is to refine a method of establishing a predetermined viscosity when recycling polyester wastes having inherently different viscosities in such a way that the desired final material has the appropriate viscosity after a fairly short time, and with little energy consumption, and the color of the melt is also to be influenceable. To this end, it is proposed that the polyester wastes are melted in a first zone (9) of an extruder (1) and the polyester wastes, due to the moisture introduced with them, undergo hydrolytic degradation, in a second zone (11) of the extruder (1) polycondensation takes place and hydrolytic degradation is counteracted and equalization of the viscosity differences is started, in a third zone (13) of the extruder (1) a solvent such as water or alcohol is added such that hydrolytic and/or glycolytic degradation of the melt take(s) place and result(s) in uniform viscosity of the melt, in a fourth zone (14) of the extruder (1) active mixing of the melt takes place and the melt is transferred from the extruder (1) into a polycondensation reactor (6), and the final desired viscosity of the melt is set in the polycondensation reactor (6).